| Preface |
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v | |
| Acknowledgements |
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ix | |
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Introduction, Definitions, Goal |
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1 | (18) |
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History of Chromatography |
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3 | (9) |
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12 | (3) |
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15 | (4) |
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17 | (2) |
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The Mass Balance Equation of Chromatography and Its General Properties |
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19 | (48) |
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Mass and Heat Balance Equations in Chromatography |
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21 | (21) |
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Solution of the System of Mass Balance Equations |
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42 | (15) |
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57 | (10) |
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63 | (4) |
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Single-Component Equilibrium Isotherms |
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67 | (84) |
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Fundamentals of Adsorption Equilibria |
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70 | (10) |
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Models of Adsorption Isotherms in Liquid--Solid Equilibria |
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80 | (29) |
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Adsorption and Affinity Energy Distribution |
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109 | (8) |
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Influence of Experimental Conditions on Equilibrium Isotherms |
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117 | (5) |
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Determination of Single-Component Isotherms |
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122 | (13) |
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Data Processing and Assessment |
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135 | (16) |
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144 | (7) |
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Competitive Equilibrium Isotherms |
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151 | (70) |
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Models of Multicomponent Competitive Adsorption Isotherms |
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153 | (38) |
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Determination of Competitive Isotherms |
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191 | (30) |
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216 | (5) |
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Transfer Phenomena in Chromatography |
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221 | (60) |
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222 | (18) |
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Axial Dispersion and Mass Transfer Resistance in Porous Media |
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240 | (17) |
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257 | (24) |
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275 | (6) |
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281 | (66) |
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283 | (7) |
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The Solution of the Mas Balance Equation |
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290 | (11) |
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The General Rate Model of Chromatography |
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301 | (9) |
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Moment Analysis and Plate Height Equations |
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310 | (18) |
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328 | (7) |
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Sources of Band Asymmetry and Tailing in Linear Chromatography |
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335 | (6) |
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Extension of Linear to Nonlinear Chromatography Models |
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341 | (6) |
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342 | (5) |
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Band Profiles of Single-Components with the Ideal Model |
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347 | (40) |
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Retrospective of the Solution of the Ideal Model of Chromatography |
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349 | (2) |
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Migration and Evolution of the Band Profile |
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351 | (12) |
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Analytical Solutions of the Ideal Model |
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363 | (14) |
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The Ideal Model in Gas Chromatography |
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377 | (2) |
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Practical Relevance of Results of the Ideal Model |
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379 | (8) |
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Band Profiles of Two Components with the Ideal Model |
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387 | (50) |
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General Principle of the Solution |
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390 | (5) |
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Elution of a Wide Band With Competitive Langmuir Isotherms |
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395 | (6) |
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Elution of a Narrow Band with Competitive Langmuir Isotherms |
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401 | (6) |
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Method of Calculation of the Ideal Model Solution in a Specific Case |
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407 | (7) |
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Dimensionless Plot of a Two-component Band System |
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414 | (2) |
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416 | (3) |
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419 | (2) |
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The Ideal Model in Gas Chromatography |
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421 | (2) |
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Practical Relevance of the Ideal Model |
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423 | (14) |
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436 | (1) |
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Band Profiles in Displacement Chromatography with the Ideal Model |
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437 | (34) |
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Steady State in the Displacement Mode. The Isotachic Train |
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439 | (11) |
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The Theory of Characteristics |
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450 | (11) |
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461 | (6) |
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Practical Relevance of the Results of the Ideal Model |
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467 | (4) |
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468 | (3) |
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Single-Component Profiles with the Equilibrium Dispersive Model |
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471 | (60) |
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Fundamental Basis of the Equilibrium Dispersive Model |
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473 | (3) |
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Approximate Analytical Solutions |
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476 | (16) |
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Numerical Solutions of the Equilibrium--Dispersive Model |
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492 | (17) |
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Results Obtained with the Equilibrium Dispersive Model |
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509 | (22) |
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527 | (4) |
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Two-Component Band Profiles with the Equilibrium--Dispersive Model |
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531 | (38) |
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Numerical Analysis of the Equilibrium--Dispersive Model |
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532 | (10) |
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Applications of the Equilibrium--Dispersive Model |
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542 | (27) |
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567 | (2) |
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Frontal Analysis, Displacement and the Equilibrium--Dispersive Model |
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569 | (36) |
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Displacement Chromatography with a Nonideal Column |
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570 | (17) |
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Applications of Displacement Chromatography |
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587 | (12) |
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Comparison of Calculated and Experimental Results |
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599 | (6) |
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603 | (2) |
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System Peaks with the Equilibrium--Dispersive Model |
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605 | (46) |
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System Peaks in Linear Chromatography |
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606 | (20) |
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High-Concentration System Peaks |
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626 | (25) |
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647 | (4) |
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Kinetic Models and Single-Component Problems |
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651 | (48) |
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Solution of the Breakthrough Curve under Constant Pattern Condition |
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653 | (16) |
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Analytical and Numerical Solutions of the Kinetic Models |
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669 | (11) |
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Comparison Between the Various Kinetic Models |
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680 | (7) |
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Results of Computer Experiments |
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687 | (2) |
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Numerical Solution of the Lumped Pore Diffusion Model |
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689 | (4) |
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The Monte Carlo Model of Nonlinear Chromatography |
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693 | (6) |
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695 | (4) |
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Gradient Elution Chromatography under Nonlinear Conditions |
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699 | (36) |
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Retention Times and Band Profiles in Linear Chromatography |
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701 | (4) |
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Retention of the Organic Modifier or Modulator |
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705 | (6) |
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Numerical Solutions of Nonlinear Gradient Elution |
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711 | (15) |
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Gradient Elution in Ion-Exchange Chromatography |
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726 | (9) |
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731 | (4) |
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Kinetic Models and Multicomponent Problems |
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735 | (44) |
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Analytical Solution for Binary Mixture; Constant Pattern Behavior |
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736 | (11) |
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Linear Driving Force Model Approach |
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747 | (7) |
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Numerical Solution of The General Rate Model of Chromatography |
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754 | (25) |
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775 | (4) |
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Simulated Moving Bed Chromatography |
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779 | (70) |
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780 | (3) |
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Modeling of Simulated Moving Bed (SMB) Separations |
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783 | (2) |
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Analytical Solution of the Linear, Ideal Model of SMB |
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785 | (21) |
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Analytical Solution of the Linear, Nonideal Model of SMB |
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806 | (2) |
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808 | (1) |
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Optimization of the SMB Process |
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809 | (7) |
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Nonlinear, Ideal Model of SMB |
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816 | (10) |
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Recent Improvements in SMB Performance with New Operating Modes |
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826 | (10) |
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Numerical Solutions for Nonlinear, Nonideal SMB |
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836 | (13) |
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845 | (4) |
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Optimization of the Experimental Conditions |
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849 | (90) |
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851 | (6) |
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The Economics of Chromatographic Separations |
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857 | (10) |
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Optimization Based on Theoretical Considerations |
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867 | (16) |
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Optimization Using Numerical Solutions |
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883 | (32) |
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915 | (5) |
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920 | (4) |
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Optimization of the SMB Process |
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924 | (15) |
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|
935 | (4) |
| Glossary of Symbols |
|
939 | (10) |
| Glossary of Terms |
|
949 | (20) |
| Index |
|
969 | |
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