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xxv | |
| Teaching (Nano)Materials |
|
xxix | |
| Learning (Nano)Materials |
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xxxi | |
| About the Authors |
|
xxxiii | |
| Acknowledgements |
|
xxxvii | |
| Nanofood for Thought -- Thinking about Nanochemistry, Nanoscience, Nanotechnology and Nanosafety |
|
xxxix | |
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1 | (48) |
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1 | (1) |
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2 | (1) |
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2 | (1) |
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What do we Mean by Large and Small Nanomaterials? |
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3 | (1) |
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Do it Yourself Quantum Mechanics |
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4 | (1) |
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5 | (1) |
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Molecular vs. Materials Self-Assembly |
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5 | (1) |
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What is Hierarchical Assembly? |
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6 | (1) |
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6 | (1) |
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7 | (1) |
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Geneology of Self-Assembling Materials |
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8 | (3) |
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Unlocking the Key to Porous Solids |
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11 | (3) |
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Learning from Biominerals -- Form is Function |
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14 | (2) |
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16 | (1) |
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Patterns, Patterns Everywhere |
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17 | (1) |
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Synthetic Creations with Natural Form |
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18 | (2) |
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Two-Dimensional Assemblies |
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20 | (3) |
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SAMs and Soft Lithography |
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23 | (1) |
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24 | (2) |
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Extending the Prospects of Nanowires |
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26 | (1) |
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27 | (4) |
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31 | (1) |
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Materials Self-Assembly of Integrated Systems |
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32 | (1) |
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33 | (16) |
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Nanofood for Thought -- Nanochemistry, Genealogy Materials Self-Assembly, Length Scales |
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45 | (4) |
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Chemical Patterning and Lithography |
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49 | (46) |
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49 | (1) |
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What are Self-Assembled Monolayers? |
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50 | (2) |
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The Science and Art of Soft Lithography |
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52 | (2) |
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54 | (1) |
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55 | (1) |
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56 | (2) |
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58 | (1) |
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Patterning the Solid State |
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59 | (2) |
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Primed for Printing Polymers |
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61 | (2) |
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Beyond Molecules -- Transfer Printing of Thin Films |
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63 | (1) |
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Electrically Contacting SAMS |
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64 | (2) |
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66 | (2) |
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Learning from Nature's Biocrystal Engineering |
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68 | (3) |
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Colloidal Microsphere Patterns |
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71 | (1) |
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71 | (2) |
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Patterning by Photocatalysis |
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73 | (1) |
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Reversibly Switching SAMs |
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74 | (2) |
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Electrowettability Switch |
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76 | (1) |
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77 | (2) |
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All Fall Down in a Row Lithography |
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79 | (1) |
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80 | (15) |
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Nanofood for Thought -- Soft Lithography, SAMs, Patterning |
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89 | (6) |
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Layer-by-Layer Self-Assembly |
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95 | (36) |
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Building One Layer at a Time |
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95 | (1) |
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Electrostatic Superlattices |
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95 | (2) |
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Organic Polyelectrolyte Multilayers |
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97 | (1) |
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Layer-by-Layer Smart Windows |
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97 | (2) |
