| Preface |
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i | |
| General Introduction |
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xii | |
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Surface Phenomena and the Structure of Interfaces in One-Component Systems |
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1 | (63) |
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Introduction to the Thermodynamics of the Discontinuity Surface in a Single Component System |
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2 | (11) |
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The Surface Energy and Intennolecular Interactions in Condensed Phases |
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13 | (18) |
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The Effect of the Interfacial Curvature on the Equilibrium in a Single Component System |
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31 | (13) |
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31 | (9) |
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40 | (4) |
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Methods Used for the Determination of the Specific Surface Free Energy |
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44 | (20) |
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59 | (2) |
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61 | (3) |
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The Adsorption Phenomena. Structure and Properties of Adsorption Layers at the Liquid-Gas Interface |
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64 | (101) |
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Principles of Adsorption Thermodynamics. The Gibbs Equation |
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65 | (19) |
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Structure and Properties of the Adsorption Layers at the Air-Water Interface |
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84 | (47) |
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The Dilute Adsorption Layers |
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84 | (13) |
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Langmuir and Szyszkowski Equations. Accounting for the Adsorbed Molecules Own Size (Mutual Repulsion) |
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97 | (15) |
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Structure and Properties of Saturated Adsorption Layers |
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112 | (19) |
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Classification of Surface Active Substances. The Assortment of Synthetic Surfactants |
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131 | (13) |
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Analytical Chemistry of Surfactants |
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144 | (21) |
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160 | (2) |
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162 | (3) |
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Interfaces Between Condensed Phases. Wetting |
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165 | (95) |
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The Interfaces Between Condensed Phases in Two-component Systems |
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166 | (10) |
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Adsorption at Interfaces Between Condensed Phases |
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176 | (17) |
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Adsorption of Ions. The Electrical Double Layer (EDL) |
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193 | (32) |
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Basic Theoretical Concepts of the Structure of Electrical Double Layer |
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194 | (20) |
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214 | (6) |
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Electrocapillary Phenomena |
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220 | (5) |
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225 | (19) |
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Controlling Wetting and Selective Wetting by Surfactants |
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244 | (6) |
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250 | (10) |
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255 | (2) |
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257 | (3) |
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The Formation of Disperse Systems |
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260 | (60) |
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Thermodynamics of Disperse Systems: the Basics |
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261 | (12) |
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Thermodynamic Principles of the Formation of New Phase Nuclei |
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273 | (16) |
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General Principles of Homogeneous Nucleation According to Gibbs and Volmer |
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273 | (6) |
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Condensation of the Supersaturated Vapor |
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279 | (1) |
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Crystallization (Condensation) from Solution |
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280 | (1) |
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280 | (2) |
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Crystallization from Melt |
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282 | (2) |
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Heterogeneous Formation of a New Phase |
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284 | (5) |
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Kinetics of Nucleation in a Metastable System |
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289 | (6) |
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The Growth Rate of Particles of a New Phase |
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295 | (5) |
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The Formation of Disperse Systems by Condensation |
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300 | (11) |
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Ultradisperse Systems. Supramolecular Chemistry |
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311 | (2) |
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Dispersion Processes in Nature and Technology |
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313 | (7) |
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316 | (2) |
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318 | (2) |
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Transfer Processes in Disperse Systems |
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320 | (141) |
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Concepts of Non-Equilibrium Thermodynamics as Applied to Transfer Processes in Disperse Systems. General Principles of the Theory of Percolations |
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321 | (6) |
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The Molecular-Kinetic Properties of Disperse Systems |
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327 | (22) |
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Sedimentation in Disperse Systems |
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329 | (1) |
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Diffusion in Colloidal Systems |
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329 | (4) |
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Equilibrium Between Sedimentation and Diffusion |
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333 | (4) |
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Brownian Motion and Fluctuations in the Concentration of Disperse Phase Particles |
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337 | (12) |
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General Description of Electrokinetic Phenomena |
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349 | (12) |
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Transfer Processes in Free Disperse Systems |
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361 | (12) |
