Thermodynamics in Materials Science, Second Edition

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  • Edition: 2nd
  • Format: Hardcover
  • Copyright: 2006-03-13
  • Publisher: CRC Press

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Thermodynamics in Materials Science, Second Edition is a clear presentation of how thermodynamic data is used to predict the behavior of a wide range of materials, a crucial component in the decision-making process for many materials science and engineering applications. This primary textbook and ongoing reference accentuates the integration of principles, strategies, and thermochemical data to generate accurate "maps" of equilibrium states, such as phase diagrams, predominance diagrams, and Pourbaix corrosion diagrams. It also recommends which maps are best suited for specific real-world scenarios and thermodynamic problems.The second edition introduces new, more user-friendly computer software, capable of converting the latest databases into the most accurate equilibrium maps yet. Each chapter presents its subject matter consistently, based on the classification of thermodynamic systems, properties, and derivations that illustrate important relationships among variables for finding the conditions for equilibrium. Each chapter also contains a summary of important concepts and relationships as well as examples and sample problems that apply appropriate strategies for solving real-world problems.The up-to-date and complete coverage of thermodynamic data, laws, definitions, strategies, and tools in Thermodynamics in Materials Science, Second Edition provides students and practicing engineers a valuable guide for producing and applying maps of equilibrium states to everyday applications in materials sciences.

Table of Contents

Why Study Thermodynamics?p. 1
The Structure of Thermodynamicsp. 17
The Laws of Thermodynamicsp. 31
Thermodynamic Variables and Relationsp. 53
Equilibrium in Thermodynamic Systemsp. 107
Statistical Thermodynamicsp. 129
Unary Heterogeneous Systemsp. 163
Multicomponent Homogeneous Nonreacting Systems: Solutionsp. 197
Multicomponent Heterogeneous Systemsp. 249
Thermodynamics of Phase Diagramsp. 285
Multicomponent Multiphase Reacting Systemsp. 349
Capillarity Effects in Thermodynamicsp. 409
Defects in Crystalsp. 465
Equilibrium in Continuous Systems: Thermodynamic Effects of External Fieldsp. 495
Electrochemistryp. 523
Fundamental Physical Constants and Conversion Factorsp. 559
Properties of Selected Elementsp. 561
Phase Transformations for the Elementsp. 563
Properties of Some Random Solutionsp. 565
Properties of Selected Compoundsp. 567
Interfacial Energies of Selected Elementsp. 569
Electrochemical Seriesp. 571
The Carnot Cyclep. 573
Answers to Homework Problemsp. 579
Indexp. 591
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