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99 | (1) |
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Assembling Metallopolymers |
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99 | (1) |
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Directly Imaging Polyelectrolyte Multilayers |
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100 | (1) |
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Polyelectrolyte-Colloid Multilayers |
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101 | (2) |
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Graded Composition LbL Films |
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103 | (1) |
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104 | (2) |
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106 | (1) |
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Layering on Curved Surfaces |
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106 | (2) |
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Crystal Engineering of Oriented Zeolite Film |
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108 | (2) |
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Zeolite-Ordered Multicrystal Arrays |
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110 | (1) |
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Crosslinked Crystal Arrays |
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111 | (1) |
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Layering with Topological Complexity |
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112 | (1) |
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113 | (2) |
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Non-Electrostatic Layer-by-Layer Assembly |
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115 | (1) |
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116 | (1) |
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Layer-by-Layer Self-Limiting Reactions |
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117 | (1) |
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118 | (13) |
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Nanofood for Thought -- Designer Monolayers, Multilayers, Materials Flatland |
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126 | (5) |
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Nanocontact Printing and Writing -- Stamps and Tips |
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131 | (36) |
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Sub-100 nm Soft Lithography |
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131 | (1) |
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Extending Microcontact Printing |
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131 | (2) |
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133 | (2) |
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Defect Patterning -- Topologically Directed Etching |
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135 | (1) |
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Below 50 nm Nanocontact Printing |
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136 | (1) |
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Nanocontact Writing -- Dip Pen Nanolithography |
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137 | (1) |
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138 | (1) |
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139 | (1) |
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Nanoscale Writing on Seminconductor Nanowires |
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140 | (1) |
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141 | (1) |
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Soft Patterning of Hard Magnets |
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142 | (1) |
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Writing Molecular Recognition |
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143 | (2) |
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DPN Writing Protein Recognition Nanostructures |
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145 | (1) |
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Patterning Bioconstructions |
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145 | (2) |
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Eating Patterns -- Enzyme DPN |
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147 | (1) |
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148 | (1) |
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148 | (1) |
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SPM Nano-Electrochemistry |
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149 | (2) |
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Beyond DPN -- Whittling Nanostructures |
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151 | (1) |
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Combi Nano -- DPN Combinatorial Libraries |
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151 | (2) |
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153 | (1) |
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154 | (1) |
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Scanning Probe Contact Printing (SP-CP) |
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155 | (2) |
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Dip Pen Nanolithography Stamp Tip -- Beyond DPN CP |
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157 | (1) |
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157 | (1) |
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The Nanogenie is out of the Bottle |
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158 | (1) |
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158 | (9) |
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Nanofood for Thought -- Sharper Chemical Patterning Tools |
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164 | (3) |
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Nanorod, Nanotube, Nanowire Self-Assembly |
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167 | (98) |
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167 | (1) |
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167 | (1) |
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Modulated Diameter Gold Nanorods |
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168 | (2) |
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Modulated Composition Nanorods |
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170 | (3) |
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Barcoded Nanorod Orthogonal Self-Assembly |
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173 | (3) |
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176 | (1) |
