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Molybdenum Disulphide Lubrication


Author(s): Lansdown
ISBN10:  0444500324
ISBN13:  9780444500328
Format:  Hardcover
Pub. Date:  5/28/1999
Publisher(s): Elsevier Science & Technology

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SummaryTable of Contents
In the 1970s and the early 1980s there was an enormous volume of research and development into the subject of molybdenum disulphide lubrication, much of which was supported by national governments for the benefit of defence, aviation or space activities. There were already some well-established practical guidelines for deciding when and how to use molybdenum disulphide, but there was still a considerable lack of universally-accepted theoretical understanding of some of the important and fundamental aspects of molybdenum disulphide technology. However, the state of knowledge was growing rapidly.

In the past fifteen years the situation with regard to the technology of molybdenum disulphide lubrication has stabilised in many respects, and a measure of consensus has been reached about some of the mechanisms involved. The use of molybdenum disulphide has become routine in some industries, and there are many well-established and reputable commercial products available. Except in the high-technology field of physical deposition techniques, especially sputtering, the output of new research publications has fallen from perhaps two hundred a year in the 1970s to fewer than ten a year in the 1990s. In spite of this maturing of the subject, it is clear that there are still many aspects in which disagreements persist about the mechanisms involved, and which as a result are unclear or misunderstood among current, and perhaps even more importantly, potential users.

One of the primary objectives of this book is to analyse the various aspects of molybdenum disulphide lubrication technology about which there are still disagreements or controversy, and to attempt to come to firm conclusions about some of the mechanisms involved. In particular, it will place emphasis on the importance and effects of burnishing and film consolidation.

Preface vii
Contents xi
List of Figures
xv
List of Tables
xxi
History
1(10)
Early Beginnings
1(2)
Recorded History
3(4)
Range of Applications
7(4)
Occurrence and Extraction
11(10)
Occurrence
11(2)
Extraction of Molybdenum Disulphide
13(4)
Extraction of Molybdenum
17(2)
Synthesis of Molybdenum Disulphide
19(2)
Molybdenum and its Compounds
21(10)
Molybdenum
21(3)
Oxides of Molybdenum
24(2)
Sulphides of Molybdenum
26(1)
Other Compounds of Molybdenum
27(1)
Molybdenum Compounds in Lubrication
28(1)
Chemical Uses of Molybdenum
29(2)
Properties of Molybdenum Disulphide
31(16)
Physical Properties
31(3)
Intercalation Compounds
34(1)
Electrical Properties
35(3)
Chemical Properties
38(1)
Effects of Temperature
39(1)
Oxidation
40(3)
Effect of Moisture
43(4)
Mechanism of Lubrication
47(14)
Fundamentals of Friction
47(3)
Friction of Molybdenum Disulphide
50(1)
Effect of Contact Load on Friction
51(5)
Effects of Vapours and Other Contaminants
56(2)
Load-Carrying Capacity
58(1)
Summary
58(3)
Formation of Molybdenum Disulphide Films
61(18)
Film Formation
61(1)
Burnished Films from Powder
62(4)
Burnishing of Soft Films
66(3)
Film Formation by Transfer
69(1)
Structure of Burnished or Run-in Films
69(3)
Effects of the Substrate on Film Formation
72(5)
Effects of Moisture and Other Vapours on Film Formation
77(2)
Properties of Molybdenum Disulphide Films
79(28)
Friction
79(2)
Effects of Moisture and Other Vapours
81(4)
Effects of Temperature
85(3)
Effects of Radiation
88(1)
Effects of Vacuum
89(1)
Effects of Particle Size and Shape
90(2)
Effect of Film Thickness
92(5)
Effects of Sliding Speed
97(2)
Film Life and Mechanism of Failure
99(5)
Effects of Additives
104(3)
Transfer in Lubrication
107(22)
General Phenomenon of Transfer
107(1)
Transfer of Molybdenum Disulphide
108(7)
Applications of Transfer
115(2)
Composition of the Transfer Source
117(3)
Nature and Location of the Transfer Source
120(9)
Lubrication by Molybdenum Disulphide Alone
129(24)
Different Techniques of Use
129(2)
Use in Free Powder Form
131(3)
Dispersions
134(2)
Compacts
136(2)
In-Situ Formation
138(10)
Burnished Films
148(5)
Sputtering and Other Physical Deposition Processes
153(26)
The Sputtering Process
153(3)
Effects of Sputtering Variables on Film Structure
156(5)
Effect of Substrate
161(2)
Structure of the Sputtered Coating
163(5)
Performance of Sputtered Coatings
168(3)
Effects of Co-Sputtering
171(3)
Effects of Ion Bombardment
174(2)
Pulsed Laser Deposition
176(3)
Bonded Films
179(28)
Types of Bonded Film
179(7)
Other Components of Bonded Films
186(1)
Substrate Preparation and Pre-Treatment
187(5)
Application of the Bonded Film
192(3)
Curing the Film
195(1)
Plasma Spraying
195(1)
Friction and Wear Properties of Bonded Films
196(8)
Repair and Renewal of Films
204(3)
Composites
207(38)
Lubricating Composites
207(1)
Polymer Composites
208(18)
Metallic Composites
226(7)
Ceramic and Inorganic Composites
233(2)
Transfer Lubrication of Rolling Bearings
235(4)
Electrical Brushes and Sliprings
239(6)
Use in Oils and Greases
245(38)
Interaction Between Molybdenum Disulphide and Liquids
245(10)
Use in Lubricating Oils
255(10)
Molybdenum Disulphide in Greases
265(10)
Pastes and Dispersions
275(8)
Other Lamellar Solid Lubricants
283(22)
Occurrence and Properties
283(1)
Intercalation
284(3)
Graphite
287(4)
Graphite Fluoride
291(3)
Transition Metal Dichalcogenides
294(11)
Corrosion and Fretting
305(8)
Background
305(2)
The Chemical Environment
307(1)
Corrosion Protection
308(2)
Fretting
310(3)
Selection and Use
313(16)
Selecting the Class of Lubricant
313(6)
Selecting the Type of Solid Lubricant
319(2)
Use of Molybdenum Disulphide
321(8)
References 329(36)
Subject Index 365

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