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Matter and Measurements | p. 2 |
Types of Matter | p. 3 |
Measurements | p. 8 |
Properties of Substances | p. 15 |
Chemistry: The Human Side: Antoine Lavoisier | p. 16 |
Chemistry: Beyond the Classroom: Titanium: A Space-Age Metal | p. 19 |
Chapter Highlights | p. 20 |
Summary Problem | p. 21 |
Questions & Problems | p. 21 |
Atoms, Molecules, and Ions | p. 26 |
Atoms and the Atomic Theory | p. 27 |
Chemistry: The Human Side: John Dalton | p. 27 |
Components of the Atom | p. 28 |
Introduction to the Periodic Table | p. 33 |
Molecules and Ions | p. 35 |
Formulas of Ionic Compounds | p. 40 |
Names of Compounds | p. 41 |
Chemistry: Beyond the Classroom: Ethyl Alcohol and the Law | p. 45 |
Chapter Highlights | p. 46 |
Summary Problem | p. 47 |
Questions & Problems | p. 47 |
Mass Relations in Chemistry; Stoichiometry | p. 52 |
Atomic Masses | p. 53 |
The Mole | p. 56 |
Mass Relations in Chemical Formulas | p. 58 |
Mass Relations in Reactions | p. 61 |
Chemistry: Beyond the Classroom: Hydrates | p. 68 |
Chapter Highlights | p. 69 |
Summary Problem | p. 69 |
Questions & Problems | p. 70 |
Reactions in Aqueous Solution | p. 76 |
Solute Concentrations; Molarity | p. 77 |
Precipitation Reactions | p. 79 |
Acid-Base Reactions | p. 82 |
Chemistry: The Human Side: Svante August Arrhenius | p. 87 |
Oxidation-Reduction Reactions | p. 87 |
Chemistry: Beyond the Classroom: Antacids | p. 94 |
Chapter Highlights | p. 95 |
Summary Problem | p. 95 |
Questions & Problems | p. 96 |
Gases | p. 102 |
Measurements on Gases | p. 103 |
The Ideal Gas Law | p. 105 |
Gas Law Calculations | p. 107 |
Stoichiometry of Gaseous Reactions | p. 110 |
Chemistry: The Human Side: Amadeo Avogadro | p. 112 |
Gas Mixtures: Partial Pressures and Mole Fractions | p. 113 |
Kinetic Theory of Gases | p. 115 |
Real Gases | p. 121 |
Chemistry: Beyond the Classroom: Airbags | p. 123 |
Chapter Highlights | p. 124 |
Summary Problem | p. 124 |
Questions & Problems | p. 125 |
Electronic Structure and the Periodic Table | p. 130 |
Light, Photon Energies, and Atomic Spectra | p. 131 |
The Hydrogen Atom | p. 134 |
Quantum Numbers | p. 138 |
Atomic Orbitals; Shapes and Sizes | p. 141 |
Electron Configurations in Atoms | p. 141 |
Chemistry: The Human Side: Glenn Seaborg | p. 145 |
Orbital Diagrams of Atoms | p. 146 |
Electron Arrangements in Monatomic Ions | p. 148 |
Periodic Trends in the Properties of Atoms | p. 150 |
Chemistry: Beyond the Classroom: The Aurora | p. 155 |
Chapter Highlights | p. 156 |
Summary Problem | p. 156 |
Questions & Problems | p. 157 |
Covalent Bonding | p. 162 |
Lewis Structures; The Octet Rule | p. 164 |
Chemistry: The Human Side: G. N. Lewis | p. 172 |
Molecular Geometry | p. 173 |
Polarity of Molecules | p. 180 |
Atomic Orbitals; Hybridization | p. 183 |
Chemistry: Beyond the Classroom: The Noble Gases | p. 188 |
Chapter Highlights | p. 189 |
Summary Problem | p. 189 |
Questions & Problems | p. 190 |
Thermochemistry | p. 194 |
Principles of Heat Flow | p. 195 |
Measurement of Heat Flow; Calorimetry | p. 198 |
Enthalpy | p. 201 |
Thermochemical Equations | p. 202 |
Enthalpies of Formation | p. 206 |
Bond Enthalpy | p. 210 |
The First Law of Thermodynamics | p. 212 |
