New Developments in Selective Oxidation II : Proceedings of the 2nd World Congress and Fourth European Workshop Meeting, Benalmadena, Spain, September 20-24, 1993

by Corberan, V. Cortes; Bellon, S. Vic

• ISBN13: 9780444815521
• ISBN10: 044481552X
• Format: Hardcover
• Copyright: 1994-06-01
• Publisher: Elsevier Science Ltd

Table of Contents

Preface
Organization
Modelling of propylene oxidation in a circulating fluidized-bed reactor	p. 1
Selective oxidation over structured multicomponent molybdate catalysts	p. 19
Relationships between the catalytic activity and the composition of various uranium-antimony mixed oxide catalysts in the selective oxidation of olefins	p. 31
Synergy in the Fe-Mo-Sb-O multiphase system	p. 41
Role of tellurium oxide in the selective oxidation of isobutene to methacrolein: [actual symbol not reproducible] catalysts	p. 55
Propylene selective oxidation as studied by oxygen-18 labelling on well-defined MoO[subscript 3] catalysts	p. 67
Selective hydrocarbon oxidation at vanadium pentoxide surfaces: ab initio cluster model studies	p. 75
Comparison between gamma-alumina and aluminium niobate supported vanadium oxides in propane oxidative dehydrogenation	p. 83
Dispersion of V[superscript 4+] ions in a SnO[subscript 2] rutile matrix as a tool for the creation of active sites in ethane oxydehydrogenation	p. 93
Oxidative dehydrogenation of ethane over chromia-pillared montmorillonite catalysts	p. 103
Oxidative dehydrogenation of propane and n-butane on V-Mg based catalysts	p. 113
Oxidative dehydrogenation of the C[subscript 4]-C[subscript 5] paraffins over vanadium-containing oxide catalysts	p. 125
Oxidehydrogenation of propane on gallium oxide-faujasite catalysts	p. 133
Characteristics of alumina boria catalysts used in ethane partial oxidation	p. 143
Effect of potassium addition to [actual symbol not reproducible] catalysts on their physicochemical and catalytic properties in oxidative dehydrogenation of propane	p. 151
Catalytic reduction of carbon dioxide by hydrocarbons and other organic compounds	p. 159
A concise description of the bulk structure of vanadyl pyrophosphate and implications for n-butane	p. 167
A study of the (surface) structure of V-P-O catalysts during pretreatment and during activation	p. 183
The oxidation of n-butane on vanadyl pyrophosphate catalysts: study of pretreatment process	p. 195
Activation of vanadium phosphorus oxide catalysts for alkane oxidation oxygen storage and catalyst performance	p. 203
Vanadium phosphate catalysts prepared by the reduction of VOPO[subscript 4], 2H[subscript 2]O	p. 213
Production of maleic and phthalic anhydrides by selective vapor phase oxidation with vanadium oxide based catalysts	p. 221
A new commercial scale process for n-butane oxidation to maleic anhydride using a circulating fluidized bed reactor	p. 233
Separation of catalyst oxidation and reduction - An alternative to the conventional oxidation of n-butane to maleic anhydride?	p. 243
On the catalyst features affecting selectivity in n-C[subscript 4] hydrocarbon oxidation and oxidative dehydrogenation. FT-IR studies	p. 253
New reaction: n-Butane direct catalytic oxidation to tetrahydrofuran	p. 265
Oxidation and ammoxidation of propane over tetragonal type M[superscript 3]OPO[subscript 4] catalysts	p. 271
Structure and Stability during the Catalytic Reaction of Unsupported V-Antimonate Catalysts for the Direct Selective Ammoxidation of Propane to Acrylonitrile	p. 281
Ammoxidation of propane over vanadium-antimony-oxide catalysts. Role of phase cooperation effects	p. 293
Selective oxidation of propane in the presence of bismuth-based catalysts	p. 305
A study of the catalytic oxidative oligomerization of methane to aromatics	p. 315
Investigation of molten cobalt halide/sodium metavanadate mixtures as redox catalysts for the oxidative coupling of methane	p. 327
The active oxygen species in oxidative coupling of methane over Li/CaO and Na/CaO using N[subscript 2]O and O[subscript 2] as oxidants	p. 337
Spectroscopic characterization of surface oxygen species on barium-containing methane coupling catalysts	p. 345
Selectivity control by oxygen pressure in methane oxidation over phosphate catalysts	p. 357
Isotopic labeling studies on oxidative coupling of methane over alkali promoted molybdate catalysts	p. 367
Methane coupling over Sm-Al mixed oxides	p. 377
Catalytic reactor engineering for the oxidative coupling of methane. Use of a fluidized bed and of a ceramic membrane reactor	p. 387
[actual symbol not reproducible] catalysts for oxidative coupling of methane: relationship between structural features and catalytic behaviours	p. 395
Oxidative conversion of methane over MgO/ZSM-5 catalysts	p. 403
Surface characterization and catalytic behaviour of Li/MgO in oxidative coupling of methane	p. 411
Solid-gas phase interface analysis on [actual symbol not reproducible] correlation between CH[subscript 4] oxidation activity and work function measurements	p. 419
The role of structural defects and oxygen migration in La[subscript 2]O[subscript 3] for the oxidative coupling of methane	p. 427
Kinetic simulation of oxidative coupling of methane in the gas phase	p. 435
Oxidative coupling of methane over Ti-La-Na catalysts	p. 443
