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9780130647924

Analysis, Synthesis, and Design of Chemical Processes

by ; ; ;
  • ISBN13:

    9780130647924

  • ISBN10:

    0130647926

  • Edition: 2nd
  • Format: Hardcover
  • Copyright: 2009-01-01
  • Publisher: Prentice Hall
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Summary

An integrative approach to continuous improvement in chemical engineering.Process design skills are the focal point of sound chemical engineering. In this second edition of "Analysis, Synthesis, and Design of Chemical Processes," the authors present design as a creative process that integrates the big picture and the small details-and relies on knowing which to stress, and why. These techniques are applied to every aspect of the discipline, from the conceptual design of a plant to improving an existing process, and more."Analysis, Synthesis, and Design of Chemical Processes" moves chemical engineering students beyond neatly delineated classroom exercises and into the world of solving the open-ended process problems they will see in practice. The authors accomplish this by emphasizing design synthesis of the entire process--from equipment sizing to optimization, from finances to operation. Coverage includes: Evolution and generation of different process configurationsEstimating capital,investment, manufacturing costs, and other economic factorsSynthesis and optimization of chemical processesPerformance analysis of existing processes and equipment Environmental concerns, green engineering, engineering ethics, and health and safetyWritten and oral communications and teamwork"Analysis, Synthesis, and Design of Chemical Processes" represents over 30 years of chemical engineering teaching at West Virginia University. Included are suggested curricula for both single-semester and year-long design courses, case studies and design projects with practical applications, and appendices with current equipment cost data andpreliminary design information for four chemical processes.About the CD-ROMThe CD-ROM contains a heavily revised version of CAPCOST, now in the form of a spreadsheet template, which is used for evaluating fixed capital investme

Table of Contents

(NOTE: Each chapter concludes with a Summary.)
Preface.
List of Nomenclature.
0. Outcomes Assessment.

For Students. For Faculty.

SECTION 1. CONCEPTUALIZATION AND ANALYSIS OF CHEMICAL PROCESSES.


1. Diagrams for Understanding Chemical Processes.
Block Flow Diagram (BFD). Process Flow Diagram (PFD). Piping and Instrumentation Diagram (P&ID). Additional Diagrams. 3-Dimensional Representation of a Process. The 3-D Plant Model.

2. The Structure and Synthesis of Process Flow Diagrams.
Introduction. Step 1—Batch vs. Continuous Process. Step 2—The Input-Output Structure of the Process. Step 3—The Recycle Structure of the Process. Step 4—General Structure of the Separation System. Step 5—Heat-Exchanger Network or Process Energy Recovery System. Information Required and Sources.

3. Tracing Chemicals through the Process Flow Diagram.
Guidelines and Tactics for Tracing Chemicals. Tracing Primary Paths Taken by Chemicals in a Chemical Process. Recycle and Bypass Streams. Tracing Nonreacting Chemicals. Limitations. Written Process Description.

4. Understanding Process Conditions.
Conditions of Special Concern for the Operation of Separation and Reactor Systems. Reasons for Operating at Conditions of Special Concern. Conditions of Special Concern for the Operation of Other Equipment. Analysis of Important Process Conditions.

SECTION 2. ENGINEERING ECONOMIC ANALYSIS OF CHEMICAL PROCESSES.


5. Estimation of Capital Costs.
Classifications of Capital Cost Estimates. Estimation of Purchased Equipment Costs. Estimating the Total Capital Cost of a Plant.

6. Estimation of Manufacturing Costs.
Factors Affecting the Cost of Manufacturing a Chemical Product. Cost of Operating Labor. Utility Costs. Raw Material Costs. Yearly Costs and Stream Factors. Estimating Utility Costs from the PFD. Cost of Treating Liquid and Solid Waste Streams. Evaluation of Cost of Manufacture for the Production of Benzene via the Hydrodealkylation of Toluene.

7. Engineering Economic Analysis.
Investments and the Time Value of Money. Different Types of Interest. Time Basis for Compound Interest Calculations. Cash Flow Diagrams. Calculations from Cash Flow Diagrams. Inflation. Depreciation of Capital Investment. Taxation, Cash Flow, and Profit.

