Zeolite synthesis is an active field of research. As long as this continues, new phases will be discovered and new techniques for preparing existing phases will appear. This edition of Verified Synthesis of Zeolitic Materials contains all the recipes from the first edition plus 24 new recipes. Five new introductory articles have been included plus those from the first edition, some of which have been substantially revised. The XRD patterns have been recorded using different instrument settings from those in the first edition and are intended to conform to typical X-ray diffraction practice. In most cases, only the XRD pattern for the productas synthesised is printed here. The exceptions are those phases which show marked changes in the XRD pattern upon calcination.

Preface

1

(1)

Synthesis commission: membership

2

(1)

Introduction and explanatory notes

3

(4)

Conditions for recording of XRD patterns

7

(1)

Contributors

8

(11)

Introduction to zeolite synthesis

Source materials for zeolite synthesis

19

(2)

Nucleation, growth, and seeding in zeolite synthesis

21

(4)

Synthesis of high-silica zeolites and phosphate-based materials in the presence of fluorides

25

(2)

Templating in molecular sieve synthesis

27

(6)

The pH value and its importance for the crystallization of zeolites

33

(6)

Microwave technology in zeolite synthesis

39

(4)

Preparation of zeolite membranes

43

(2)

Safety considerations for zeolite synthesis

45

(2)

Product characterization by x-ray powder diffraction

47

(4)

Determination of the elemental compositor of zeolitic materials

51

(4)

Characterization of zeolites by SEM

55

(2)

Product characterization by NMR

57

(4)

Characterization of zeolites by sorption capacity measurements

61

(6)

Ion-exchange capacity

67

(2)

Characterization by IR spectroscopy

69

(4)

How to read a patent

73

Synthesis recipes

ABW - Li-A (BW)

74

AEI - AlPO4-18

78

AEI - SAPO-18 (DPEA method)

81

AEI - SAPO-18 (TEA method)

84

AEL - AlPO4-11

87

AFI - AlPO4-5

90

AFI - SAPO-5

93

AFI - CoAPO-5

96

AFI - SSZ-24

99

AFO - SAPO-41

102

AFS - MAPO-46

105

ANA - Analcime

107

AST - AlPO4-16

110

ATN - MAPO-39

113

BEA - Zeolite Beta

115

BEA - [Ti,Al] Beta

118

CAN - Cancrinite

121

CHA - Chabazite

123

CHA - SSZ-13

126

CHA - SAPO-34

129

CHA - SAPO-44

132

CLO - Cloverite (GaPO4)

134

EAB - TMA-E

137

EDI - Barrer K-F

140

EDI - Linde Type F

142

EMT - EMC-2

145

EUO - [Ga] EU-1

147

FAU - Linde Type X

150

FAU - Low-silica Type X (LSX)

153

FAU - Linde Type Y

156

FAU - High-silica Faujasite EMC-1

159

FAU - [Ga] Type Y

162

FAU - SAPO-37

164

FER - ZSM-35

167

GIS - Zeolite P

169

KFI - ZK-5

171

KFI - High-silica KFI

174

LEV - [B]-Levyne

177

LTA - Linde Type A

179

LTA - ZK-4

182

LTA - Zeolite Alpha

185

LTA - GaPO4

188

LTL - Linde Type L

190

MAZ - Mazzite

193

MER - Linde W

196

MFI - High-alumina ZSM-5

198

MFI - Silicalite-1

201

MFI - [B] ZSM-5

203

MFI - [Fe] ZSM-5

205

MFI - [Ti] ZSM-5

207

MFI - [Ti,Al] ZSM-5

209

MOR - Mordenite

212

MTN - ZSM-39

214

MTT - ZSM-23

217

MTW - ZSM-12

220

MTW - [Ga] ZSM-12

222

MWW - MCM-22

225

NAT - [Ga] Natrolite

228

OFF - Linde Type T

230

OFF - Offretite

233

OFF - [Ga] Offretite

236

PAU - ECR-18

239

PAU - Paulingite (seeded)

241

PHI - Phillipsite

244

PHI - High-alumina Phillipsite

246

RHO - High-silica Rho

249

SOD - NaBr-Sodalite

251

STT - SSZ-23

255

TON - ZSM-22

258

VFI - VPI-5 (DPA method)

261

VFI - VPI-5 (TBA method)

263

SUZ-4

265

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