Gas Phase Oxidation of Benzene to Phenol using Pd/Cu Salt Catalysts. Effect of Counter Anion in Copper Salts	p. 451
Low temperature gas-phase selective oxidation of 1-butene to 2-butanone on supported Pd/V[subscript 2]O[subscript 3] catalysts	p. 461
The adsorption of oxygen on Ag and Ag-Au alloys: Mechanistic implications in ethylene epoxidation catalysis	p. 471
Detailed modeling of transport-kinetics interactions of ethylene epoxidation at high vacuum and atmospheric pressures	p. 481
Doping effects in ethylene epoxidation over potassium promoted silver catalysts	p. 495
A temperature programmed surface reaction study of the catalytic epoxidation and total oxidation of ethylene on silver	p. 499
HRTEM and TPO study of the behaviour under oxidizing conditions of some Rh/CeO[subscript 2] catalysts	p. 507
Redox molecular sieves as heterogeneous catalysts for liquid phase oxidations	p. 515
Influence of the synthesis procedure and chemical composition on the activity of titanium in Ti-Beta catalysts	p. 531
Selective oxidation of ammonia to hydroxylamine with hydrogen peroxide on titanium based catalysts	p. 541
Palladium catalyzed oxidation of benzene to phenol using molecular oxygen	p. 551
Partial oxidation of cinnamyl alcohol on bimetallic catalysts of improved resistance to self-poisoning	p. 561
Novel tungsten catalysts grafted onto polymeric materials: a comparison with phase transfer catalysis	p. 571
Selective oxidation of cyclopentene and cyclohexene by hydrogen peroxide catalyzed by heteropolyacids	p. 583
Highly selective epoxidation of olefins on mono-transition-metal-substituted Keggin-type heteropolytungstates by molecular oxygen in the presence of aldehyde	p. 593
Selective oxidation of cyclohexene with molecular oxygen catalyzed by transition metal substituted polyoxometalates	p. 603
Novel catalysts for olefin cleavage using hydrogen peroxide	p. 609
Novel one-pot synthesis of indigo from indole and organic hydroperoxide	p. 615
Selective oxidations with short-lived manganese (V)	p. 623
Catalytic oxidation of polyols: new example of nonradical mechanism of oxygenation	p. 629
Copper-catalyzed oxidative decarboxylation of aliphatic carboxylic acids	p. 639
Cyclohexane oxidation by the GOAGG[superscript III] system: formation of iron (hydr)oxide particles and reactivation	p. 647
Oxidation of cyclohexane catalyzed by polyhalogenated and perhalogenated manganese porphyrins	p. 653
Polymer supported iron catalysts for the oxidation of cyclohexane	p. 659
Selective oxidation of 2-mercaptobenzothiazole	p. 667
Selective oxidation of gaseous hydrocarbons by microbial cells	p. 675
Selective enzymatic oxidations by using oxygen as oxidizing agent: immobilization and stabilization of FNR, a NADP[superscript +] regenerating enzyme	p. 685
ESR study of photo-oxidation of phenol at low temperature on polycrystalline titanium dioxide	p. 693
Partial oxidation of benzene over the carbon whisker cathode added with iron oxide and palladium black during O[subscript 2]-H[subscript 2] fuel cell reactions	p. 703
Influence of operational variables on the photodegradation kinetics of Monuron in aqueous titanium dioxide dispersions	p. 713
Heterogeneous photocatalytic oxidation of liquid isopropanol by TiO[subscript 2], ZrO[subscript 2] and ZrTio[subscript 4] powders	p. 721
Effect of the state of vanadium on the properties incorporation titanium phosphate-based catalysts for oxidation of toluene	p. 729
Quantum-chemical description of the oxidation of alkylaromatic molecules on vanadium oxide catalysts	p. 739
Characterisation of [actual symbol not reproducible] catalysts for the gas-phase oxidation of fluorene to 9-fluorenone	p. 749
Gas-phase catalytic oxydehydrogenation of ethylbenzene on AlPO[subscript 4] catalysts	p. 759
Selective gas-phase dehydrogenation of cyclohexanol with magnesium orthophosphates	p. 769
Effect of K-doping on 2-propanol adsorption, desorption and catalytic oxidation over vanadia-titania	p. 777
Selective oxidation of methanol on iron-chromium-molybdenum oxide catalysts	p. 787
Creation of new selective sites by spill-over oxygen [alpha]-Sb[subscript 2]O[subscript 4] in the oxidation of ethanol	p. 795
Effect of titania on the properties of alumina supported molybdena catalysts	p. 803
Selective dehydrogenation of ethanol over vanadium oxide catalyst	p. 811
Cesium promotion of iron phosphate catalyst and influence of steam on the oxidative dehydrogenation of isobutyric acid to methacrylic acid	p. 819
Iron hydroxysilicates: New selective and active isobutyric acid oxidative dehydrogenation catalysts	p. 829
Thermolysis of heteropolyacid [actual symbol not reproducible] and catalytic properties of the thermal decomposition products in oxidation of acrolein to acrylic acid	p. 837
Selective oxidation of aldehydes over V-Mo-O[subscript x]/SiO[subscript 2] catalysts	p. 845
Diacetyl synthesis by the direct partial oxidation of methyl ethyl ketone over vanadium oxide catalysts	p. 853
Selective oxidation of hydrogen sulfide on a sodium promoted iron oxide on silica catalyst	p. 861
Effect of morphology of honeycomb SCR catalysts on the reduction of [actual symbol not reproducible] and the oxidation of SO[subscript 2]	p. 869
Author index	p. 877
Subject index	p. 881
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