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Applied Mineralogy in the Mining Industry,9780444500779
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Applied Mineralogy in the Mining Industry


Author(s): Petruk
ISBN10:  0444500774
ISBN13:  9780444500779
Format:  Hardcover
Pub. Date:  11/29/2000
Publisher(s): Elsevier Science & Technology

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SummaryTable of Contents
Techniques of performing applied mineralogy investigations, and applications and capabilities of recently developed instruments for measuring mineral properties are explored in this book intended for practicing applied mineralogists, students in mineralogy and metallurgy, and mineral processing engineers.
The benefits of applied mineralogy are presented by using in-depth applied mineralogy studies on base metal ores, gold ores, porphyry copper ores, iron ores and industrial minerals as examples. The chapter on base metal ores includes a discussion on the effects of liberation, particle sizes and surfaces coatings of Pb, Cu, Fe, Ca and So4- on the recoveries of sphalerite, galena and chalcopyrite. The chapter on gold discusses various methods of determining the quantities of gold in different minerals, including 'invisible' gold in pyrite and arsenopyrite, so that a balance of the distribution of gold among the minerals can be calculated. This book also discusses the roles of pyrite, oxygen, moisture and bacterial (thiobacillus ferrooxidans) on reactions that produce acidic drainage from tailings piles, and summarizes currently used and proposed methods of remediation of acidic drainage.
Preface v
Acknowledgements viii
Credits ix
Table of Contents
x
General Principles of Applied Mineralogy
Introduction
1(1)
Applied Mineralogy Investigations
2(25)
Identifying minerals and determining mineral compositions
3(1)
Base metal ores
3(1)
Main minerals of economic value and gangue
4(1)
Silver minerals
4(1)
Sphalerite
4(1)
Gold
4(1)
Tin and indium minerals
5(1)
Secondary copper minerals
5(1)
Anglesite (PbSO4)
5(1)
Deleterious elements
5(1)
Minerals in greisen-type tin-tungsten deposits
6(1)
Minerals in porphyry-copper ores
7(1)
Minerals in iron ores
7(1)
Quantities of minerals
8(1)
Size distribution
9(1)
Predicting grind
9(2)
Ground or powdered materials
11(1)
Mineral liberations
12(4)
Stereological corrections
16(4)
Measurements of mineral liberations in sieved fractions and unsieved samples
20(2)
Discussion
22(1)
Textures
23(1)
Mineral associations
24(1)
Binary mineral technique
24(1)
Dominant mineral technique
24(1)
Average composition of average particle
24(1)
Proportion of mineral in contact with other minerals
25(1)
Surface coatings on particles
25(1)
Search for rare minerals
25(2)
Instruments for Performing Applied Mineralogy Studies
Introduction
27(1)
Optical Microscopes
28(1)
X-Ray Diffractometer
29(2)
Scanning Electron Microscope (SEM) with Energy Dispersive X-Ray Analyser (EDS)
31(3)
Low-vacuum SEM
34(1)
Electron Microprobe (MP)
34(2)
Proton Induced X-Ray Emission (PIXE)
36(1)
Secondary Ion Mass Spectrometer (SIMS) and (ToF-SIMS)
37(1)
Laser Ionization Mass Spectrometer (LIMS) and ToF-LIMS
38(1)
Cathodoluminescence (CL)
39(4)
Infrared Spectroscopy
43(1)
Image Analysis System
43(8)
Optical microscope
44(1)
Scanning electron microscope (SEM) or microprobe (MP)
45(1)
