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VIRENDER K. SHARMA received his Ph.D. in?Marine and Atmospheric Chemistry at the Florida Insitute of Technology after graduating from the Indian Institute of Technology in New Delhi, India with the Master in Technology.?He?is?currently?Professor of Chemistry at F.I.T. He was a visiting research scholar at Stanford University under the advisory of Professor Ed Solomon and won both the?ACS Faculty of the Year award in 2008 and the?Orlando Section Outstanding Chemist Award.?His research interests include the study of kinetics and mechanisms of oxidations by transition metals in higher oxidation states in aqueous solution, development of innovative and effective methods for reducing the level of contaminants in the aquatic environment, and the physical chemistry of natural waters.
GOESTER KLINGELHOEFER is a professor?of inorganic and analytical chemistry and the University of Mainz, Germany.
TETSUAKI NISHIDA is professor of chemistry at?Kinki University, Japan.
Preface
Chapter 1 In-Situ Mössbauer Spectroscopy with Synchrotron Radiation on Thin Films
S Stankov, T Ślęzak, M Zając, M Ślęzak, M Sladecek, R Röhlsberger, B. Sepiol, G Vogl, N Spiridis, J Łażewski, K Parliński, and J Korecki
1 1 Introduction
1.2 Instrumentation
1.3 Synchrotron radiation-based Mössbauer techniques
References
Chapter 2 Mössbauer Spectroscopy in Studying Electronic Spin and Valence States of Ironin the Earth’s Lower Mantle
Jung-Fu Lin, Zhu Mao, and Ercan E Alp
2.1 Introduction
2.2 Synchrotron Mössbauer Spectroscopy at High Pressures and Temperatures
2.3 Crystal Field Theory on the 3d Electronic States
2.4 Conclusion
Acknowledgments
References
Chapter 3 In-beam Mössbauer Spectroscopy Using a Radioisotope Beam and a Neutron Capture Reaction
Yoshio Kobayashi
3.1 Introduction
3.257Mn (→ 57Fe) Implantation Mössbauer Spectroscopy
3.3 Neutron in-beam Mössbauer Spectroscopy
3 .4 Summary
References
Radionuclides
Chapter 4 Lanthanides(151Eu and 155Gd)-Mössbauer Spectroscopic Study of Defect-FluoriteOxides Coupled with New Defect-Crystal-Chemistry Model
Nakamura, N Igawa, Y Okamoto, Y Hinatsu, J, Wang, M Takahashi and M. Takeda
4.1 Introduction
4.2Defect-crystal-Chemistry (DCC) Lattice-parameter Model
4.3 Lns Mössbauer and Lattice-parameter Data of DF Oxides
4.4 DCC-Model Lattice-parameter and Lns-Mössbauer Data Analysis
Conclusion
References
Chapter 5 Mössbauer and Magnetic Study of Neptunyl(+1) Complexes
T Nakamoto, A Nakamura and M Takeda
5.1 Introduction
5.2 237Np Mössbauer Spectroscopy
5.3 Magnetic Property of Neptunyl Monocation (NpO2+)
5.4 Mössbauer and Magnetic Study of Neptunyl(+1) Complexes
5.5 Discussion
Conclusion
Acknowledgment
References
Chapter 6 Mössbauer Spectroscopy of 161Dy in Dysprosium Dicarboxylates
M Takahashi, C I Wynter, B R Hillery, Virender K Sharma, D Quarless, Leopold May, T Misu, S G Sobel, M Takeda, and E Brown
6.1 Introduction
6.2 Experimental Methods
6.3 Results and Discussion
6.4 Acknowledgment
References
Chapter 7 Study of Exotic Uranium Compounds using 238U Mössbauer Spectroscopy
Satoshi Tsutsui1,2and Masami Nakada2
7.1 Introduction
7.2 Determination of Nuclear g-factor in the Excited State of 238U Nuclei
7.3 Application of 238U Mössbauer Spectroscopy to Heavy Fermion
7.4 Application to Two-dimensional (2D) Fermi Surface System of Uranium Dipnictides