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Magnetic Nanorods Bunch Up |
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177 | (1) |
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Magnetic Nanorods and Magnetic Nanoclusters |
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178 | (3) |
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An Irresistable Attraction for Biomolecules |
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181 | (2) |
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Hierarchically Ordered Nanorods |
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183 | (1) |
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184 | (2) |
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Nanotubes from Nanoporous Templates |
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186 | (2) |
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Layer-by-Layer Nanotubes from Nanorods |
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188 | (1) |
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Synthesis of Single Crystal Semiconductor Nanowires |
|
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189 | (1) |
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Vapor-Liquid-Solid Synthesis of Nanowires |
|
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189 | (2) |
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What Controls Nanowire-Oriented Growth? |
|
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191 | (1) |
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Supercritical Fluid-Liquid-Solid Synthesis |
|
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191 | (2) |
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Nanowire Quantum Size Effects |
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193 | (2) |
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Zoo of Nanowire Compositions and Architectures |
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195 | (1) |
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195 | (1) |
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196 | (3) |
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Crossed Semiconductor Nanowires -- Smallest LED |
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199 | (2) |
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Nanowire Diodes and Transistors |
|
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201 | (1) |
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201 | (2) |
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Catalytic Nanowire Electronics |
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203 | (1) |
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Nanowire Heterostructures |
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204 | (2) |
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Longitudinal Nanowire Superlattices |
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206 | (1) |
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Axial Nanowire Heterostructures |
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207 | (2) |
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209 | (1) |
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Coaxially Gated Nanowire Transistor |
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209 | (3) |
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Vertical Nanowire Field Effect Transistors |
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212 | (3) |
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Integrated Metal--Semiconductor Nanowires -- Nanoscale Electrical Contacts |
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215 | (1) |
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Photon-Driven Nanowire Laser |
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216 | (2) |
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Electrically Driven Nanowire Laser |
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218 | (2) |
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Nanowire UV Photodetectors |
|
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220 | (1) |
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Simplifying Complex Nanowires |
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220 | (2) |
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Nanowire Casting of Single-Crystal Nanotubes |
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222 | (1) |
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Solution-Phase Routes to Nanowires |
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223 | (3) |
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Spinning Nanowire Devices |
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226 | (1) |
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Hollow Nanofibers by Electrospinning |
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227 | (2) |
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229 | (1) |
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Carbon Nanotube Structure and Electrical Properties |
|
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229 | (2) |
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231 | (2) |
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Carbon Nanotube Nanomechanics |
|
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233 | (1) |
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Carbon Nanotube Chemistry |
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233 | (3) |
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Carbon Nanotubes All in a Row |
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236 | (2) |
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Carbon Nanotube Photonic Crystal |
|
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238 | (2) |
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Putting Carbon Nanotubes Exactly Where You Want Them |
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240 | (2) |
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The Nanowire Pitch Challenge |
|
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242 | (2) |
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Integrated Nanowire Nanoelectronics |
|
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244 | (2) |
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A Small Thought at the End of a Large Chapter |
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246 | (1) |
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246 | (19) |
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Nanofood for Thought -- Wires, Rods, Tubes, Low Dimensionality |
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260 | (5) |
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Nanocluster Self-Assembly |
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265 | (60) |