Discrimination by grey levels (grey level images)
45(1)
Discrimination by mineral compositions (several minerals with same grey levels)
46(1)
QEM-SEM
47(1)
Enhancement
47(1)
Preparing binary images of minerals for measurement
47(1)
Mineral quantities
48(1)
Size distributions of minerals
48(1)
Grain shapes and grain boundary irregularities
49(1)
Liberations of minerals
49(1)
Mineral associations
49(1)
Applications of image analysis to on-line control
49(2)
Mineralogical Characteristics and Processing of Massive Sulfide Base Metal Ores from the Bathurst-Newcastle Mining Area
Introduction
51(1)
General Characteristics of Bathurst-Newcastle Base Metal Deposits
51(6)
Mineralogical characteristics
52(1)
Pyrite
52(1)
Sphalerite
52(1)
Galena
53(1)
Chalcopyrite
54(1)
Silver
55(1)
Gold
56(1)
Trace minerals
57(1)
Applied Mineralogy Studies of Brunswick No. 12 and Brunswick No. 6 Ores
57(7)
Size distributions and mineral liberations
58(5)
Texture Analysis
63(1)
Applied Mineralogy Studies of Products from the Cu-Pb Rougher Circuit in BMS Concentrator
64(6)
Sphalerite
65(1)
Pyrite
66(1)
Galena
66(4)
Summary
70(3)
Volcanogenic Base Metal Deposits in the Flin Flon-Snow Lake Areas, Manitoba, Canada
Introduction
73(1)
Characteristics of Trout Lake and Callinan Ores
73(12)
Trout Lake ores
77(1)
Massive sphalerite (MS) ore type
77(1)
Banded pyrite + sphalerite (BP+S) ore type
77(1)
Massive pyrite (MP) ore type
77(1)
Mixed/banded chalcopyrite + sphalerite (M/BC+S) ore type
78(1)
Sheared chalcopyrite + sphalerite (SC+S) ore type
79(1)
Massive chalcopyrite + pyrrhotite (MC+P) ore type
79(2)
Vein quartz and chalcopyrite (VQ+C) ore type
81(1)
Chalcopyrite stringer (CS) ore type
81(1)
Disseminated pyrite and chalcopyrite (DP+C) ore type
81(1)
Callinan ore types
82(1)
Pyrite ore type
82(1)
Sheared pyrite ore
82(1)
Pyrrhotite ore type
83(1)
Sheared pyrrhotite ore type
83(2)
Minerals in Trout Lake and Callinan Ores
85(5)
Pyrite (FeS2)
85(1)
Pyrrhotite (Fe(1-x)S)
85(2)
Chalcopyrite (CuFeS2)
87(1)
Sphalerite (ZnS)
88(1)
Galena (PbS)
88(1)
Au-Ag-Hg alloy
88(1)
Other Minerals
89(1)
Mineral Processing
90(9)
Cu concentrate
91(1)
Chalcopyrite
91(4)
Sphalerite
95(1)
Pyrite
95(1)
Gold
95(1)
Silver
96(1)
Galena
97(1)
Tellurium
97(1)
Selenium and antimony
97(1)
Zn concentrate
98(1)
Sphalerite
98(1)
Summary and Conclusions
99(4)
Relationships Between Mineral Characteristics and Flotability
Introduction
103(1)
Flotability of Chalcopyrite-Bearing Particles
103(4)
Chalcopyrite in a base metal ore
103(1)
Conclusionsn
104(1)
Test tube flotation test
104(1)
Conclusions
105(1)
Characteristics of chalcopyrite in cleaner flotation tails of a commercial concentrator
105(2)
Nickel in Serpentinized Ore
107(4)
Conclusions
109(2)
Applied Mineralogy Related to Gold
Introduction
111(1)
Mineralogy
111(2)
Textures and Microstructures
113(5)
Gold in fractures and microfractures in rocks, and in veinlets and microveinlets in minerals
113(2)
Gold in interstitial spaces between mineral grains and at borders of mineral grains
115(1)
Encapsulated gold in a host mineral
115(1)
Submicroscopic gold associated with framboidal pyrite
115(3)
Submicroscopic gold associated with very fine-grained clay minerals
118(1)
Gold in oxidized zones
118(1)
Types of Gold Deposits
118(4)
Gold in shear zones
119(1)
Gold in Carlin-type deposits
119(1)
