Organic Synthesis: The Disconnection Approach: Warren, Stuart G.: 9780471101604: Book: : eCampus.com

Introduction

The Disconnection Approach

(5)

Basic Principles: Synthesis of Aromatic Compounds

(10)

Strategy I: The Order of Events

(10)

One-Group C-X Disconnections

(8)

Strategy II: Chemoselectivity

(7)

Two-Group C-X Disconnections

(10)

Strategy III: Reversal of Polarity, Cyclisation Reactions, Summary of Strategy

(9)

Amine Synthesis

(6)

Strategy IV: Protecting Groups

(9)

One-Group C-C Disconnections I: Alcohols

(11)

General Strategy A: Choosing a Disconnection

(7)

Strategy V: Stereoselectivity A

(13)

One-Group C-C Disconnections II: Carbonyl Compounds

106

(8)

Strategy VI: Regioselectivity

114

(5)

Alkene Synthesis

119

(7)

Strategy VII: Use of Acetylenes

126

(6)

Two-Group Disconnections I: Diels-Alder Reactions

132

(8)

Strategy VIII: Introduction to Carbonyl Condensations

140

(4)

Two-Group Disconnections II: 1,3-Difunctionalised Compounds and α,β-unsaturated Carbonyl Compounds

144

(8)

Strategy IX: Control in Carbonyl Condensations

152

(18)

Two-Group Disconnections III: 1,5-Difunctionalised Compounds, Michael Addition and Robinson Annelation

170

(9)

Strategy X: Use of Aliphatic Nitro Compounds in Synthesis

179

(6)

Two-Group Disconnections IV: 1,2-Difunctionalised Compounds

185

(12)

Strategy XI: Radical Reactions in Synthesis. FGA and its Reverse

197

(12)

Two-Group Disconnections V: 1,4-Difunctionalised Compounds

209

(8)

Strategy XII: Reconnections

217

(6)

Two-Group Disconnections VI: 1,6-Difunctionalised Compounds

223

(6)

General Strategy B: Strategy of Carbonyl Disconnections

229

(11)

Strategy XIII: Introduction to Ring Synthesis. Saturated Heterocycles

240

(11)

Three-Membered Rings

251

(8)

Strategy XIV: Rearrangements in Synthesis

259

(9)

Four-Membered Rings: Photochemistry in Synthesis

268

(6)

Strategy XV: Use of Ketenes in Synthesis

274

(4)

Five-Membered Rings

278

(5)

Strategy XVI: Pericyclic Rearrangements in Synthesis Special Methods for Five-Membered Rings

283

(9)

Six-Membered Rings

292

(9)

General Strategy C: Strategy of Ring Synthesis

301

(13)

Strategy XVII: Stereoselectivity B

314

(12)

Aromatic Heterocycles

326

(20)

General Strategy D: Advanced Strategy

346

(20)

General References

366

(1)

References

367

(14)

Index

381


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