Chemistry: Beyond the Classroom: Energy Balance in the Human Body | p. 216 |
Chapter Highlights | p. 218 |
Summary Problem | p. 218 |
Questions & Problems | p. 219 |
Liquids and Solids | p. 224 |
Liquid-Vapor Equilibrium | p. 225 |
Phase Diagrams | p. 230 |
Molecular Substances; Intermolecular Forces | p. 233 |
Network Covalent, Ionic, and Metallic Solids | p. 238 |
Crystal Structures | p. 244 |
Chemistry: The Human Side: Dorothy Hodgkin | p. 247 |
Chemistry: Beyond the Classroom: Allotropy | p. 249 |
Chapter Highlights | p. 250 |
Summary Problem | p. 251 |
Questions & Problems | p. 252 |
Solutions | p. 256 |
Concentration Units | p. 257 |
Principles of Solubility | p. 261 |
Colligative Properties of Nonelectrolytes | p. 264 |
Colligative Properties of Electrolytes | p. 271 |
Chemistry: Beyond the Classroom: Maple Syrup | p. 274 |
Chapter Highlights | p. 275 |
Summary Problem | p. 275 |
Questions & Problems | p. 276 |
Rate of Reaction | p. 282 |
Meaning of Reaction Rate | p. 283 |
Reaction Rate and Concentration | p. 286 |
Reactant Concentration and Time | p. 290 |
Models for Reaction Rate | p. 295 |
Chemistry: The Human Side: Henry Eyring | p. 299 |
Reaction Rate and Temperature | p. 299 |
Catalysts | p. 302 |
Reaction Mechanisms | p. 304 |
Chemistry: Beyond the Classroom: The Ozone Story | p. 308 |
Chapter Highlights | p. 310 |
Summary Problem | p. 310 |
Questions & Problems | p. 311 |
Gaseous Chemical Equilibrium | p. 320 |
The N[subscript 2]O[subscript 4]-NO[subscript 2] Equilibrium System | p. 321 |
The Equilibrium Constant Expression | p. 324 |
Determination of K | p. 329 |
Applications of the Equilibrium Constant | p. 330 |
Effect of Changes in Conditions on an Equilibrium System | p. 334 |
Chemistry: Beyond the Classroom: An Industrial Application of Gaseous Equilibrium | p. 340 |
Chapter Highlights | p. 342 |
Summary Problem | p. 342 |
Questions & Problems | p. 343 |
Acids and Bases | p. 350 |
Bronsted-Lowry Acid-Base Model | p. 351 |
The Ion Product of Water | p. 352 |
pH and pOH | p. 353 |
Weak Acids and Their Equilibrium Constants | p. 357 |
Weak Bases and Their Equilibrium Constants | p. 365 |
Acid-Base Properties of Salt Solutions | p. 368 |
Chemistry: Beyond the Classroom: Organic Acids and Bases | p. 371 |
Chapter Highlights | p. 373 |
Summary Problem | p. 373 |
Questions & Problems | p. 374 |
Equilibria in Acid-Base Solutions | p. 378 |
Buffers | p. 379 |
Acid-Base Indicators | p. 386 |
Acid-Base Titrations | p. 388 |
Chemistry: Beyond The Classroom: Acid Rain | p. 394 |
Chapter Highlights | p. 395 |
Summary Problem | p. 396 |
Questions & Problems | p. 396 |
Complex Ions | p. 402 |
Composition of Complex Ions | p. 403 |
Geometry of Complex Ions | p. 407 |
Chemistry: The Human Side: Alfred Werner | p. 411 |
Electronic Structure of Complex Ions | p. 411 |
Formation Constants of Complex Ions | p. 416 |
Chemistry: Beyond the Classroom: Chelates: Natural and Synthetic | p. 418 |
Chapter Highlights | p. 420 |
Summary Problem | p. 420 |
Questions & Problems | p. 421 |
Precipitation Equilibria | p. 424 |
Precipitate Formation; Solubility Product Constant (K[subscript sp]) | p. 425 |
Dissolving Precipitates | p. 431 |
Chemistry: Beyond the Classroom: Qualitative Analysis | p. 436 |
Chapter Highlights | p. 438 |
