Handbook of Organopalladium Chemistry for Organic Synthesis, 2 Volume Set

by Editor: Ei-ichi Negishi (Purdue Univ., West Lafayette, Indiana); Associate Editor: Armin de Meijere

• ISBN13: 9780471473800
• ISBN10: 0471473804
• Format: eBook
• Publisher: WILEY

Summary

Organized to provide maximum utility to the bench synthetic chemist. The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. Contributors include over 24 world authorities in the field.

Table of Contents

Preface

Contributors

Abbreviations

Volume 1

Introduction And Background

Historical Background of Organopalladium Chemistry

Fundamental Properties of Palladium and Patterns of the Reactions of Palladium and Its Complexes

Palladium Compounds: Stoichiometric Preparation, In Situ Generation, And Some Physical And Chemical Properties

Background for Part II 39

Pd(0) and Pd(II) Compounds without Carbon-Palladium Bonds

Metallic Palladium and Its Mixtures

Palladium Complexes Containing Halogen and Oxygen Ligands

Pd(0) and Pd(II) Complexes Containing Phosphorus and Other Group 15 Atom Ligands

Pd(0) and Pd(II) Complexes Containing Sulfur and Selenium Ligands

Hydridopalladium Complexes

Palladium Complexes Containing Metal Ligands

Chiral Pd(0) and Pd(II) Complexes

Organopalladium Compounds Containing Pd(0) and Pd(II)

General Discussion of the Methods of Synthesis and in-Situ Generation of Organopalladium Compounds

Stoichiometric Synthesis and Some Notable Properties of Organopalladium Compounds of Pd(0) and Pd(II)

Palladium Complexes Containing Pd(I), Pd(III), or Pd(IV)

Palladium-Catalyzed Reactions Involving Reductive Elimination

Background for Part III

Palladium-Catalyzed Carbon-Carbon Cross-Coupling

Overview of the Negishi Protocol with Zn, Al, Zr, and Related Metals

Overview of the Suzuki Protocol with B

Overview of the Stille Protocol with Sn

Overview of Other Palladium-Catalyzed Cross-Coupling Protocols

Palladium-Catalyzed Aryl-Aryl Coupling

Palladium-Catalyzed Alkenyl-Aryl, Aryl-Alkenyl, and Alkenyl-Alkenyl Coupling Reactions

Heteroaromatics via Palladium-Catalyzed Cross-Coupling

Palladium-Catalyzed Alkynylation

Sonogashira Alkyne Synthesis

Palladium-Catalyzed Alkynylation with Alkynylmetals and Alkynyl Electrophiles

Palladium-Catalyzed Cross-Coupling between Allyl, Benzyl, or Propargyl Groups and Unsaturated Groups

Palladium-Catalyzed Cross-Coupling between Allyl-, Benzyl-, or Propargylmetals and Allyl, Benzyl, or Propargyl Electrophiles

Palladium-Catalyzed Cross-Coupling Involving Alkylmetals or Alkyl Electrophiles

Palladium-Catalyzed Cross-Coupling Involving Saturated Alkylmetals

Reactions between Homoallyl-, Homopropargyl-, or Homobenzylmetals and Alkenyl or Aryl Electrophiles

Palladium-Catalyzed Cross-Coupling Involving alpha;-Hetero-Substituted Organic Electrophiles

Palladium-Catalyzed Cross-Coupling with Acyl Halides and Related Electrophiles

Palladium-Catalyzed Cross-Coupling with Other alpha;-Hetero-Substituted Organic Electrophiles

Palladium-Catalyzed Cross-Coupling Involving alpha;-Hetero-Substituted Organometals

Palladium-Catalyzed Cross-Coupling Involving Metal Cyanides

Other alpha;-Hetero-Substitu

Table of Contents provided by Publisher. All Rights Reserved.