Gold in volcanogenic massive sulfide base metal deposits
120(1)
Gold associated with prophyry copper deposits
121(1)
Gold in conglomerate (Witwatersrand-type) deposits
121(1)
`invisible' gold
121(1)
Characterizing Gold Ore with Respect to Processing
122(4)
Selecting samples and fractions for analysis
122(1)
Assaying the sample and fractions
123(1)
Identifying the minerals
123(1)
Determining mineral contents
123(1)
Proportion of exposed and encapsulated gold in each sieved fraction
124(1)
Amount of cyanidable gold
124(1)
Diagnostic leaching
125(1)
`Invisible' gold (microbeam analysis and staining)
125(1)
Calculating mineral balance for gold among different minerals
126(1)
Processing Gold Ores
126(6)
Leaching (Cyanidation)
126(1)
Refractory gold ores
127(1)
Roasting
127(1)
Pressure leaching
128(1)
Bioleaching
128(1)
Flotation
128(1)
Gravitational techniques
129(1)
Heap Leaching
129(1)
Vein type deposits
130(1)
Carlin-type deposits
130(1)
Volcanogenic massive sulfide base metal deposits
131(1)
Porphyry copper deposits
131(1)
Bioleaching
131(1)
Selected Examples of Characterizing Gold Tailings
132(3)
Gold in tailings from David Bell circuit, Teck-Corona, Hemlo, Ontario
132(1)
Gold tailings, Nor Acme Mine, Snow Lake, Manitoba
132(3)
Applied Mineralogy: Porphyry Copper Deposits
Introduction
135(1)
Characteristics of Porphyry Copper Deposits
135(9)
Primary ore minerals
136(1)
Vein density
136(1)
Silicification
136(1)
Alteration
137(1)
Potassic alteration
138(1)
Phyllic alteration
138(1)
Argillic alteration
139(1)
Propylitic alteration
139(1)
Distribution of other minerals
139(1)
Hypogene and alteration non-metallic minerals
140(1)
Maturity
140(1)
Role of sulfur
141(1)
Depth of porphyry copper system
141(1)
Supergene mineralization
142(1)
Mineralogy of cap
142(1)
Mineralogy of blanket zone
143(1)
Applied Mineralogy Related to Mineral Processing
144(2)
Mineralogical characterization of intensely oxidized ores
144(1)
Mineralogical characterization of partly oxidized ores
144(1)
Mineralogical characterization of primary ores
145(1)
Identifying Minerals
146(3)
Mineralogical Characteristics and Processing of Iron Ores
Introduction
149(1)
Iron Ores in the Labrador Trough
149(27)
Characteristics of the ores
149(1)
Ores of the Iron Ore Company of Canada (IOC), Labrador City, Newfoundland
150(1)
Ores in the Wabush deposits
150(1)
Ores in the Mount Wright deposits
150(1)
Mineralogy
150(1)
Hematite (Fe2O3)
151(1)
Magnetite (Fe3O4)
151(1)
Martite
151(1)
Goethite (FeO(OH)
151(2)
Limonite
153(1)
Mn Minerals
154(1)
Pyrolusite (MnO2)
154(1)
Psilomelane (Mn oxide with 40 to 50 wt % Mn)
154(1)
Wad (Mn oxide with 18 to 22 wt % Mn)
154(1)
Ankerite and Siderite
154(1)
Mining
155(1)
Mineral Processing
155(1)
A case history: determining mineral characteristics that affect mineral processing of IOC ores
155(1)
Mineral characteristics of ore and concentrator products
156(4)
Pilot plant tests and mineralogical characteristics of products
160(5)
Modifications to IOC plant
165(1)
Mineralogical characteristics of ore from the Wabush Deposits
166(6)
Mineralogical Characteristics of ore from the Mount Wright deposits and evaluation of QCM concentrator
172(4)
Oolitic iron ore in the Peace River Deposit
176(4)
Mineralogical characteristics of the Peace River iron deposits
176(3)
Laboratory mineral processing tests
179(1)
Summary
180(5)
Carol Lake ores
