Advances in Controlled/Living Radical Polymerization

by Matyjaszewski, Krzysztof

• ISBN13: 9780841238541
• ISBN10: 0841238545
• Format: Hardcover
• Copyright: 2003-06-26
• Publisher: American Chemical Society

Summary

Presents new developments in controlled/living radical polymerization in three areas: atom transfer radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation transfer (RAFT). Also includes synthesis and characterization of many newmaterials.

Table of Contents

Preface	xiii
Fundamentals
Controlled/Living Radical Polymerization: State of the Art in 2002	2	(8)
Krzysztof Matyjaszewski
Criteria for Livingness and Control in Nitroxide-Mediated and Related Radical Polymerizations	10	(14)
Hanns Fischer
Mechanisms and Kinetics of Living Radical Polymerization: Absolute Comparison of Theory and Experiment	24	(18)
Takeshi Fukuda
Chiaki Yoshikawa
Yungwan Kwak
Atsushi Goto
Yoshinobu Tsujii
Conventional Radical Polymerization
Termination Kinetics of Acrylate and Methacrylate Homo- and Copolymerizations	42	(17)
Michael Buback
Mark Egorov
Achim Feldermann
Lewis Acid-Catalyzed Tacticity Control during Radical Polymerization of (Meth)acrylamides	59	(13)
Yoshio Okamoto
Shigeki Habaue
Yutaka Isobe
Propagation and Termination in Free Radical Polymerization of Styrene to High Conversion Investigated by Electron Spin Resonance Spectroscopy	72	(14)
Per B. Zetterlund
Hirotomo Yamazoe
Satoru Yamauchi
Bunichiro Yamada
Electron Spin Resonance Study of Conventional Radical Polymerization of tert-Butyl (Meth)acrylates Using Radical Precursors Prepared by Atom Transfer Radical Polymerization	86	(16)
Atsushi Kajiwara
Mikiharu Kamachi
Atom Transfer Radical Polymerization: Mechanisms
Living Radical Polymerization with Designed Metal Complexes	102	(14)
Masami Kamigaito
Tsuyoshi Ando
Mitsuo Sawamoto
Controlled Radical Polymerization Catalyzed by Ruthenium Complexes: Variations on Ru-Cp#	116	(14)
Sebastien Delfosse
Aurore Richel
Francois Simal
Albert Demonceau
Alfred F. Noels
Oscar Tutusaus
Rosario Nunez
Clara Vinas
Francesc Teixidor
Toward Structural and Mechanistic Understanding of Transition Metal-Catalyzed Atom Transfer Radical Processes	130	(18)
Tomislav Pintauer
Blayne McKenzie
Krzysztof Matyjaszewski
Mechanistic Aspects of Copper-Mediated Living Radical Polymerization	148	(13)
Jeetan Lad
Simon Harrisson
David M. Haddleton
ESR Study and Radical Observation in Transition Metal-Mediated Polymerization: Unified View of Atom Transfer Radical Polymerization Mechanism	161	(19)
Aileen R. Wang
Shiping Zhu
Krzysztof Matyjaszewski
Peculiarities in Atom Transfer Radical Copolymerization	180	(13)
Bert Klumperman
Gregory Chambard
Richard H. G. Brinkhuis
Atom Transfer Radical Polymerization of Methyl Methacrylate Utilizing an Automated Synthesizer	193	(13)
Huiqi Zhang
Martin W. M. Fijten
Richard Hoogenboom
Ulrich S. Schubert
Asymmetric Atom Transfer Radical Polymerization: Enantiomer-Selective Cyclopolymerization of rac-2,4-Pentanediyl Dimethacrylate Using Chiral ATRP Initiator	206	(15)
Toyoji Kakuchi
Masashi Tsuji
Toshifumi Satoh
Organic Acids Used as New Ligands for Atom Transfer Radical Polymerization	221	(15)
Shenmin Zhu
Deyue Yan
Marcel Van Beylen
Nøvel Fluorinated Polymer Materials Based on 2,3,5,6- Tetrafluoro-4-methoxystyrene	236	(14)
Soren Hvilsted
Sachin Borkar
Heinz W. Siesler
Katja Jankova
Copper Removal in Atom Transfer Radical Polymerization	250	(18)
Mical E. Honigfort
Shingtza Liou
Jude Rademacher
Dennis Malaba
Todd Bosanac
Craig S. Wilcox
William J. Brittain
Atom Transfer Radical Polymerization: Materials and Applications
Synthesis and Properties of Copolymers with Tailored Sequence Distribution by Controlled/Living Radical Polymerization	268	(15)
Jean-Francois Lutz
Tadeusz Pakula
Krzysztof Matyjaszewski
Controlled Synthesis of Amphiphilic Poly(methacrylate)-g-[poly(ester)/poly(ether)] Graft Terpolymers	283	(16)
Isabelle Ydens
Philippe Degee
Jan Libiszowski
Andrzej Duda
