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Organic Chemistry I as a Second LanguageTM: Translating the Basic Concepts, 2nd Edition
by David R. Klein (Johns Hopkins Univ. )ISBN13:
9780470129296
ISBN10:
0470129298
Format:
Paperback
Pub. Date:
6/1/2007
Publisher(s):
WILEY
List Price: $50.67
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Related Products
Organic Chemistry I As a Second Language: First Semester Topics, 3rd Edition
Organic Chemistry I as a Second Language: Translating the Basic Concepts
Summary
Get a Better Grade in Organic Chemistry Organic Chemistry may be challenging, but that doesn't mean you can't get the grade you want. With David Klein's Organic Chemistry as a Second Language: Translating the Basic Concepts, you'll be able to better understand fundamental principles, solve problems, and focus on what you need to know to succeed. Here's how you can get a better grade in Organic Chemistry: Understand the Big Picture. Organic Chemistry as a Second Language points out the major principles in Organic Chemistry and explains why they are relevant to the rest of the course. By putting these principles together, you'll have a coherent framework that will help you better understand your textbook. Study More Efficiently and Effectively Organic Chemistry as a Second Language provides time-saving study tips and a clear roadmap for your studies that will help you to focus your efforts. Improve Your Problem-Solving Skills Organic Chemistry as a Second Language will help you develop the skills you need to solve a variety of problem types-even unfamiliar ones! Need Help in Your Second Semester? Get Klein's Organic Chemistry II as a Second Language! 978-0-471-73808-5
Table of Contents
| Introduction | |
| Bond-Line Drawings | |
| How to Read Bond-Line Drawings | |
| How to Draw Bond-Line Drawings | |
| Mistakes to Avoid | |
| More Exercises | |
| Identifying Formal Charges | |
| Finding Lone Pairs That Are Not Drawn | |
| Resonance | |
| What Is Resonance? | |
| Curved Arrows: The Tools for Drawing Resonance Structures | |
| The Two Commandments | |
| Drawing Good Arrows | |
| Formal Charges in Resonance Structures | |
| Drawing Resonance Structures--Step by Step | |
| Drawing Resonance Structures--By Recognizing Patterns | |
| A Lone Pair Next to a Pi Bond | |
| A Lone Pair Next to a Positive Charge | |
| A Pi Bond Next to a Positive Charge | |
| A Pi Bond Between Two Atoms, Where One of Those Atoms Is Electronegative (N, O, etc.) | |
| Pi Bonds Going All the Way Around a Ring | |
| Assessing the Relative Importance of Resonance Structures | |
| Acid-Base Reactions | |
| Factor 1--What Atom Is the Charge on? | |
| Factor 2--Resonance | |
| Factor 3--Induction | |
| Factor 4--Orbitals | |
| Ranking the Four Factors | |
| Quantitative Measurement (pKa values) | |
| Predicting the Position of Equilibrium | |
| Showing a Mechanism | |
| Geometry | |
| Orbitals and Hybridization States | |
| Geometry | |
| Nomenclature | |
| Functional Group | |
| Unsaturation | |
| Naming the Parent Chain | |
| Naming Substituents | |
| Stereoisomerism | |
| Numbering | |
| Common Names | |
| Going from a Name to a Structure | |
| Conformations | |
| How to Draw a Newman Projection | |
| Ranking the Stability of Newman Projections | |
| Drawing Chair Conformations | |
| Placing Groups on the Chair | |
| Ring Flipping | |
| Comparing the Stability of Chairs | |
| Don't Be Confused by the Nomenclature | |
| Configurations | |
| Locating Stereocenters | |
| Determining the Configuration of a Stereocenter | |
| Nomenclature | |
| Drawing Enantiomers | |
| Diastereomers | |
| Meso Compounds | |
| Drawing Fischer Projections | |
| Optical Activity | |
| Mechanisms | |
| Curved Arrows | |
| Arro w Pushing | |
| Drawing Intermediates | |
| Nucleophiles and Electrophiles | |
| Bases Versus Nucleophiles | |
| The Regiochemistry Is Contained Within the Mechanism | |
| The Stereochemistry Is Contained Within the Mechanism | |
| A List of Mechanisms | |
| Substitution Reactions | |
| The Mechanisms | |
| Factor 1--The Electrophile (Substrate) | |
| Factor 2--The Nucleophile | |
| Factor 3--The Leaving Group | |
| Factor 4--The Solvent | |
| Using All Four Factors | |
| Substitution Reactions Teach Us Some Important Lessons | |
| Elimination Reactions | |
| Mechanisms (E1 and E2) | |
| Factor 1--The Substrate | |
| Factor 2--The Base | |
| Factor 3--The Leaving Group | |
| Factor 4--Solvent Effects | |
| Using All of the Factors | |
| Elimination Reactions--Regiochemistry and Stereochemistry | |
| Addition Reactions | |
| Terminology Describing Regiochemistry | |
| Terminology Describing Stereochemistry | |
| Adding H and H | |
| Adding H and X, Markovnikov | |
| Adding H and Br, Anti-Markovnikov | |
| Adding H and OH, Markovnikov | |
| Adding H and OH, Anti-Markovnikov | |
| Synthesis Techniques | |
| Adding Br and Br; Adding Br and OH | |
| Adding OH and OH, Anti | |
| Adding OH and OH, Syn | |
| Oxidati ve Cleavage of an Alkene | |
| Predicting Products | |
| General Tips for Predicting Products | |
| Getting Practice | |
| Substitution Versus Elimination Reactions | |
| Looking Forward | |
| Synthesis | |
| One-step Syntheses | |
| Multistep Syntheses | |
| Retrosynthetic Analysis | |
| Creating Your Own Problems | |
| Answer Key | |
| Index | |
| Table of Contents provided by Publisher. All Rights Reserved. |
