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Practical Guide to Surface Science and Spectroscopy,9780121746100
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Practical Guide to Surface Science and Spectroscopy


Author(s): Chung
ISBN10:  0121746100
ISBN13:  9780121746100
Format:  Hardcover
Pub. Date:  2/19/2001
Publisher(s): Elsevier Science & Technology


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SummaryTable of Contents
Practical Guide to Surface Science and Spectroscopy provides a practical introduction to surface science as well as describes the basic analytical techniques that researchers use to understand what occurs at the surfaces of materials and at their interfaces. These techniques include auger electron spectroscopy, photoelectron spectroscopy, inelastic scattering of electrons and ions, low energy electron diffraction, scanning probe microscopy, and interfacial segregation. Understanding the behavior of materials at their surfaces is essential for materials scientists and engineers as they design and fabricate microelectronics and semiconductor devices.


The book gives over 100 examples, discussion questions and problems with varying levels of difficulty. Included with this book is a CD-ROM, which not only contains the same information, but also provides many elements of animation and interaction that are not easily emulated on paper. In diverse subject matters ranging from the operation of ion pumps, computer-assisted data acquisition to tapping mode atomic force microscopy, the interactive component is especially helpful in conveying difficult concepts and retention of important information. The succinct style and organization of this practical guide is ideal for anyone who wants to get up to speed on a given topic in surface spectroscopy or phenomenon within a reasonable amount of time.

Key Features
* Both theory and practice are emphasized
* Logical organization allows one to get up to speed on any given topic quickly
* Numerous examples, questions for discussion and practice problems are included
* The CD includes animation and interactive elements that help to convey difficult concepts


(Harcourt Science and Technology) A concise and accessible introductory guide to a wide range of surface science and spectroscopy issues, exploring both the theoretical and practical aspects of each topic. The CD-ROM contains all of the material in the text, plus animation and interactive elements that make the text an experience.
Preface xi
Fundamental Concepts in Ultrahigh Vacuum, Surface Preparation, and Electron Spectroscopy
1(22)
Introduction
1(1)
The Need for Ultrahigh Vacuum
2(2)
Achieving Ultrahigh Vacuum
4(3)
Pressure Measurement
7(2)
Preparation of Clean Surfaces
9(1)
Need for Electron Spectroscopy
10(2)
Electron Scattering from Solid Surfaces
12(1)
Electron Energy Analyzers
13(6)
Retarding Field Analyzer
14(2)
Cylindrical Mirror Analyzer
16(1)
Concentric Hemispherical Analyzer
17(2)
Other Considerations
19(4)
Problems
19(4)
Auger Electron Spectroscopy
23(22)
Auger Electron Emission
23(1)
Experimental Aspects
24(2)
Sensitivity of Auger Electron Spectroscopy
26(1)
Energies and Shapes of Auger Peaks
27(1)
Chemical State Effects
28(1)
Intensity of Auger Electron Emission
29(4)
Profile Analysis
33(1)
Scanning Auger Microprobe
33(2)
Quantitative Analysis
35(4)
Case Study: Surface Composition of a 5 at% Al-Fe Alloy
39(6)
Problems
40(5)
Photoelectron Spectroscopy
45(24)
One-Electron Description of the Photoelectric Effect
45(2)
Photon Sources
47(3)
Detectors
50(1)
Element Identification
51(1)
Chemical Shift
51(2)
Relaxation Shift and Multiplet Splitting
53(1)
Chemical Bonding on Surfaces
54(2)
Band Structure Studies
56(4)
Extended X-Ray Absorption Fine Structure
60(2)
Special Applications
62(7)
Auger Electron and Photoelectron Forward Scattering
62(1)
Photoemission of Adsorbed Xenon
63(1)
Problems
64(5)
Inelastic Scattering of Electrons and lons
69(14)
One-Electron Excitation of Core and Valence Electrons
69(2)
Plasmon Excitations
71(1)
Surface Vibrations
72(3)
Ion Scattering Spectroscopy
75(2)
Secondary Ion Mass Spectrometry
77(6)
Problems
80(3)
Low-Energy Electron Diffraction
83(18)
Introduction
83(1)
Electron Diffraction
83(2)
Naming Conventions for Surface Structures
85(2)
Experimental Aspects
87(1)
Selected Properties of the Surface Reciprocal Space
88(1)
Kinematic Theory
89(3)
Applications of the Kinematic Theory
92(9)
Determination of Real Space Lattice from LEED Pattern
92(1)
Angular Spread of Diffracted Beams
93(2)
Steps
95(1)
Surface Vibrations
96(1)
Problems
97(1)
Appendix Diffraction Intensity as a Function of Temperature
98(3)
Scanning Probe Microscopy
101(18)
Introduction
101(1)
Historical Perspective
102(1)
Review of Electron Tunneling
103(1)
Principle of STM Imaging
104(2)
STM Image Implementation
106(1)
STM Implementation
107(5)
Coarse Motion Control
107(1)
Fine Motion Control
107(2)
Tip Preparation
109(1)
Vibration Isolation
110(1)
Data Acquisition and Analysis
111(1)
Applications of STM
112(2)
High-Resolution Imaging of Surfaces
112(1)
Spectroscopy
113(1)
Lithography
113(1)
Current Fluctuations
114(1)
Limitations of STM and Solutions
114(1)
Scanning Capacitance Microscopy
115(1)
Atomic Force Microscopy
115(4)
Equations of Interest
116(1)
Problems
116(1)
Additional Reading
117(2)
Interfacial Segregation
119(18)
Introduction
119(1)
Gibbs Adsorption Equation
119(4)
One Component Systems
123(1)
Surface Segregation in Binary Alloys
124(3)
Relationship Between Surface and Bulk Composition of Binary Alloys
127(2)
The Unified Segregation Model
129(2)
Surface Energy and Heat of Mixing
129(1)
Elastic Strain Energy
130(1)
Entropy Change
131(1)
Comparison with Experiment
131(1)
Environmental Effects on Surface Segregation
131(6)
Problems
133(4)
Metal-Semiconductor Interfaces
137(20)
Surface States
137(4)
Semiconductor Surfaces
141(5)
The Space Charge Region
141(3)
Fermi-Level Pinning
144(2)
Work Function Measurements
146(2)
Photoemission
147(1)
Kelvin Method
147(1)
Retarding Field Technique
148(1)
The Metal-Semiconductor Interface
148(9)
The Schottky Model
148(4)
Surface States and the Defect Model
152(1)
Case Study: Gold on InP
153(1)
Problems
153(3)
Appendix Useful Information for Semiconductors
156(1)
Gas-Surface Interactions
157(24)
Introduction
157(2)
Heat of Adsorption
159(8)
The Langmuir Adsorption Isotherm
167(5)
Noninteracting Atoms
167(3)
Interacting Atoms
170(1)
Effect on Surface Tension
171(1)
Pressure Effects
172(1)
Promoters, Poisons, and Ensemble Effects
172(1)
Surface Compounds
173(1)
Case Studies
174(7)
Strong Metal-Support Interaction
174(3)
Ductility of Ni3Al
177(1)
Problems
178(3)
Index 181

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