Stanislaw Penczek
Philippe Dubois
New Materials Using Atom Transfer Radical Polymerization: Microcapsules Containing Polar Core Oil	299	(17)
Mir Mukkaram Ali
Harald D. H. Stover
Synthesis of Poly(N, N-Dimethylacrylamide) Brushes from Functionalized Latex Surfaces by Aqueous Atom Transfer Radical Polymerization	316	(15)
Jayachandran N. Kizhakkedathu
Diane Goodman
Donald E. Brooks
End-Functional Polystyrenes via Quasiliving Atom Transfer Radical Polymerization and New Polymer Structures Therefrom	331	(11)
Bela Ivan
Tamas Fonagy
Tibor Erdey-Gruz
Gyorgy Hollo-Szabo
Marta Szesztay
Ulrich Schulze
Jurgen Pionteck
A Strategy to Prepare Anemone-Shaped Polymer Brush by Controlled/Living Radical Polymerization	342	(10)
Fu-Mian Li
Ming-Qiang Zhu
Xin Zhang
Liu-He Wei
Fu-Sheng Du
Zi-Chen Li
Surface Modification of Ethylene-Vinyl Alcohol Copolymer Films by Surface-Confined Atom Transfer Radical Polymerization	352	(14)
Ning Luo
Scott M. Husson
Douglas E. Hirt
Dwight W. Schwark
Polymers, Particles, and Surfaces with Hairy Coatings: Synthesis, Structure, Dynamics, and Resulting Properties	366	(17)
Tadeusz Pakula
Piotr Minkin
Krzysztof Matyjaszewski
Photoinduced Free Radical Promoted Cationic Block Copolymerization by Using Macrophotoinitiators Prepared by ATRP and Ring-Opening Polymerization Methods	383	(11)
Yusuf Yagci
Mustafa Degirmenci
Bioinspired Triblock Copolymers Prepared by Atom Transfer Radical Copolymerization	394	(18)
Jan C. M. van Hest
Lee Ayres
Henri Spijker
Matthijn Vos
Joost Opsteen
Nitroxide-Mediated Polymerization and Stable Free Radical Polymerization
Influence of Solvent and Polymer Chain Length on the Homolysis of SGI-Based Alkoxyamines	412	(12)
Olivier Guerret
Jean-Luc Couturier
Florence Chauvin
Hafid El-Bouazzy
Denis Bertin
Didier Gigmes
Sylvain Marque
Hanns Fischer
Paul Tordo
Impact of Dilution on the Rate Constant of Termination <kt> in Nitroxide-Mediated Polymerization	424	(14)
Celine Chevalier
Olivier Guerret
Yves Gnanou
Nitroxide-Mediated Polymerization in Miniemulsion: A Direct Way from Bulk to Aqueous Dispersed Systems	438	(14)
B. Charleux
The Use of PROXYL Nitroxides in Nitroxide-Mediated Polymerization	452	(14)
Neil R. Cameron
Catherine A. Bacon
Alistair J. Reid
Nitroxide-Mediated Semibatch Polymerization for the Production of Low-Molecular Weight Solvent-Borne Coatings Resins	466	(15)
Yanxiang Wang
Frederic Naulet
Michael F. Cunningham
Robin A. Hutchinson
Boroxyl-Based Radical Initiators and Polymerization	481	(15)
T. C. Chung
H. Hong
Controlled Radical Polymerization of Alkyl Methacrylates in the Presence of NO/NO2 Mixtures	496	(24)
Christophe Detrembleur
Michael Claes
Robert Jerome
RAFT and Other Degenerative Transfer Processes
Kinetics and Mechanism of RAFT Polymerization	520	(16)
Graeme Moad
Roshan T. A. Mayadunne
Ezio Rizzardo
Melissa Skidmore
San H. Thang
On the Importance of Xanthate Substituents in the MADIX Process	536	(15)
Mathias Destarac
Daniel Taton
Samir Z. Zard
Twana Saleh
Yvan Six
Influences of the Structural Design of RAFT Agents on Living Radical Polymerization Kinetics	551	(19)
Thomas P. Davis
Christopher Barner-Kowollik
T. L. Uyen Nguyen
Martina H. Stenzel
John F. Quinn
Philipp Vana
Vinylidene Chloride Copolymerization with Methyl Acrylate by Degenerative Chain Transfer	570	(16)
P. Lacroix-Desmazes
R. Severac
B. Boutevin
RAFT Polymerization in Homogeneous Aqueous Media	586	(17)
Andrew B. Lowe
Brent S. Sumerlin
Michael S. Donovan
David B. Thomas
Pierre Hennaux
Charles L. McCormick
RAFT Polymers: Novel Precursors for Polymer--Protein Conjugates	603	(16)
Christine M. Schilli
Axel H. E. Muller
Ezio Rizzardo
San H. Thang
(Bill) Y. K. Chong
New Concepts for Controlled Radical Polymerization: The DPE System	619	(12)
P. C. Wieland
O. Nuyken
Y. Heischkel
B. Raether
C. Strissel
Organotellurium-Mediated Living Radical Polymerization	631	(14)
Shigeru Yamago
Kazunori Iida
Jun-ichi Yoshida
Indexes
Author Index	645	(2)
Subject Index	647