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265 | (1) |
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When is a Nanocluster a Nanocrystal or Nanoparticle? |
|
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266 | (1) |
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Synthesis of Capped Semiconductor Nanoclusters |
|
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266 | (2) |
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Electrons and Holes in Nanocluster Boxes |
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268 | (2) |
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Watching Nanoclusters Grow |
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270 | (1) |
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Nanocrystals in Nanobeakers |
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271 | (2) |
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Nanocluster Semiconductor Alloys and Beyond |
|
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273 | (1) |
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Nanocluster Phase Transformation |
|
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274 | (1) |
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Capped Gold Nanoclusters -- Nanonugget Rush |
|
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275 | (2) |
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Alkanethiolate Capped Nanocluster Diagnostics |
|
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277 | (1) |
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Periodic Table of Capped Nanoclusters |
|
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278 | (1) |
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There's Gold in Them Thar Hills! |
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278 | (1) |
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Water-Soluble Nanoclusters |
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279 | (2) |
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Capped Nanocluster Architectures and Morphologies |
|
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281 | (1) |
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Alkanethiolate Capped Silver Nanocluster Superlattice |
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282 | (2) |
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284 | (1) |
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Beyond Crystal of Nanocrystals -- Binary Nanocrystal Superlattices |
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285 | (1) |
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Capped Magnetic Nanocluster Superlattice -- High Density Data Storage Materials |
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286 | (1) |
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Alloying Core--Shell Magnetic Nanoclusters |
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287 | (1) |
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Soft Lithography of Capped Nanoclusters |
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288 | (1) |
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Organizing Nanoclusters by Evaporation |
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289 | (1) |
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Electroluminescent Semiconductor Nanoclusters |
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289 | (2) |
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Full Color Nanocluster-Polymer Composites |
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291 | (2) |
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Capped Semiconductor Nanocluster Meets Biomolecule |
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293 | (3) |
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Nanocluster DNA Sensors -- Besting the Best |
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296 | (1) |
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Semiconductor Nanoclusters Extend and Branch Out |
|
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297 | (2) |
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Branched Nanocluster Solar Cells |
|
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299 | (1) |
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Tetrapod of Tetrapods -- Towards Inorganic Dendrimers |
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300 | (1) |
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Golden Tips -- Making Contact with Nanorods |
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301 | (2) |
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Flipping a Nanocluster Switch |
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303 | (1) |
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Photochromic Metal Nanoclusters |
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304 | (2) |
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Carbon Nanoclusters -- Buckyballs |
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306 | (1) |
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Building Nanodevices with Buckyballs |
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307 | (1) |
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Carbon Catalysis with Buckyball |
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308 | (1) |
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309 | (16) |
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Nanofood for Thought -- Nanoclusters, Nanocrystals, Quantum Dots, Quantum Size Effects |
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320 | (5) |
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Microspheres -- Colors from the Beaker |
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325 | (54) |
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Nature's Photonic Crystals |
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325 | (1) |
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325 | (2) |
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327 | (1) |
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Defects, Defects, Defects |
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328 | (1) |
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328 | (2) |
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330 | (1) |
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Transferring Nature's Photonic Crystal Technology to the Chemistry Laboratory |
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330 | (1) |
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Microsphere Building Blocks |
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331 | (1) |
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331 | (1) |
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332 | (1) |