8. Profitability Analysis.
A Typical Cash Flow Diagram for a New Project. Profitability Criteria for Project Evaluation. Comparing Several Large Projects—Incremental Economic Analysis. Establishing Acceptable Returns from Investments—The Concept of Risk. Evaluation of Equipment Alternatives. Incremental Analysis for Retrofitting Facilities. Evaluation of Risk in Evaluating Profitability. Profit Margin Analysis.

SECTION 3. SYNTHESIS AND OPTIMIZATION OF CHEMICAL PROCESSES.


9. Utilizing Experience-Based Principles to Confirm the Suitability of a Process Design.
The Role of Experience in the Design Process. Presentation of Tables of Technical Heuristics and Guidelines.

10. Synthesis of the PFD from the Generic BFD.
Information Needs and Sources. Reactor Section. Separator Section. Reactor Feed Preparation and Separator Feed Preparation Sections. Recycle Section. Environmental Control Section. Major Process Control Loops. Flow Summary Table. Major Equipment Summary Table.

11. Synthesis of a Process Using a Simulator and Simulator Troubleshooting.
The Structure of a Process Simulator. Information Required to Complete a Process Simulation—Input Data. Handling Recycle Streams. Choosing Thermodynamic Models. Case Study—Toluene Hydrodealkylation Process.

12. Process Optimization.
Background Information on Optimization. Strategies. Topological Optimization. Parametric Optimization. Lattice Search Techniques vs. Experimental Design. Process Flexibility and the Sensitivity of the Optimum.

13. Pinch Technology.
Introduction. Heat Integration and Network Design. Composite Temperature Enthalpy Diagram. Composite Enthalpy Curves for Systems without a Pinch. Using the Composite Enthalpy Curve to Estimate Heat Exchanger Surface Area. Effectiveness Factor (F) and the Number of Shells. Combining Costs to Give the EAOC for the Network. Other Considerations. Heat Exchanger Network Synthesis Analysis and Design (HENSAD) Program. Mass-Exchange Networks.

SECTION 4. ANALYSIS OF PROCESS PERFORMANCE.


14. Process Input/Output Models.
Representation of Process Inputs and Outputs. Analysis of the Effect of Process Inputs on Process Outputs. A Process Example.

15. Tools for Evaluating Process Performance.
Key Relationships. Thinking with Equations. Base Case Ratios. Analysis of Systems Using Controlling Resistances. Graphical Representations.

16. Performance Curves for Individual Unit Operations.
Applications to Heat Transfer. Application to Fluid Flow. Application to Separation Problems.

17. Performance of Multiple Unit Operations.
Analysis of a Reactor with Heat Transfer. Performance of a Distillation Column. Performance of a Heating Loop. Performance of the Feed Section to a Process.

18. Reactor Performance.
Production of Desired Product. Reaction Kinetics and Thermodynamics. The Chemical Reactor. Heat Transfer in the Chemical Reactor. Reactor System Case Studies.

19. Regulating Process Conditions.
A Simple Regulation Problem. The Characteristics of Regulating Valves. Regulating Flowrates and Pressures. The Measurement of Process Variables. Common Control Strategies Used in Chemical Processes. Exchanging Heat and Work between Process and Utility Streams. Case Studies.

20. Process Troubleshooting and Debottlenecking.
Recommended Methodology. Troubleshooting Individual Units. Troubleshooting Multiple Units. A Process Troubleshooting Problem. Debottlenecking Problems.

SECTION 5. THE IMPACT OF CHEMICAL ENGINEERING DESIGN ON SOCIETY.


21. Ethics and Professionalism.
Ethics. Professional Registration. Legal Liability. Business Codes of Conduct.

22. Health, Safety, and the Environment.
Risk Assessment. Regulations and Agencies. Fires and Explosions. Process Hazard Analysis. Chemical Safety and Hazard Investigation Board. Inherently Safe Design. Glossary.

23. Green Engineering.
Environmental Regulations. Environmental Fate of Chemicals. Green Chemistry. Pollution Prevention during Process Design. Analysis of a PFD for Pollution Performance and Environmental Performance. An Example of the Economics of Pollution Prevention. Life-Cycle Analysis.

24. Chemical Product Design.
Strategies for Chemical Product Design. Needs. Ideas. Selection. Manufacture. Batch Processing. Economic Considerations.

SECTION 6. INTERPERSONAL AND COMMUNICATION SKILLS.


25. Teamwork.
Groups. Group Evolution. Teams and Teamwork. Misconceptions. Learning in Teams. Other Reading.

26. Written and Oral Communications.
Audience Analysis. Written Communication. Oral Communications. Software and Author Responsibility.