Summary Problem | p. 438 |
Questions & Problems | p. 439 |
Spontaneity of Reaction | p. 444 |
Spontaneous Processes | p. 445 |
Entropy, S | p. 447 |
Free Energy, G | p. 452 |
Chemistry: The Human Side: J. Willard Gibbs | p. 453 |
Standard Free Energy Change, [Delta]G[degree] | p. 454 |
Effect of Temperature, Pressure, and Concentration on Reaction Spontaneity | p. 457 |
The Free Energy Change and the Equilibrium Constant | p. 461 |
Additivity of Free Energy Changes; Coupled Reactions | p. 462 |
Chemistry: Beyond the Classroom: Global Warming | p. 465 |
Chapter Highlights | p. 466 |
Summary Problem | p. 467 |
Questions & Problems | p. 468 |
Electrochemistry | p. 474 |
Voltaic Cells | p. 475 |
Standard Voltages | p. 479 |
Relations Between E[degree], [Delta]G[degree], and K | p. 484 |
Effect of Concentration on Voltage | p. 486 |
Electrolytic Cells | p. 489 |
Chemistry: The Human Side: Michael Faraday | p. 493 |
Commercial Cells | p. 493 |
Chemistry: Beyond the Classroom: Corrosion of Metals | p. 498 |
Chapter Highlights | p. 499 |
Summary Problem | p. 500 |
Questions & Problems | p. 500 |
Nuclear Reactions | p. 506 |
Radioactivity | p. 507 |
Chemistry: The Human Side: The Curies | p. 511 |
Rate of Radioactive Decay | p. 512 |
Mass-Energy Relations | p. 514 |
Nuclear Fission | p. 518 |
Nuclear Fusion | p. 521 |
Chemistry: Beyond the Classroom: Biological Effects of Radiation | p. 523 |
Chapter Highlights | p. 524 |
Summary Problem | p. 525 |
Questions & Problems | p. 525 |
Chemistry of the Metals | p. 530 |
Metallurgy | p. 531 |
Reactions of the Alkali and Alkaline Earth Metals | p. 537 |
Redox Chemistry of the Transition Metals | p. 540 |
Chemistry: Beyond the Classroom: Essential Metals in Nutrition | p. 546 |
Chapter Highlights | p. 547 |
Summary Problem | p. 547 |
Questions & Problems | p. 548 |
Chemistry of the Nonmetals | p. 550 |
The Elements and Their Preparation | p. 551 |
Hydrogen Compounds of Nonmetals | p. 555 |
Oxygen Compounds of Nonmetals | p. 559 |
Oxoacids and Oxoanions | p. 562 |
Chemistry: Beyond the Classroom: Arsenic and Selenium | p. 570 |
Chapter Highlights | p. 571 |
Summary Problem | p. 571 |
Questions & Problems | p. 572 |
Organic Chemistry | p. 576 |
Saturated Hydrocarbons: Alkanes | p. 577 |
Unsaturated Hydrocarbons: Alkenes and Alkynes | p. 581 |
Aromatic Hydrocarbons and Their Derivatives | p. 583 |
Oxygen Compounds; Functional Groups | p. 585 |
Isomerism in Organic Compounds | p. 588 |
Synthetic Organic Polymers | p. 593 |
Chemistry: Beyond the Classroom: Cholesterol | p. 596 |
Chapter Highlights | p. 598 |
Summary Problem | p. 598 |
Questions & Problems | p. 599 |
Units, Constants, and Reference Data | p. 603 |
Properties of the Elements | p. 609 |
Exponents and Logarithms | p. 611 |
Nomenclature | p. 616 |
Molecular Orbitals | p. 619 |
Answers to Even-Numbered and Challenge Questions & Problems | p. 625 |
Gredits | p. 643 |
Index/Glossary | p. 647 |
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The Used, Rental and eBook copies of this book are not guaranteed to include any supplemental materials. Typically, only the book itself is included. This is true even if the title states it includes any access cards, study guides, lab manuals, CDs, etc.