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332 | (1) |
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Basics of Microsphere Self-Assembly |
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333 | (1) |
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Microsphere Self-Assembly -- Crystals and Films |
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334 | (2) |
|
Colloidal Crystalline Fluids |
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336 | (1) |
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Beyond Face Centered Cubic Packing of Microspheres |
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337 | (1) |
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Templates -- Confinement and Epitaxy |
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338 | (2) |
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340 | (1) |
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340 | (3) |
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Optical Properties of Colloidal Crystals -- Combined Bragg--Snell Laws |
|
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343 | (1) |
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Basic Optical Properties of Colloidal Crystals |
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343 | (2) |
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345 | (1) |
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346 | (2) |
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Synthesizing a Full Photonic Band Gap |
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348 | (1) |
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349 | (1) |
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Getting Smart with Planar Defects |
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350 | (3) |
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Switching Light with Light |
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353 | (1) |
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353 | (1) |
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354 | (3) |
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357 | (1) |
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357 | (2) |
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Colloidal Photonic Crystal Solar Cell |
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359 | (1) |
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Thermochromic Colloidal Photonic Crystal Switch |
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360 | (1) |
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Liquid Crystal Photonic Crystal |
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361 | (2) |
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Encrypted Colloidal Crystals |
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363 | (2) |
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Gazing into the Photonic Crystal Ball |
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365 | (1) |
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365 | (14) |
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Nanofood for Thought -- Colloidal Assembly, Colloidal Crystals, Colloidal Crystal Devices, Structural Color |
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373 | (6) |
|
Microporous and Mesoporous Materials from Soft Building Blocks |
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379 | (56) |
|
Escape from the Zeolite Prison |
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379 | (1) |
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A Periodic Table of Materials Filled with Holes |
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380 | (1) |
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Modular Self-Assembly of Microporous Materials |
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381 | (2) |
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Hydrogen Storage Coordination Frameworks |
|
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383 | (1) |
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Overview and Prospects of Microporous Materials |
|
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384 | (1) |
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Mesoscale Soft Building Blocks |
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385 | (2) |
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Micelle Versus Liquid Crystal Templating Paradox |
|
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387 | (1) |
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Designing Function into Mesoporous Materials |
|
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387 | (1) |
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388 | (2) |
|
Mesostructure and Dimensionality |
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390 | (1) |
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Mesocomposition -- Nature of Precursors |
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390 | (1) |
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391 | (1) |
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Periodic Mesoporous Silica--Polymer Hybrids |
|
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392 | (1) |
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393 | (1) |
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Capped Nanocluster Meets Surfactant Mesophase |
|
|
394 | (2) |
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Marking Time in Mesostructured Silica -- New Approach to Optical Data Storage |
|
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396 | (1) |
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Sidearm Mesofunctionalization |
|
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397 | (1) |
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398 | (2) |
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Mesomorphology -- Films, Interfaces, Mesoepitaxy |
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400 | (2) |
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402 | (2) |
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Mesomorphology -- Spheres, Other Shapes |
|
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404 | (2) |
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Mesomorphology -- Patterned Films, Soft Lithography, Micromolding |
|
|
406 | (2) |
|
Mesomorphology -- Morphosynthesis of Curved Form |
|
|
408 | (2) |
|
Chiral Surfactant Micelles -- Chiral Mesoporous Silica |
|
|
410 | (3) |
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413 | (1) |
|
Mesochemistry and Topological Defects |
|
|
414 | (1) |
|
Mesochemistry -- Synthesis in ``Intermediate'' Dimensions |
|
|
415 | (3) |
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418 | (17) |
|
Nanofood for Thought -- Soft Blocks Template Hard Precursors, Holey Materials |
