Handbook of Ring-Opening Polymerization

by Dubois, Philippe; Coulembier, Olivier; Raquez, Jean-Marie

• ISBN13: 9783527319534
• ISBN10: 3527319530
• Edition: 1st
• Format: Hardcover
• Copyright: 2009-03-02
• Publisher: Wiley-VCH

Summary

This comprehensive, truly one-stop reference discusses monomers, methods, stereochemistry, industrial applications and more. Chapters written by internationally acclaimed experts in their respective fields cover both basic principles and up-to-date information, ranging from the controlled ring-opening polymerization methods to polymer materials of industrial interest. All main classes of monomers including heterocyclics, cyclic olefins and alkynes, and cycloalkanes, are discussed separately as well as their specificities regarding the ring-opening polymerization techniques, the mechanisms, the degree of control, the properties of the related polymers and their applications. The two last chapters are devoted to the implementation of green chemistry in ring-opening polymerization processes. Of much interest to chemists in academia and industry.

Author Biography

Philippe Dubois received his PhD degree from University of Li+¿ge. In 1997 he moved to University of Mons-Hainaut (UMH) where he obtained the chair of macromolecular chemistry and directed the Laboratory of Polymeric and Composite Materials. He has co-authored about 350 publications and is co-inventor of 40 patents. He co-edited 5 books. In 2007 he became Director of of The Center of Innovation and Research in Materials and Polymers (CIRMAP) at UMH. He is currently past-president of the Belgian Royal Chemical Society (president in 2006-2007) and scientific director of Materia Nova research center in Mons.

Olivier Coulembier received his PhD degree from University of Mons-Hainaut (Belgium) in 2005 and joined the University of Stanford (United States) for his postdoctoral research in 2006. He is currently Postdoral Researcher by Belgian F.N.R.S. in the Laboratory of Polymeric and Composite Materials (LPCM) of Professor Philippe Dubois at University of Mons-Hainaut. His main activities are focused on the (non)organometallic ring-opening polymerization of cyclic monomers. He has authored 20 scientific papers in international journals.

Jean-Marie Raquez works in the Laboratory of Polymeric and Composites Materials (Professor P. Dubois) at University of Mons-Hainaut (UMH) in Mons, Belgium. He has authored 12 scientific papers and 5 US patents in Materials Technology including macromolecular synthesis and reactive processing.

Table of Contents

Thermodynamics and kinetics of ring-opening polymerization (ROP)

General mechanisms in ROP Silicium containing polymers

Sulfur-nitrogen-phosphorous containing polymers

Polymerization of depsipeptides, cyclic urethanes and ureas

Polyethers and polyoxazolines

Polyamides Metathesis polymerization of olefins and polymerization of alkynes

Polyesters from -lactones Polyesters from dilactones

Polyesters from large lactones Polyanhydrides and polycarbonates

Polymerization of cycloalkanes

Metal-free catalysis in ROP

Enzyme-mediated ROP

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