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Transfer Processes in Structured Disperse Systems (in Porous Diaphragms and Membranes) |
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373 | (17) |
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Optical Properties of Disperse Systems: Transfer of Radiation |
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390 | (18) |
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Light Scattering by Small Particles (Rayleigh Scattering) |
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390 | (12) |
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Optical Properties of Disperse Systems Containing Larger Particles |
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402 | (6) |
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Transfer of Ultrasonic Waves in Disperse Systems. Acoustic and Electroacoustic Phenomena |
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408 | (13) |
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Theoretical Principles of Ultrasound Propagation Through Disperse Systems (Acoustics) |
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409 | (8) |
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Electroacoustic Phenomena |
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417 | (4) |
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Methods of Particle Size Analysis |
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421 | (40) |
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426 | (5) |
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Sedimentation Analysis in the Centrifugal Force Field |
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431 | (4) |
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Nephelometry, Ultramicroscopy |
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435 | (3) |
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Light Scattering by Concentration Fluctuations |
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438 | (4) |
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Photon Correlation Spectroscopy (Dynamic Light Scattering) |
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442 | (10) |
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Particle Size Analysis by Acoustic Spectroscopy |
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452 | (2) |
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454 | (2) |
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456 | (5) |
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Lyophilic Colloidal Systems |
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461 | (45) |
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The Conditions of Formation and Thermodynamic Stability of Lyophilic Colloidal Systems |
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462 | (6) |
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Critical Emulsions as Lyophilic Colloidal Systems |
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468 | (4) |
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Micellization in Surfactant Solutions |
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472 | (15) |
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Thermodynamics of Micellization |
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476 | (7) |
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Concentrated Dispersions of Micelle-Forming Surfactants |
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483 | (3) |
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Formation of Micelles in Non-Aqueous Systems |
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486 | (1) |
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Solubilization in Solutions of Micelle-Forming Surfactants. Microemulsions |
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487 | (11) |
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Lyophilic Colloidal Systems in Polymer Dispersions |
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498 | (8) |
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502 | (2) |
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504 | (2) |
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General Causes for Degradation and Relative Stability of Lyophobic Colloidal Systems |
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506 | (77) |
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The Stability of Disperse Systems with Respect to Sedimentation and Aggregation. Role of Brownian Motion |
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507 | (14) |
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Molecular Interactions in Disperse Systems |
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521 | (15) |
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Factors Governing the Colloid Stability |
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536 | (7) |
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Electrostatic Component of Disjoining Pressure and its Role in Colloid Stability. Principles of DLVO Theory |
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543 | (13) |
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Structural-Mechanical Barrier |
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556 | (5) |
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561 | (10) |
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The Influence of Isothermal Mass Transfer (Ostwald Ripening) on the Decrease in Degree of Dispersion |
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571 | (12) |
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577 | (3) |
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580 | (3) |
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Structure, Stability and Degradation of Various Lyophobic Disperse Systems |
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583 | (66) |
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584 | (12) |
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596 | (11) |
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Emulsions and Emulsion Films |
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607 | (17) |
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624 | (5) |
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Coagulation of Hydrophobic Sols by Electrolytes |
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629 | (7) |
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Detergency. Microencapsulation |
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636 | (5) |
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Systems with Solid Dispersion Medium |
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641 | (8) |
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642 | (4) |
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646 | (3) |
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Principles of Physical-Chemical Mechanics |
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649 | (84) |
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Description of Mechanical Properties of Solids and Liquids |
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651 | (14) |
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Structure Formation in Disperse Systems |
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665 | (24) |
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Rheological Properties of Disperse Systems |
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689 | (13) |
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Physico-Chemical Phenomena in Processes of Deformation and Fracture of Solids. The Rehbinder Effect |
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702 | (31) |
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The Role of Chemical Nature of the Solid and the Medium in the Adsorption-Caused Decrease of Material Strength |
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705 | (10) |
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The Role of External Conditions and the Structure of Solid in the Effects of Adsorption Action on Mechanical Properties of Solids |
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715 | (8) |
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The Application of Rehbinder's Effect |
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723 | (5) |
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728 | (3) |
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|
731 | (2) |
| Subject Index |
|
733 | |
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