27. A Report Writing Case Study.
The Assignment Memorandum. Response Memorandum. Visual Aids. Example Reports. Checklist of Common Mistakes and Errors.

Appendix A. Cost Equations and Curves for the CAPCOST Program.
Purchased Equipment Costs. Pressure Factors. Material Factors and Bare Module Factors.

Appendix B. Information for the Preliminary Design of Four Chemical Processes.
Production of Dimethyl Ether (DME) via the Dehydration of Methanol. Acrylic Acid Production via the Catalytic Partial Oxidation of Propylene. Production of Acetone via the Dehydrogenation of Isopropyl Alcohol (IPA). Production of Heptenes from Propylene and Butenes.

Appendix C. Design Projects (on companion CD-ROM).
Project 1. Increasing the Production of 3-Chloro-1-Propene (Allyl Chloride) in Unit 600. Project 2. Design and Optimization of a New 20,000 Metric Tons per Year Facility to Produce Allyl Chloride at La Nueva Cantina, Mexico. Project 3. Scale-Down of Phthalic Anhydride Production at TBWS Unit 700. Project 4. The Design of a New, 100,000 Metric Tons per Year, Phthalic Anhydride Production Facility. Project 5. Problems at the Cumene Production Facility, Unit 800. Project 6. Design of a New, 100,000 Metric Tons per Year, Cumene Production Facility.

Index.

Supplemental Materials

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Excerpts

Preface This book represents the culmination of many years of teaching experience in the senior design course at West Virginia University (WVU) and University of Nevada, Reno. Although the program at WVU has evolved over the last thirty years and is still evolving, it is fair to say that the current program has gelled over the last fifteen years as a concerted effort by the authors to integrate "design" throughout the undergraduate curriculum in chemical engineering. We view design as the focal point of chemical engineering practice. Far more than the development of a set of specifications for a new chemical plant, design is the creative activity through which engineers continuously improve the operations of facilities to create products that enhance the quality of life. Whether developing the grass-roots plant, proposing and guiding process modifications, or troubleshooting and implementing operational strategies for existing equipment, engineering design requires a broad spectrum of knowledge and intellectual skills to be able to analyze the big picture and the minute details and, most important, to know when to concentrate on each. Our vehicle for helping students develop and hone their design skills is process design rather than plant design, covering synthesis of the entire chemical process through topics relating to the preliminary sizing of equipment, flowsheet optimization, economic evaluation of projects, and the operation of chemical processes. The purpose of this text is to assist chemical engineering students in making the transition from solving well-posed problems in a specific subject to integrating all the knowledge that they have gained in their undergraduate education and applying this information to solving open-ended process problems. Many of the "nuts and bolts" issues regarding plant design (for example, what schedule pipe to use for a given stream or what corrosion allowance to use for a vessel in a certain service) are not covered. Although such issues are clearly important to the practicing engineer, several excellent handbooks and textbooks are available to address such problems, and these are cited in the text where they apply. In the second edition, we have rearranged material from the first edition and have added several new chapters. The new material includes the following: Chapter 0, titled Outcomes assessment, addresses the subject from both student and faculty perspectives, including the relationship to the ABET EC 2000 criteria for accreditation of engineering programs in the United States. The material in Chapter 1 on process diagrams has been expanded to include some preliminary plant layout information. The topology of the chemical plant is introduced with the help of three-dimensional graphics tools. A digital "movie" is included on the CD accompanying the book, which gives a "virtual plant tour" of a simple chemical process. Material on the structure, synthesis, and conceptual design of chemical processes is added to the new Chapter 2. The hierarchical approach to conceptual design is presented with several examples. The chapter on capital cost estimation (new Chapter 5) has been revised, and new capital cost estimates for process equipment are presented (in Appendix A) which are based on an extensive survey of equipment manufacturers carried out during 2001. The CAPCOST program for estimating the fixed capital cost of building a new chemical plant has been revised extensively. The program is now written in the form of a Microsoft? Excel? template. The new capital costs from Chapter 5 and Appendix A are included. In addition, a full financial analysis, including operating costs, raw material costs, cash flow diagrams, and a Monte Carlo simulation feature, is included. Detailed calculations on how to estimate utility costs are included in the new Chapter 6 (old Chapter 3). Raw material costs and fuel cost

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