Advances in Heterocyclic Chemistry

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  • Edition: 1st
  • Format: Hardcover
  • Copyright: 2010-02-19
  • Publisher: Academic Pr

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The definitive serial in the field -- since 1960. * Provides up-to-date material on a fast growing and highly topical subject area * Contains the latest research covering a wide variety of heterocyclic topics * Written by leading authorities and designed as a handbook for students and industry and academic researchers

Table of Contents

Contributorsp. vii
Milestone of 100 Volumes of Advances in Heterocyclic Chemistry Marked by the Publication of Volumes 99, 100, and 101 as a Celebratory Setp. ix
Preface to Volume 99p. xi
Cycloaddition and Cyclization Chemistry of 2H-Azirinesp. 1
Introductionp. 1
Photocycloaddition Reactions of 2H-Azirinesp. 3
Thermal Cyclizations of 2H-Azirinesp. 12
2H-Azirines as Dienophiles or Dipolarophiles in Cycloaddition Reactionsp. 19
Concluding Remarksp. 27
Acknowledgmentp. 28
Referencesp. 28
Heterocyclic BINAP Analoguesp. 33
Introductionp. 33
Development of Synthetic Routes from BINAP to Heterocyclic BINAP Analoguesp. 35
Ligands with Phosphine Groups Attached to the Heterocyclic Ringp. 37
Ligands with Phosphine Groups Attached to the Non-Heterocyclic Ringp. 45
Acknowledgmentp. 55
Referencesp. 55
Monocyclic Hetarenes with ?-Electron Aromatic Sextetp. 61
Introductionp. 62
The Aromatic ?-Electron Sextetp. 63
Sextet ?-Electron Heteroaromatics with Four-Membered Ringsp. 70
Sextet ?-Electron Heteroaromatics with Five-Membered Ringsp. 73
Sextet ?-Electron Heteroaromatics with Six-Membered Ringsp. 82
Other 6-Membered Hetarenes. Pnictogenabenzenes: Phosphabenzene (3-Phosphinine), Arsa-, Stiba-, Bismabenzenesp. 88
Sextet ?-Electron Heteroaromatics with Seven-Membered Ringsp. 96
Conclusionsp. 97
Referencesp. 98
Biologically Active Silacyclanesp. 107
Introductionp. 107
Neurotropic Substancesp. 109
Cholesterol Level Lowering and Hypotensive Agentsp. 121
Sila-steroidsp. 123
Cytotoxic Agentsp. 125
Fungicides and Bactericidesp. 132
Odorantsp. 134
Toxicity of Silacyclanesp. 138
Referencesp. 138
Positional Selectivity in Electrophilic Substitution in ?-Excessive Heteroaromaticsp. 143
Introductionp. 144
Generation and Stability of Hetarenium Ionsp. 145
Positional Selectivity and Some Transformations of Hetarenium Ionsp. 149
Positional Selectivity in Reactions of Furan, Thiophene, Selenophene, Pyrrole and their Derivatives with Electrophilesp. 157
Positional Selectivity in Reactions of N-Substituted Pyrroles with Electrophilesp. 165
Referencesp. 175
Cyclic Azomethine Imines from Diazenes (Azo Compounds)p. 185
Introductionp. 186
[3+2] Cycloaddition Reactions of In Situ Generated Azoalkenes and Thiocyanic Acid. Cyclic Azomethine Imine Intermediatesp. 187
Intramolecular Interaction of Diazene N-Atoms with Carbenoid C-Atoms. Cyclic Azomethine Iminesp. 195
Referencesp. 206
Pyrroles and N-Vinylpyrroles from Ketones and Acetylenes: Recent Stridesp. 209
Introductionp. 210
Synthesis of Pyrroles and N-Vinylpyrrolesp. 211
Reactions of Pyrroles and N-Vinylpyrrolesp. 222
Physicochemical and Quantum Chemical Studies of Ketoximes and Pyrrolesp. 241
Conclusionp. 244
Referencesp. 245
Subject indexp. 255
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