180(1)
Wabush ore
181(1)
Mount Wright ores
182(1)
Minette-type Peace River ironstone
182(3)
Applied Mineralogy Investigations of Industrial Minerals
Introduction
185(1)
Graphite
186(4)
A case history of characterizing a graphite ore
186(1)
Method of Analysis
187(1)
Results
187(2)
Interpretation of Results
189(1)
Recommendations
190(1)
Beneficiation improvement
190(1)
TALC
190(2)
Applied Mineralogy in exploration
190(1)
Applied Mineralogy related to mineral processing
191(1)
Applied mineralogy in quality control of cosmetic products
192(1)
Wollastonite
192(2)
A case history of characterizing a wollastonite ore
193(1)
Garnet
194(1)
Mineralogical study of a garnet deposit
195(1)
Quartz
195(3)
Mineralogical study of quartz
196(1)
Characterizing quartz with respect to manufacturing silicon and ferrosilicon
197(1)
Method of Characterizing Airborne Dusts
198(3)
Applied Mineralogy to Tailings and Waste Rock Piles - Sulfide Oxidation Reactions and Remediation of Acidic Water Drainage
Introduction
201(1)
General Characteristics of Tailings and Waste Rock Piles
202(2)
Mineralogical Studies of Tailings and Waste Rock Piles
204(2)
Objective
204(1)
Sampling and method of analysis
204(2)
Minerals
206(1)
Reactions in Tailings Piles
206(12)
Oxidation of sulfide minerals
206(2)
Pyrite
208(1)
Pyrrhotite
209(1)
Dissolution of Carbonate minerals
210(1)
Dissolution of aluminum hydroxides, aluminosilicates and silicates
210(2)
Precipitation of secondary minerals
212(1)
Soluble iron sulfates
212(1)
Melanterite (Fe2+SO47H2O))
212(1)
rozenite (Fe2+SO4.4H2O)
212(1)
siderotil (Fe2+SO4.5H2O)
212(1)
Less soluble sulfate minerals
213(1)
Insoluble ferric oxhydroxides and sulfates
213(1)
Goethite (α-FeO(OH)
213(1)
Lepidocrocite (γ-FeO(OH)
213(1)
Ferrihydrite (Fe2O3.9H2O)
213(1)
Schwertmannite (Fe8O8SO4 (OH)6)
213(1)
Jarosite (KFe3(SO4)2(OH)6)
213(1)
Precipitation of arsenic-bearing minerals
214(1)
Scorodite (Fe3+AsO4.2H2O)
214(1)
Mansfieldite (AlAsO4.2H1O)
214(1)
Beudantite (PbFe3+ 3(AsO4)(SO4)(OH)6)
214(1)
Precipitation of phosphates
214(1)
Predicting secondary minerals
215(1)
Correlating pH, pore water concentrations, rock chemistry and mineralogy in tailings piles
216(1)
pH in site O tailings pile
216(1)
primary minerals in site O tailings pile
216(1)
Pore water chemistry in site O tailings pile
216(2)
Secondary minerals in site O tailings pile
218(1)
Remediation and Prevention of Acidic Drainage from Mine Wastes
218(5)
Treatment of acidic water
219(1)
On-site treatment facilities
219(1)
Continuous flow reactors
219(1)
Downstream wetlands
219(1)
Infiltration controls
220(1)
Sulfide oxidation controls (Tailings Management Programs)
220(1)
Restricting entrance of oxygen
221(1)
Disposal of tailings into deep lakes
221(1)
A water pond established above tailings behind retention dams
221(1)
A bog on the tailings surface
221(1)
Oxygen-consuming covers
221(1)
Dry covers
222(1)
Enhanced sulfate reduction
222(1)
Thickened slurry with moisture retaining capabilities
222(1)
Precipitates that coat sulfide mineral surfaces
222(1)
precipitation of heavy metals in reservoir minerals
223(1)
Bactericidal controls
223(1)
Cemented ``hardpan'' layers
223(1)
Separating sulfide minerals from gangue minerals
223(1)
Summary
223(4)
References 227(32)
Subject Index 259(6)
Mineral Index 265

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