Electroactive Polymers for Corrosion Control

by Zarras, Peter; Stenger-Smith, John D.; Wei, Yen

• ISBN13: 9780841237902
• ISBN10: 0841237905
• Format: Hardcover
• Copyright: 2003-03-13
• Publisher: American Chemical Society

Summary

Electroactive Polymers for Corrosion Control is designed to help chemists and engineers prevent corrosion of metals. This book discusses electroactive polymers, electrically conductive polymers, and mechanisms of corrosion protection (passivation of metals). Professor Alan MacDiarmid, 2000 Nobel Laureate, presents a brief review of the history of electroactive materials with a general understanding of the synthesis of electroactive materials and corrosion in aqueous environments. Several authors explain the phenomena of corrosion and propose mechanisms by which electroactive polymers inhibit corrosion. Several studies include current state-of-the-art synthesis of electroactive polymers, and data supporting the prevention of corrosion in various media are discussed. Inaddition, new techniques for measuring the onset of corrosion are presented. Chapters in this volume represent a broad range of new electroactive materials used in corrosion prevention and techniques used to measure corrosion. Both materials scientists and engineers will find this book useful for understanding and preventing corrosion. Alternatives to traditional barriercoatings used to prevent or retard corrosion are also discussed. Although previously published books have focused on organic and inorganic barrier coatings to prevent corrosion, this book focuses exclusively on electroactive polymers and their performance in retarding corrosion. Electroactivepolymers represent a new, environmentally friendly approach to corrosion prevention.

Table of Contents

Preface	xi
Introduction
An Introduction to Corrosion Protection Using Electroactive Polymers	2	(16)
P. Zarras
J. D. Stenger-Smith
Corrosion-Protective Coatings from Electroactive Polymers	18	(16)
Karen Gebert Thompson
Brian C. Benicewicz
Effective Corrosion Protection with the Organic Metal Polyaniline: Basic Principles and Recent Progress	34	(42)
Bernhard Wessling
Theoretical Section
Iron-Polyaniline Interfaces: Implications for Corrosion Protection	76	(14)
M. Fahlman
X. Crispin
J. A. O. Smallfield
R. Lazzaroni
J. L. Bredas
S. Li
Y. Wei
A. J. Epstein
Assessment of Electronic Factors Necessary for Corrosion Inhibition: An Analysis of Substituted Aniline Oligomers	90	(13)
Susan A. Jansen
Lawrence T. Sein, Jr.
James M. Varnum
Thanh Duong
Yen Wei
Factors Influencing the Performance of Inherently Conducting Polymers as Corrosion Inhibitors: The Dopant	103	(23)
Gordon G. Wallace
Anton Dominis
Geoffrey M. Spinks
Dennis E. Tallman
Synthesis Section
Synthesis and Characterization of Polymers with Oligoaniline Side Chains	126	(14)
Ru Chen
Brian C. Benicewicz
Improved Synthesis and Corrosion Properties of Poly(bis-(dialkylamino)phenylene vinylene)s (BAMPPV)	140	(16)
Nicole Anderson
David J. Irvin
Jennifer A. Irvin
John D. Stenger-Smith
Andrew Guenthner
Cindy Webber
Peter Zarras
Synthesis and Study of Phenyl-Capped Tetraaniline as an Anticorrosion Additive	156	(12)
Wanjin Zhang
Youhai Yu
Liang Chen
Huaping Mao
Ce Wang
Yen Wei
Additive Section
Sulfur-Quinone Polyurethanes and the Protection of Iron against Corrosion	168	(7)
Yongqi Hu
A. Brent Helms
David E. Nikles
Rahul Sharma
Shane C. Street
Garry W. Warren
Dehua Yang
Amine-Quinone Polyimides for Protecting Iron against Corrosion	175	(7)
Mijeong Han
Huimin Bie
David E. Nikles
G. W. Warren
Lignosulfonic Acid-Doped Polyaniline (LIGNO-PANI™) for the Corrosion Prevention of Cold-Rolled Steel	182	(14)
B. C. Berry
A. U. Shaikh
T. Viswanathan
Electroactive Polymer for Corrosion Inhibition of Aluminum Alloys	196	(12)
S. C. Yang
R. Brown
R. Racicot
Y. Lin
F. McClarnon
Analytical Section
Corrosion Protection Properties of Coatings of the Epoxy-Cured Aniline Oligomers Based on Salt Spray and UV-Salt Fog Cyclic Tests	208	(20)
Yen Wei
Homayoun Jamasbi
Shuxi Li
Shan Cheng
Susan A. Jansen
Lawrence T. Sein, Jr.
Wanjin Zhang
Ce Wang
Scanning Vibrating Electrode Studies of Electroactive Conducting Polymers on Active Metals	228	(26)
Dennis E. Tallman
Jie He
Victoria Johnston Gelling
Gordon P. Bierwagen
Gordon G. Wallace
Solvent-Free Polyaniline Coating for Corrosion Prevention of Metal	254
Xianhong Wang
Jinlong Lu
Ji Li
Xiabin Jing
Fosong Wang
Indexes
Author Index	271
Subject Index	273