Organic Chemistry

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  • Edition: 5th
  • Format: Hardcover
  • Copyright: 2003-01-01
  • Publisher: PRENTICE HALL
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In a highly accessible fashion, this top-selling book bridges the gap between conceptual understanding and actual applicationwhile strongly emphasizing the development of problem-solving skills. The book focuses on traditional organic chemistry topics and offers up-to-date aspects of spectroscopy, relevant photographs, and many applications to polymer chemistry integrated throughout the book.

Table of Contents

1. Introduction and Review.
2. Structure and Properties of Organic Molecules.
3. Structure and Stereochemistry of Alkanes.
4. The Study of Chemical Reactions.
5. Stereochemistry.
6. Alkyl Halides: Nucleophilic Substitution and Elimination.
7. Structure and Synthesis of Alkenes.
8. Reactions of Alkenes.
9. Alkynes.
10. Structure and Synthesis of Alcohols.
11. Reactions of Alcohols.
12. Infrared Spectroscopy and Mass Spectrometry.
13. Nuclear Magnetic Resonance Spectroscopy.
14. Ethers, Epoxides, and Sulfides.
15. Conjugated Systems, Orbital Symmetry, and Ultraviolet Spectroscopy.
16. Aromatic Compounds.
17. Reactions of Aromatic Compounds.
18. Ketones and Aldehydes.
19. Amines.
20. Carboxylic Acids.
21. Carboxylic Acid Derivatives.
22. Alpha Substitutions and Condensations of Enols and Enolate Ions.
23. Carbohydrates and Nucleic Acids.
24. Amino Acids, Peptides, and Proteins.
25. Lipids.
26. Synthetic Polymers.
Answers to Selected Problems.


To the Student As you begin your study of organic chemistry, yon might feel overwhelmed by the number of compounds, names, reactions, and mechanisms that confront you. You may even wonder whether you can learn all this material in a single year. The most important function of a textbook is to organize the material to show that most of organic chemistry consists of a few basic principles and many extensions and applications of these principles. Relatively little memorization is required if you grasp the major concepts and develop flexibility in applying those concepts. Frankly, I have a poor memory, and I hate memorizing lists of information. I don't remember the specifics of most of the reactions and mechanisms in this book, but I can work them out by remembering a few basic principles, like "alcohol dehydrations usually go by E1 mechanisms:" Still, you'll have to learn some facts and fundamental principles to serve as the working "vocabulary" of each chapter. As a student, I learned this the hard way when I made a D on my second organic chemistry exam. I thought organic would be like general chemistry, where I could memorize a couple of equations and fake my way through the exams. For example, in the ideal gas chapter, I would memorize pv = nrT,and I was good to go. When I tried the same approach in organic, I got a D. We learn by making mistakes, and I learned a lot in organic chemistry. In writing this book, I've tried to point out a small number of important facts and principles that should be learned to prepare for solving problems. For example, of the hundreds of reaction mechanisms shown in this book, about 20 are the fundamental mechanistic steps that combine into the longer, more complicated mechanisms. I've highlighted these fundamental mechanisms in Key Mechanismboxes to alert you to their importance. Spectroscopy is another area where a student might feel pressured to memorize hundreds of facts, such as NMR chemical shifts and infrared vibration frequencies. I couldn't do that, so I've always gotten by with knowing about a dozen NMR chemical shifts and about a dozen IR vibration frequencies, and knowing how they are affected by other influences. I've listed those important infrared frequencies in Table 12-2 and the important NMR chemical shifts in Table I 3-3. Don't try to memorize your way through this course.It doesn't work; you have to know what's going on so you can apply the material. Also, don't think (like I did) that you can get by without memorizing anything. Read the chapter, listen carefully to the lectures, and work the problems. The problems will tell you whether or not you know the material. If you can do the problems, you should do well on the exams. If you can't do the problems, you probably won't be able to do the exams, either. If you keep having to look up something to do the problems, that item is a good one to learn. Here are some hints I give my students at the beginning of the course: Read the material in the book before the lecture (expect 13-15 pages per lecture). Knowing what to expect and what is in the book, you can take fewer notes and spend more time listening and understanding the lecture. After the lecture, review you notes and the book, and do the in-chapter problems. Also, read the material for the next lecture. If you are confused about something, visit your instructor during office hours immediately, before you fall behind. Bring your attempted solutions to problems with you to show your instructor where you are having trouble. To study for the exam, begin by reviewing each chapter and your notes, then concentrate on the end-of-chapter problems. Also use old exams for practice, if available. Remember the two "golden rules" of organic chemistry. DON'T GET BEHIND!The course moves too fast, and it's hard to catch up.

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