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9783527344772

Metal Nano 3D Superlattices Synthesis, Properties, and Applications

by
  • ISBN13:

    9783527344772

  • ISBN10:

    3527344772

  • Edition: 1st
  • Format: Hardcover
  • Copyright: 2023-01-10
  • Publisher: Wiley-VCH
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Summary

Metal Nano 3D Superlattices

Unique view on producing metal nano 3D superlattices by differing their morphologies, crystalline structures, chemical, and physical properties

After presenting an overview on the various factors involved in producing metal 3D superlattices called supracrystals by differing their morphologies, crystalline structures, chemical, physical, and intrinsic properties, Metal Nano 3D Superlattices: Synthesis, Properties, and Applications reveals the existence of new materials with unexpected properties. Readers will gain insight into the various approaches on the production and on the specific properties of nanocrystals self-assembled in 3D superlattices also called colloidal crystals, supra or super crystals. These properties open up new avenues of research and potentially aiding in major progress. Overall, the work reviews the progress of and gives perspective on assembled nanocrystals, with a concentrated focus on self-assemblies of metal nanocrystals.

Sample topics covered by the highly qualified and internationally awarded author include:

  • Syntheses of nanocrystals with low size distribution.
  • The wide variety of self-assembled nanocrystals in 3D superlattices strongly depends on an impressive number of parameters.
  • The intrinsic chemical and physical properties of 3D superlattices of nanocrystals opens the way to the discovery of unexpected properties. This concerns growth processes, coherent breathing of in 3D superlattices, electron transport through thick assemblies, etc.
  • A strong analogy between atomic crystals and 3D superlattices of nanocrystals emerge: incompressible nanocrystals and coating agents act as mechanical springs holding together the nanocrystals and replace respectively, in atomic crystals, atoms and atomic bonds.
  • The intrinsic chemical and physical properties of nanocrystals and their assemblies depend on their crystalline structures called nanocrystallinity.
  • Collective properties due to dipolar interactions between nanocrystals are pointed out.
  • Water soluble suprastructures act as efficient universal nanoheaters. In addition, reconstruction near the cytoplasmic membrane in tumor cells of nanocrystal self-assemblies takes place opening various biomedical applications.
  • The physical (optical, magnetic, electronic, vibrational) properties of isolated nanocrystals remain present in addition to the intrinsic and collective properties. This allows to benefit from the unique properties of nanocrystals while avoiding their potential size-related risks in future applications.

Metal Nano 3D Superlattices offers a deep dive into their synthesis, chemical and physical properties, and applications and is an essential resource for inorganic chemists, materials scientists, physical chemists, surface chemists, and medicinal chemists conducting research related to or involved in the practical application of the topics covered within.

Author Biography

Marie-Paule Pileni is a Distinguished Professor at University P&M Curie and Senior Researcher in Nuclear and Environmental Center, France. She is a member (1999- at present) and chair (2004-2010) of Institut Universitaire de France, IUF, which favors the development of high quality research and interdisciplinary projects among French universities. She has published more than 450 articles with H-index of 73. Over her career, she received significant awards and prizes: the Langmuir award of the American Chemical Society, the lecture award of the Japanese Chemical Society, the research award of the Alexander von Humboldt Foundation in Germany, the Descartes-Huygens prize of the Royal Netherlands Academy of Arts, Science and Emila Valori prize from the French Academy of Sciences, Catalán-Sabatier Lectureship award from the Royal Society of Chemistry of Spain, Life Achievement award from Journal Colloid Interface Science, Pierre Süe prize from the French Chemical Society and Chalmers Lecture award. In addition, she received the French citation award laureate from the Institute of Scientific Information for most quoted French scientist between 1981 and 1998. She is a member of various European scientific academies. She is a commandor in 'l' Ordre National de la Légion d'Honneur'.

Table of Contents

1. Analogy between atomic crystals and supracrystals
2. Nanocrystals Syntheses
3. Chemical and Physical properties of metal nanocrystals differing by their nanocrystallinities
4. Supracrystal growth processes.
5. Collective properties (optical, magnetic, vibrational) due to dipolar interactions of 2D and 3D supracrystals
6. Intrinsic properties of supracrystals
7. Elastic properties of supracrystals
8. 3D self assemblies of supracrystals in aqueous solution
9. Encapsulation of nanocrystals into liposomes
10. Potential application of such assemblies

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