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Nitrenes and Nitrenium Ions



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This is the edition with a publication date of 5/13/2013.

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Featuring contributions respected leaders in the field, Nitrene and Nitrenium Ions is the first comprehensive book to explore the role of reactive intermediate nitrene and nitrenium ions in chemistry and biochemistry. Covering a broad range of topics, including ultrafast studies, computational studies, behavior in aqueous solution, electronic structures, and reactions with aromatic compounds, this valuable resource will empower graduate students and researchers to better understand and expand their synthetic utility.

Author Biography

DANIEL E. FALVEY, PhD, is Professor at the University of Maryland. His research focuses on reaction mechanisms and reactive intermediates, with an emphasis on the exploration of intermediates that play a role in biochemical processes. Dr. Falvey has been awarded the Merck Award and the Reynold C. Fuson Memorial Award in Chemistry. Acclaimed for his teaching abilities, he has received the Outstanding Teacher Award from the Center for Teaching Excellence.

ANNA D. GUDMUNDSDOTTIR, PhD, is Professor of Chemistry at the University of Cincinnati. Dr. Gudmundsdottir's studies photo-removeable protecting groups, reactive intermediates, and polymer modification. Her research team elucidated the reactivity of triplet alkyl and vinyl nitrenes in solution and solid state using transient spectroscopy and matrix isolation. Among her many honors, Dr. Gudmundsdottir is a recipient of the NSF CAREER Award.

Table of Contents




Chapter 1.   Ultrafast Studies of Azides and Nitrenes
Jin Wang, Matthew S. Platz, The Ohio State University, Ohio, Gotard Burdzinski, Adam Mickiewicz University Poland

Chapter 2.   Computational Studies of Nitrenes and their Excited State Precursors
Subham Vyas, Arthur H. Winter, Christopher M. Haddad, The Ohio State University, Ohio 

Chapter 3. Nitrenium Ions in Photoaffinity Labeling
R. Marshall Wilson, Valentyna Voskresenska Bowling Green State University, Ohio

Chapter 4. Nitrenium Ions in Aquoeous Solution
Mike Novak, Yue-Ting Wang Miami University, Ohio 

Chapter 5 Triplet Alkylnitrenes
Sivaramakrishnan Muthukrishnan,  Ranaweera A. A. U. Ranaweera, Anna D. Gudmundsdottir, University of Cincinnati, Ohio

Chapter 6. Electronic Structures of Nitrenium Ions
Dan Falvey,  University of Maryland, Maryland

Chapter 7. Raman Studies of Nitrenium Ions
David Lee Phillips,  University of Hong Kong, Hong Kong

Chapter 8. Matrix Studies of Heterocyclic Nitrenes
Curt Wentrup University of Queensland, Australia 

Chapter 9. Dehydroaromatic Nitrenes
Dirk Grote Wolfram Sander, Ruhr-Universität Bochum, Germany

Chapter 10. Synthetic Applications of Nitrenium Ions
Duncan Wardrop, University of Illinois-Chicago, Illinois

Chapter 11. Flourinated Nitrene Precursors
Elisa Leyva,  Denisse de Loera Socorro Leyva Jimenez-Catano, Univ. Autonoma San Luis Potosi, San Luis Potosi, Mexico

Chapter 12. Acylnitrenes
Nina Gritsan,  Institute of Chemical Kinetics and Combustion Novosibirsk, Russia 


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