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BRIAN M. TISSUE, PhD, is Associate Professor of Chemistry at Virginia Tech, where he teaches analytical chemistry at both the undergraduate and graduate levels. In addition to curriculum development, Dr. Tissue oversees a research program in nanomaterials and analytical spectroscopy, preparing and testing nanocomposites for catalytic activity. Among his honors, Dr. Tissue has received an NSF Career Award and a Cottrell Scholar Award from the Research Corporation for Science Advancement.
I Quantitative analysis using reactions that go to \completion 3
1 Making Measurements 5
1.1 Introduction 5
1.2 GLP and a Few Other Important Acronyms 11
1.3 Precision and Random Error 17
1.4 Discarding a Suspected Outlier 27
1.5 Calibration 30
1.6 Maintaining Accurate Results 44
Practice Exercises 50
2 Sample Preparation, Extractions, and Chromatography 55
2.1 Sampling and Control Samples 55
2.2 Sample Preparation 59
2.3 Solvents and Solutions 65
2.4 Introduction to Solubility 69
2.5 Extraction 72
2.6 Stationary Phases 82
2.7 Solid-Phase Extraction (SPE) 88
2.8 Introduction to Chromatography 90
2.9 Immunoassays 94
Practice Exercises 96
3 Classical Methods 103
3.1 Introduction 103
3.2 Review of Chemical Reactions 105
3.3 Reactions in Aqueous Solution 112
3.4 Gravimetry 121
3.5 Titration 125
3.6 Titration Curves 132
3.7 Coulometry 133
Practice Exercises 136
4 Molecular Spectroscopy 141
4.1 Introduction 141
4.2 Properties of Electromagnetic Radiation 142
4.3 Electromagnetic Spectrum 145
4.4 Spectroscopic Transitions 147
4.5 UV/Vis Absorption Spectroscopy 151
4.6 UV/Vis Instrumentation 152
4.7 Beer-Lambert Law 154
4.8 Molecular Fluorescence 160
Practice Exercises 164
II Reactions that do not go to\completion." Equilibria in aqueous solu-tions 171
5 Acid-Base Equilibria and Activity 173
5.1 Acids and Bases 173
5.2 Weak Acids and Weak Bases 180
5.3 Water and Kw 185
5.4 Acid Strength 191
5.5 The Concept of Activity 199
5.6 Acid-Base Equilibrium Calculations 211
Practice Exercises 219
6 Buffer Solutions and Polyprotic Acids 223
6.1 Buffer Solutions 223
6.2 Alpha Fraction Plots 229
6.3 Weak Acid Titration Curve 233
6.4 Polyprotic Acids 235
Practice Exercises 245
7 Complexation and Precipitation Equilibria 249
7.1 Complex Terminology 250
7.2 Complex Equilibria 253
7.3 Competing Equilibria 261
7.4 Stepwise Complexation 267
7.5 Precipitate Equilibrium 272
7.6 Molar Solubility 281
7.7 Precipitation and Competing Equilibria 289
Practice Exercises 296
Instrumental methods and analytical separations 303
8 Electroanalytical Chemistry 305
8.1 Introduction 305
8.2 Standard Reduction Potentials 308
8.3 Using Half Reactions 313
8.4 Background on Spontaneous Reactions and Equilibrium 320
8.5 Reaction Energies, Voltages, and the Nernst Equation 322
8.6 Electrochemical Cells 326
8.7 Potentiometry 330
8.8 Ion-Selective Electrodes (ISE) 333
8.9 Voltammetry 339
Practice Exercises 346
9 Atomic Spectrometry 351
9.1 Atomization 352
9.2 Atomic Absorption Spectrometry (AAS) 356
9.3 Atomic Emission spectrometry (AES) 363
9.4 Introduction to Mass Spectrometry (MS) 365
9.5 ICP-MS Measurements 368
9.6 Summary 369
Practice Exercises 371
10 Analytical Separations 377
10.1 Thin-Layer Chromatography 378
10.2 Chromatogram Terminology 381
10.3 Column Selection 384
10.4 High Performance Liquid Chromatography 388
10.5 Gas Chromatography 395
10.6 Molecular Mass Spectrometry 398
10.7 Electrophoresis 405
Practice Exercises 409
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