Summary
Acknowledgment
References
Spin Dynamics
Chapter 8 Reversible Spin-state Switching Involving a Structural Change
Satoru Nakashima
8.1 Introduction
8.2Three Assembled Structures of Fe(NCX)2(bpa)2 (X=S, Se) and Their Structural Change by Desorption of Propanol Molecules
8.3 Occurrence of Spin-crossover Phenomenon in Assembled Complexes Fe(NCX)2(bpa)2 (X=S, Se, BH3) by Enclathrating Guest Molecules
8.4 Reversible Structural Change of Host Framework of Fe(NCS)2(bpp)2•2(benzene) Triggered By Sorption of Benzene Molecules
8.5 Reversible Spin-state Switching Involving a Structural Change of Fe(NCX)2(bpp)2•2(benzene) (X=Se, BH3) Triggered By Sorption of Benzene Molecules
8.6 Conclusion
References
Chapter 9 Spin- Crossover and Related Phenomena Coupled with Spin, Photon and Charge
N Kokima and A Sugahara
9.1 Introduction
9.2 Photo-induced Spin-crossover Phenomena
9 3 Charge Transfer Phase Transition
9 4 Spin Equilibrium and Succeeding Phenomena
Fluctuation
References
Chapter 10 Spin Crossover in Iron(III) Porphyrins Involving the Intermediate-Spin State
Mikio Nakamura and Masashi Takahashi
10.1 Introduction
10.2 Methodology to Obtain Pure Intermediate-Spin Complexes
10.3 Spin Crossover Involving the Intermediate-Spin State
10.4 Spin Crossover Triangle in Iron(III) Porphyrins
10.5 Conclusion
Acknowledgments
References
Chapter 11 Tin(II) Lone Pair Stereoactivity: Influence on Structures and Properties, and Mössbauer Spectroscopic Properties
Georges Dénès1, M Cecilia Madamba1, Hocine Merazig2 and Abdualhafed Muntasar
11.1 Introduction
11.2 Experimental
11.3 Crystal Structures
11.4 Tin Electronic Structure and Mössbauer Spectroscopy
11.5 Application to the Structural Determination of α−SnF2
11.6 Application to the Structural Determination of the Highly Layered Structures of α−PbSnF4 and BaSnF4
11.7 Application to the Structural Study of Disordered Phases
11.8 Lone Pair Stereoactivity and Material Properties
11.9 Conclusion
Acknowledgments
References
Biological Applications
Chapter 12 Synchrotron Radiation Based Nuclear Resonant Scattering: Applications to Bioinorganic Chemistry
Yisong Guo, Yoshitaka Yoda, Xiaowei Zhang, Yuming Xiao, Stephen P Cram
12.1 Introduction
12.2 Technical Background
12.3 Applications in Bioinorganic Chemistry
12.4 Summary and Prospects
Acknowledgment
References
Chapter 13 Mössbauer Spectroscopy in Biological and Biomedical Research
Alexander A Kamnev1,*, Krisztina Kovács2, Irina V Alenkina3, and Michael I. Oshtrakh
13.1 Introduction
13.2 Microorganisms-related studies
13.3 Plants
13.4 Enzymes
13.5 Hemogoblin
13.6 Ferritin and Hemosiderin
13.7 Tissues
13.8 Pharmaceutical Products
13.9 Conclusions
Acknowledgments
References
Chapter 14 Controlled Spontaneous Decay of Mossbauer Nuclei (Theory and Experiments)
Vladimir I Vysotskii and Alla A Kornilova
14.1 Introduction to the Problem of Controlled Spontaneous Gamma-decay
14.2 General Consideration
14.3 Controlled Spontaneous Gamma-decay of Excited Nucleus in the System of Mutually Uncorrelated Modes of Electromagnetic Vacuum
14.4 Spontaneous Gamma-decay in the System of Synchronized Modes of Electromagnetic Vacuum
14.5 Experimental Study of the Phenomenon of Controlled Gamma-decay of Mossbauer Nuclei