|
|
430 | (5) |
|
Self-Assembling Block Copolymers |
|
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435 | (38) |
|
Polymers, Polymers Everywhere in Nanochemistry |
|
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435 | (1) |
|
Block Copolymer Self-Assembly -- Chip Off the Old Block |
|
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435 | (2) |
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437 | (2) |
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439 | (1) |
|
Block Copolymer Thin Films |
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439 | (3) |
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442 | (1) |
|
Spatial Confinement of Block Copolymers |
|
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442 | (2) |
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444 | (1) |
|
Block Copolymer Lithography |
|
|
444 | (2) |
|
Decorating Block Copolymers |
|
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446 | (1) |
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447 | (2) |
|
Nanowires from Block Copolymers |
|
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449 | (2) |
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451 | (2) |
|
Assembling Inorganic Polymers |
|
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453 | (1) |
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453 | (2) |
|
Supramolecular Assemblies |
|
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455 | (1) |
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456 | (2) |
|
Structural Color from Lightscale Block Copolymers |
|
|
458 | (1) |
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459 | (2) |
|
Block Copolymer Biofactories |
|
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461 | (1) |
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462 | (11) |
|
Nanofood for Thought -- Block Copolymer Self-Assembling Nanostructures |
|
|
468 | (5) |
|
Biomaterials and Bioinspiration |
|
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473 | (58) |
|
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473 | (1) |
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474 | (1) |
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475 | (1) |
|
Nature's Siliceous Sculptures |
|
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476 | (1) |
|
Ancient to Modern Synthetic Morphology |
|
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477 | (1) |
|
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478 | (1) |
|
Biomineralization and Biomimicry Analogies |
|
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479 | (2) |
|
|
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481 | (1) |
|
Viral Cage Directed Synthesis of Nanoclusters |
|
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482 | (1) |
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483 | (1) |
|
Polynucleotide Directed Nanocluster Assembly |
|
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484 | (1) |
|
DNA Coded Nanocluster Chains |
|
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485 | (2) |
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487 | (2) |
|
Bacteria Directed Materials Self-Assembly |
|
|
489 | (2) |
|
Using a Virus that is Benign, to Align |
|
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491 | (1) |
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492 | (1) |
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|
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493 | (3) |
|
Morphosynthesis -- Inorganic Materials with Complex Form |
|
|
496 | (2) |
|
Echinoderm vs. Block Copolymers |
|
|
498 | (1) |
|
Fishy Top-Down Photonic Crystals |
|
|
499 | (2) |
|
Aluminophosphates Shape Up |
|
|
501 | (1) |
|
Better Bones Through Chemistry |
|
|
502 | (2) |
|
|
|
504 | (1) |
|
Biological Lessons in Materials Design |
|
|
505 | (1) |
|
Surface Binding Through Directed Evolution |
|
|
505 | (3) |
|
|
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508 | (1) |
|
Biomolecular Motors -- Nanomachines Everywhere |
|
|
508 | (2) |
|
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510 | (2) |
|
|
|
512 | (3) |
|
ATPase -- Biomotor Nanopropellors |
|
|
515 | (1) |
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|
|
516 | (1) |
|
|
|
517 | (14) |
|
Nanofood for Thought -- Organic Matrix, Biomineralization, Biomimetics, Bioinspiration |
|
|
527 | (4) |
|
Self-Assembly of Large Building Blocks |
|
|
531 | (22) |
|
Self-assembling Supra-micron Shapes |
|
|
531 | (1) |
|
Synthesis Using the ``Capillary Bond'' |
|
|
532 | (1) |
|
Crystallizing Large Polyhedral-Shaped Building Blocks |
|
|
533 | (1) |
|
Self-Assembling 2D and 3D Electrical Circuits and Devices |
|
|
533 | (1) |
|
Crystallizing Micron-Sized Planar Building Blocks |
|
|
534 | (2) |
|
Polyhedra with Patterned Faces that Autoconstruct |
|
|
536 | (4) |
|
Large Sphere Building Blocks Self-Assemble into 3D Crystals |
|
|
540 | (1) |
|
|
|
541 | (1) |
|
|
|
541 | (2) |
|
|
|
543 | (1) |
|
|
|
544 | (3) |
|
Self-Assembly and Synthetic Life |
|
|
547 | (1) |
|
|
|
548 | (5) |
|
Nanofood for Thought -- Static and Dynamic, Capillary Bond, Shape Assembly |
|
|
550 | (3) |
|
|
|
553 | (26) |
|
|
|
553 | (1) |
|
|
|
554 | (1) |
|
Fuel Cells -- Hold the Membrane |
|
|
554 | (1) |
|
|
|
554 | (1) |
|
Beating the Ink Diffusion Dilemma |
|
|
555 | (1) |
|
|
|
556 | (1) |
|
|
|
556 | (1) |
|
|
|
556 | (1) |
|
Complete Crystallographic Control |
|
|
557 | (1) |
|
|
|
557 | (1) |
|
|
|
558 | (1) |
|
Writing 3D Nanofluidic and Nanophotonic Networks |
|
|
559 | (1) |
|
Break-and-Glue Transistor Assembly |
|
|
560 | (1) |
|
Turning Nanostructures Inside-out |
|
|
560 | (1) |
|
|
|
560 | (2) |
|
Escape from the Silica and Polystyrene Prison |
|
|
562 | (1) |
|
|
|
562 | (1) |
|
Light Writing for Light Guiding |
|
|
562 | (1) |
|
Nanoring Around the Collar |
|
|
563 | (1) |
|
|
|
563 | (1) |
|
Fungus with the Midas Touch |
|
|
564 | (1) |
|
Self-assembled Electronics |
|
|
565 | (1) |
|
Gears Sink Their Teeth into the Interface |
|
|
565 | (1) |
|
|
|
566 | (2) |
|
Matter that Matters -- Materials of the ``Next Kind'' |
|
|
568 | (3) |
|
|
|
571 | (8) |
|
Nanofood for Thought -- Nano Potpourri |
|
|
574 | (5) |
|
|
|
579 | (6) |
| Appendix A: Origin of the Term ``Self-Assembly'' |
|
585 | (4) |
| Appendix B: Cytotoxicity of Nanoparticles |
|
589 | (4) |
| Appendix C: Walking Macromolecules Through Colloidal Crystals |
|
593 | (4) |
| Appendix D: Patterning Nanochannel Alumina Membranes With Single Channel Resolution |
|
597 | (2) |
| Appendix E: Muscle Powered Nanomachines |
|
599 | (4) |
| Appendix F: Bacteria Power |
|
603 | (4) |
| Appendix G: Chemically Driven Nanorod Motors |
|
607 | (4) |
| Subject Index |
|
611 | |
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