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Heteroatom Chemistry,9780471187318
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Heteroatom Chemistry


Author(s): Editor: Eric Block (State Univ. of New York at Albany)
ISBN10:  0471187313
ISBN13:  9780471187318
Format:  Hardcover
Pub. Date:  7/1/1990
Publisher(s): Wiley-VCH

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SummaryTable of Contents
Heteroatom Chemistry Edited by Eric Block A concise introduction to heteroatom chemistry. This collection contains current summaries of research from top experts on each of the principle heteroatoms. Highlights include recent trends in the organic chemistry of such heteroatoms as boron, sulfur, silicon, germanium, selenium, tellurium, tin, phosphorus, arsenic, antimony and bismuth. It is highly recommended for the graduate student as useful supplemental reading and for the seasoned researcher who suddenly needs know the latest research of heteroatom chemistry. This book includes current references and a full subject index.

This is one of the first books to deal in a broader manner with all important elements described as main group non metals. It is especially useful for graduate students and researchers who need a concise introduction to current 'hot' areas of research for the principle heteroatoms (sulfur, phosphorus, boron, silicon, tin etc.). The references are up-to-date, and the subject index is extensive.
Preface
Chapter 1. New Chemistry of Fused 1,2,3-Selenadiazoles and 1,2,3-Thiadiazoles
Wataru Ando and Norihiro Tokitoh
Chapter 2. Organosilicon Chemistry: A Synergistic Relation between Theory and Experiment
Yitzhak Apeloig
Chapter 3. Electron-Rich Bonding at Low-Coordination Main Group Element Centers
Anthony J. Arduengo, III, and David A. Dixon
Chapter 4. New Aspects of Organosulfur and Selenium Chemistry: The Selenosulfonation Reaction
Thomas G. Back, Kurt Brunner, M. Vijaya Krishna, Enoch K. Y. Lai, and K. Raman Muralidharan
Chapter 5. Ligand Coupling in Bismuth and Lead Derivatives
Derek H. R. Barton
Chapter 6. Cycloaddition Reactions and Rearrangements of Stable Silenes and their Derivatives
Adrian G. Brook
Chapter 7. Carbanion Production by Reductive Cleavage of Carbon-Sulfur and Carbon-Oxygen Bonds
Theodore Cohen
Chapter 8. Asymmetric Reactions of Atropisomeric Sulfur Compounds
Sergio Cossu, Ottorino De Lucchi, Davide Fabbri, Maria Paola Fois, and Paola Maglioli
Chapter 9. Reactions of Sulfoxides with Organometallic Reagents: Is Sulfurane an Intermediate?
Naomichi Furukawa
Chapter 10. Facile Syntheses of Unsaturated Aldehydes, Ketones, Amides, and Related Natural Products via Arsonium Salts
Yao-Zeng Huang, Li-Lan Shi, Jian-Hua Yang, Wen-Juan Xiao, Sao-Wei Li, and Wei-Bo Wang
Chapter 11. Efficient Asymmetric Syntheses of Chiral Sulfoxides and Some Synthetic Applications
Henri B. Kagan
Chapter 12. Original Syntheses of Molecules Containing Adjacent Quaternary Carbons
A. Krief, J. L. Laboureur, M. Hobe, and P. Barbeaux
Chapter 13. A Review of Multidentate Lewis Acid Chemistry
Henry G. Kuivila
Chapter 14. The Interaction of Group IVB (14) Elements with Positive Charge on a Beta Carbon
Joseph B. Lambert, Gen-tai Wang, and Erik C. Chelius
Chapter 15. Synthesis and Structures of Some Novel Organic Compounds Containing Boron and Phosphorus
Anthony G. Avent, Michael F. Lappert, Brian Skelton, Colin L. Raston, Lutz M. Engelhardt, Stephen Harvey, and Allan H. White
Chapter 16. Stereochemistry of Sulfoxide and Its Application to Synthesis
Atsuyoshi Ohno
Chapter 17. Phosphaalkynes--New Building Blocks in Heteroatom Chemistry
Manfred Regitz
Chapter 18. Recent Advances in Silicon-Containing Cyclic Polyacetylenes
Hideki Sakurai
Chapter 19. Unusual Bonding between Bismuth and Carbon in Bismuth Pentaaryls: The Color Problem of Bi(C6H5)5
Konrad Seppelt
Chapter 20. Syntheses and Structures of Copper and Silver Cluster Complexes with Sulfur-Containing Ligands
Kaluo Tang and Youqi Tang
Index

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