14.6 Experimental Study of the Phenomenon of Controlled Gamma-decay by Investigation of Space Anisotropy and Self-focusing of Mossbauer Radiation
14.7 Direct Experimental Observation and Study of the Process of Controlled Radioactive and Excited Nuclei Radiative Gamma-decay by the Delayed Gamma-gamma Coincidence Method
14.8 Conclusion
References
Chapter 15 Natural's Strategy to Oxidize Tryptophan: EPR and Mossbauer Characterization of High-Valent Fe Intermediates
Kednerlin Dornevil and Aimin Liu
15.1 Two Oxidizing Equivalents Stored at a Ferric Heme
15.2 Oxidation of L-Tryptophan by Heme-Based Enzymes
15.3 The Chemical Reaction Catalyzed by MauG
15.4 A High-Valent bis-Fe(IV) Intermediate in MauG
15.5 High-Valent Fe Intermediate of Tryptophan 2,3-Dioxygenase
15.6 Concluding Remarks
References
Chapter 16 Iron in Neurodegeneration
Jolanta Gałązka-Friedman, Erika R Bauminger, and Andrzej Friedman
16.1 Introduction
16.2 Neurodegeneration and Oxidative Stress
16.3 Mössbauer Studies of Healthy Brain Tissue
16.4 Properties of Ferritin and Hemosiderin Present in Healthy Brain Tissue
16.5 Concentration of Iron Present in Healthy and Diseased Brain Issue
16.6 Asymmetry of the Mössbauer Spectra of Healthy and Diseased Brain Tissue
16.7 Conclusion – the Possible Role of Iron in Neurodegeneration
References
Chapter 17 Emission (57Co) Mössbauer Spectroscopy: Biology-related Applications, Potentials and Prospects
Alexander A Kamnev
17.1 Introduction
17.2 Methodology
17.3 Microbiological Applications
17.4 Enzymological Applications
17.5 Conclusions and Outlook
Acknowledgments
References
Iron Oxides
Chapter 18 Mossbauer Spectroscopy in Study of Nanocrystalline Iron Oxides from Thermal Processes
Jiří Tuček, Libor Machala, Jiří Frydrych, Jiří Pechoušek, and Radek Zbořil
18.1 Introduction
18.2 Polymorphs of Iron (III) Oxide, Their Crystal Structures, Magnetic Properties, and Polymorphous Phase Transformations
18.3 Use of 57Fe Mössbauer Spectroscopy in Monitoring Solid State Reaction Mechanisms towards Iron Oxides
18.4 Various Mössbauer Spectroscopy Techniques in Study of Applications Related to Nanocrystalline Iron Oxides
18.5 Conclusion
Acknowledgment
References
Chapter 19 Transmission and Emission 57Fe Mössbauer Studies on Perovskites and Related Oxide Systems
Zoltán Homonnay and Zoltán Németh
19.1 Introduction
19.2 Study of high-Tc superconductors
19.3 Study of Strontium ferrate and its substituted analogues
19.4 Pursuing Colossal Magnetoresistance in Doped Lanthanum Cobaltates
References
Chapter 20 Enhancing the Possibilities of 57Fe Mössbauer Spectrometry to Study the Inherent Properties of Rust Layers
Karen E García, César A Barrero, Alvaro L Morales, and Jean-Marc Greneche
20.1 Introduction
20.2 Mössbauer Characterization of Some Iron Phases Presented in the Rust Layers
20.3 Determining Inherent Properties of Rust Layers by Mössbauer Spectrometry
20.4 Final Remarks
Acknowledgments
References
Chapter 21 Application of Mössbauer Spectroscopy in Nanomagnetics
Lakshmi Nambakkat
21.1 Introduction
21.2 Spinel Ferrites
21.3 Nano Sized Fe-Al Alloys Synthesized by High Energy Ball Milling
21.4 Magnetic Thin Films/Multilayer Systems: 57Fe/Al MLS
Conclusion
Acknowledgment
References
Chapter 22 Mössbauer Spectroscopy and Surface Analysis
José F Marco, J Ramón Gancedo, Matteo Monti and Juan de la Figuera
22.1 Introduction
