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Group Theory and Quantum Mechanics,9780486432472
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Group Theory and Quantum Mechanics


Author(s): Michael Tinkham
ISBN10:  0486432475
ISBN13:  9780486432472
Format:  Paperback
Pub. Date:  12/17/2003
Publisher(s): Dover Publications

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SummaryTable of Contents
This graduate-level text develops aspects of group theory most relevant to physics and chemistry and illustrates their applications to quantum mechanics: abstract group theory, theory of group representations, physical applications of group theory, full rotation group and angular momentum, quantum mechanics of atoms, molecular quantum mechanics, and solid-state theory. 1964 edition.

Graduate-level text develops group theory relevant to physics and chemistry and illustrates their applications to quantum mechanics, with systematic treatment of quantum theory of atoms, molecules, solids. 1964 edition.
Preface v
Introduction
1(5)
The Nature of the Problem
1(2)
The Role of Symmetry
3(3)
Abstract Group Theory
6(12)
Definitions and Nomenclature
6(1)
Illustrative Examples
7(1)
Rearrangement Theorem
8(1)
Cyclic Groups
9(1)
Subgroups and Cosets
9(1)
Example Groups of Finite Order
10(2)
Conjugate Elements and Class Structure
12(1)
Normal Divisors and Factor Groups
13(2)
Class Multiplication
15(3)
Exercises
16(1)
References
17(1)
Theory of Group Representations
18(32)
Definitions
18(2)
Proof of the Orthogonality Theorem
20(5)
The Character of a Representation
25(3)
Construction of Character Tables
28(1)
Decomposition of Reducible Representations
29(2)
Application of Representation Theory in Quantum Mechanics
31(6)
Illustrative Representations of Abelian Groups
37(2)
Basis Functions for Irreducible Representations
39(4)
Direct-product Groups
43(3)
Direct-product Representations within a Group
46(4)
Exercises
47(1)
References
48(2)
Physical Applications of Group Theory
50(44)
Crystal-symmetry Operators
51(3)
The Crystallographic Point Groups
54(8)
Irreducible Representations of the Point Groups
62(3)
Elementary Representations of the Three-dimensional Rotation Group
65(2)
Crystal-field Splitting of Atomic Energy Levels
67(2)
Intermediate Crystal-field-splitting Case
69(6)
Weak-crystal-field Case and Crystal Double Groups
75(3)
Introduction of Spin Effects in the Medium-field Case
78(2)
Group-theoretical Matrix-element Theorems
80(2)
Selection Rules and Parity
82(5)
Directed Valence
87(2)
Application of Group Theory to Directed Valence
89(5)
Exercises
92(1)
References
93(1)
Full Rotation Group and Angular Momentum
94(60)
Rotational Transformation Properties and Angular Momentum
94(4)
Continuous Groups
98(3)
Representation of Rotations through Eulerian Angles
101(2)
Homomorphism with the Unitary Group
103(3)
Representations of the Unitary Group
106(3)
Representation of the Rotation Group by Representations of the Unitary Group
109(2)
Application of the Rotation-representation Matrices
111(4)
Vector Model for Addition of Angular Momenta
115(2)
The Wigner or Clebsch-Gordan Coefficients
117(4)
Notation, Tabulations, and Symmetry Properties of the Wigner Coefficients
121(3)
Tensor Operators
124(7)
The Wigner-Eckart Theorem
131(2)
The Racah Coefficients
133(4)
Application of Racah Coefficients
137(2)
The Rotation-Inversion Group
139(2)
Time-reversal Symmetry
141(6)
More General Invariances
147(7)
Exercises
151(2)
References
153(1)
Quantum Mechanics of Atoms
154(56)
Review of Elementary Atomic Structure and Nomenclature
155(2)
The Hamiltonian
157(1)
Approximate Eigenfunctions
157(5)
Calculation of Matrix Elements between Determinantal Wavefunctions
162(5)
Hartree-Fock Method
167(3)
Calculation of L-S-term Energies
170(3)
Evaluation of Matrix Elements of the Energy
173(5)
Eigenfunctions and Angular-momentum Operations
178(3)
Calculation of Fine Structure
181(7)
Zeeman Effect
188(5)
Magnetic Hyperfine Structure
193(8)
Electric Hyperfine Structure
201(9)
Exercises
206(2)
References
208(2)
Molecular Quantum Mechanics
210(57)
Born-Oppenheimer Approximation
210(3)
Simple Electronic Eigenfunctions
213(3)
Irreducible Representations for Linear Molecules
216(3)
The Hydrogen Molecule
219(1)
Molecular Orbitals
220(3)
Heitler-London Method
223(3)
Orthogonal Atomic Orbitals
226(1)
Group Theory and Molecular Orbitals
227(6)
Selection Rules for Electronic Transitions
233(1)
Vibration of Diatomic Molecules
234(4)
Normal Modes in Polyatomic Molecules
238(4)
Group Theory and Normal Modes
242(6)
Selection Rules for Vibrational Transitions
248(2)
Molecular Rotation
250(2)
Effect of Nuclear Statistics on Molecular Rotation
252(3)
Asymmetric Rotor
255(2)
Vibration-Rotation Interaction
257(3)
Rotation-Electronic Coupling
260(7)
Exercises
264(2)
References
266(1)
Solid-state Theory
267(68)
Symmetry Properties in Solids
267(3)
The Reciprocal Lattice and Brillouin Zones
270(5)
Form of Energy-band Wavefunctions
275(4)
Crystal Symmetry and the Group of the k Vector
279(2)
Pictorial Consideration of Eigenfunctions
281(3)
Formal Consideration of Degeneracy and Compatibility
284(6)
Group Theory and the Plane-wave Approximation
290(3)
Connection between Tight- and Loose-binding Approximations
293(2)
Spin-orbit Coupling in Band Theory
295(2)
Time Reversal in Band Theory
297(2)
Magnetic Crystal Groups
299(4)
Symmetries of Magnetic Structures
303(6)
The Landau Theory of Second-order Phase Transitions
309(2)
Irreducible Representations of Magnetic Groups
311(6)
Exercises
313(2)
References
315(2)
Appendix
A Review of Vectors, Vector Spaces, and Matrices
317(6)
B Character Tables for Point-symmetry Groups
323(8)
C Tables of ck and ak Coefficients for s, p, and d Electrons
331(4)
Index 335

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