Short Review of NMR Theory | p. 1 |
Origin of the Spectrum | p. 1 |
Coupling to other Nuclei | p. 5 |
Bibliography | p. 6 |
The Range of Chemical Shifts, Coupling Constants, and What Influences Each | p. 7 |
Chemical Shift Values | p. 9 |
Coupling Constants | p. 15 |
Coupling to Hydrogen | p. 16 |
Coupling to Carbon | p. 18 |
Coupling to Phosphorus | p. 21 |
Coupling to Metals | p. 22 |
Bibliography | p. 23 |
Oxidation State from P(-III) over P(0) to P(+V) | p. 25 |
Bibliography | p. 29 |
¿5-Phosphanes | p. 31 |
Bibliography | p. 35 |
¿3-Phosphanes | p. 37 |
Phosphorus Element Single Bonds | p. 37 |
Box Story: Electronic and Steric Properties of Phosphanes and Phosphites | p. 44 |
Phosphorus Carbon Multiple Bonds | p. 47 |
Phosphorus Phosphorus Bonds | p. 59 |
Diphosphanes | p. 60 |
Diphosphanes | p. 65 |
Bibliography | p. 68 |
Main Group Compounds | p. 71 |
As Lewis Base | p. 71 |
As Lewis Acid P(I), P(III), and P(V) | p. 75 |
Bibliography | p. 81 |
Transition Metal Complexes | p. 83 |
Phosphanes | p. 83 |
Chelate Phosphanes (Influence of Ring Size) | p. 87 |
Phosphides (Terminal and Bridging) | p. 89 |
Phosphinidines (Terminal and Bridging) | p. 101 |
Phosphaacetylene Complexes | p. 112 |
Agostic M-P-H Interactions | p. 115 |
Naked Phosphorus | p. 117 |
Box Story: Isolobal Theory | p. 125 |
Bibliography | p. 126 |
Index | p. 129 |
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