22.2 The Physical Basis: How and Why Electrons Appear in Mössbauer Spectroscopy
22.3 Increasing Surface Sensitivity in Electron Mössbauer Spectroscopy
22.4 The Practical Way: Experimental Low Energy Electron Mössbauer Spectroscopy
22.5 Mössbauer Surface Imaging Techniques
22.6 Recent Surface Mössbauer Studies in an "ancient" Material: Fe3O4
Acknowledgments
References
Chapter 23 57Fe Mössbauer Spectroscopy in the Investigation of the Precipitation of Iron OxidesSvetozar Musić, Mira Ristić, and Stjepko Krehula
23.1 Introduction
23.2 Complexation of Iron Ions by Hydrolysis
23.3 Precipitation of Iron Oxides by Hydrolysis Reactions
23.4 Precipitation of Iron Oxides from Dense -FeOOH Suspensions
23.5 Precipitation and Properties of Some Other Iron Oxides
23.6 Influence of Cations on the Precipitation of Iron Oxides
Acknowledgment
References
Chapter 24 Ferrates (IV, V, and VI): Mössbauer Spectroscopy Characterization
Virender K Sharma, Yurii Perfiliev, Radek Zboril, Libor Machala, and Clive Wynter
24.1 Introduction
24.2 Spectroscopic Characterization
24.3 Mössbauer Spectroscopy Characterization
Acknowledgments
References
Chapter 25 Characterization of Dilute Iron-Doped Yttrium Aluminum Garnets by Mössbauer Spectrometry
Kiyoshi Nomura and Zoltán Németh
25.1 Introduction
25.2 Sample Preparations by sol-gel Method
25.3 X-ray Diffraction and EXAFS Analysis
25.4 Magnetic Properties
25.5 Mössbauer Analysis of YAG Doped with Dilute Iron
25.6 Micro-discharge Treatment of Iron Doped YAG
Conclusion
Acknowledgment
References
Industrial Applications
Chapter 26 Some Mössbauer Studies of Fe-As Based High Temperature Superconductors
Amar Nath and Airat Khasanov
26.1 Introduction
26.2 Experimental
26.3 Where Do the Injected Electrons Go?
26.4 New Electron-rich Species in Ni-doped Single Crystals: Is it Superconducting?
26.5 Can O2 play an Important Role?
Acknowledgment
References
Chapter 27 Mossbauer Study of New Electrically Conductive Glass
Tetsuaki Nishida and Shiro Kubuki
27.1 Introduction
27.2 Structural Relaxation of Electrically Conductive Vanadate Glass
Acknowledgments
References
Chapter 28 Applications of Mössbauer Spectroscopy in the Study of Lithium Battery Materials
Ricardo Alcántara, Pedro Lavela, Carlos Pérez Vicente, José L Tirado
28.1 Introduction
28.2 Cathode Materials for Li-ion Batteries
28.3 Anode Materials for Li-ion Batteries
Conclusions
Acknowledgment
References
Chapter 29 Mössbauer Spectroscopic Investigations of Novel Bimetal Catalysts for Preferential CO Oxidation in H2
29.1 Introduction
29.2 Experimental Section
29.3 Results and Discussion
Conclusion
Acknowledgments
References
Chapter 30 The use of Mossbauer Spectroscopy in Coal Research-Is it Relevant or Not?
F B Waanders
30.1 Introduction
30.2 Experimental Procedures
30.3 Results and Discussion
Conclusions
References
Environmental Applications
Chapter 31 Water Purification and Characterization of Recycled Iron-Silicate Glass
Shiro Kubuki and Tetsuaki Nishida
31.1 Introduction
31.2 Property and Structure of Recycled Silicate Glasses
31.3 Summary
Reference
Chapter 32 Mössbauer Spectroscopy in the Study of Laterite Mineral Processing
Eamonn Devlin, Michail Samouhos, Charalabos Zografidis
32.1 Introduction
32.2 Conventional Processing
32.3 Microwave Processing
Reference
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