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Preface. | |
List of Contributors. | |
Mechanistic Aspects of Metal-Catalyzed C,C- and C,X-Bond-Forming Reactions | |
Mechanisms of Cross-Coupling Reactions. | |
Formation of C,C-Bonds in the Palladium-Catalyzed ¿-Arylation of Carbonyl Compounds and Nitriles. | |
Key Intermediates in the Formation of C-X (X = N, O, S) bonds in Metal-Catalyzed Reactions 25 | |
Reductive Elimination of C-N, C-O, and C-S Bonds From Organopalladium(II) Complexes. | |
Summary and Outlook. | |
Abbreviations. | |
References. | |
Metal-Catalyzed Cross-Coupling Reactions of Organoboron Compounds with Organic Halides | |
Introduction. | |
Advances in the Synthesis of Organoboron Compounds. | |
Reaction Mechanism. | |
Reaction Conditions. | |
Side Reactions. | |
Reactions of B-Alkyl Compounds. | |
Reactions of B-Alkenyl Compounds. | |
Reactions of B-Aryl Compounds. | |
Reactions of B-Allyl and B-Alkynyl Compounds. | |
Reactions Giving Ketones. | |
Dimerization of Arylboronic Acids. | |
N-, O-, and S-Arylation. | |
Abbreviations. | |
References. | |
Organotin Reagents in Cross-Coupling Reactions | |
Introduction. | |
Mechanism and Methodology. | |
Natural Product Synthesis. | |
Organic Synthesis. | |
Polymer Chemistry. | |
Inorganic Synthesis. | |
Conclusions. | |
Experimental Procedures. | |
Abbreviations. | |
References. | |
Organosilicon Compounds in Cross-Coupling ReactionsScott E. Denmark | |
Introduction. | |
Modern Organosilicon-Cross-Coupling. | |
Mechanistic Studies in Silicon-Cross-Coupling. | |
Applications to Total Synthesis. | |
Summary and Outlook. | |
Experimental Procedures. | |
Abbreviations. | |
References. | |
Cross-Coupling of Organyl Halides with Alkenes: The Heck Reaction | |
Introduction. | |
Principles. | |
Cascade Reactions and Multiple Couplings. | |
Related Palladium-Catalyzed Reactions. | |
Enantioselective Heck-Type Reactions. | |
Syntheses of Heterocycles, Natural Products and Other Biologically Active Compounds Applying Heck Reactions. | |
Carbopalladation Reactions in Solid-Phase Syntheses. | |
The Heck Reaction in Fine Chemicals Syntheses. | |
Conclusions. | |
Experimental Procedures. | |
Acknowledgments. | |
Abbreviations and Acronyms. | |
References. | |
Cross-Coupling Reactions to sp Carbon Atoms | |
Introduction. | |
Alkynylcopper Reagents. | |
Alkynyltin Reagents. | |
Alkynylzinc Reagents. | |
Alkynylboron Reagents. | |
Alkynylsilicon Reagents. | |
Alkynylmagnesium Reagents. | |
Other Alkynylmetals. | |
Concluding Remarks. | |
Experimental Procedures. | |
Acknowledgments. | |
Abbreviations and Acronyms. | |
References. | |
Carbometallation Reactions | |
Introduction. | |
Carbometallation Reactions of Alkynes. | |
Carbometallation Reactions of Alkenes. | |
Zinc-Enolate Carbometallation Reactions. | |
Carbometallation Reactions of Dienes and Enynes. | |
Carbometallation Reactions of Allenes. | |
Conclusions. | |
Experimental Procedures. | |
Acknowledgments. | |
References. | |
Palladium-Catalyzed 1,4-Additions to Conjugated Dienes | |
Introduction. | |
Palladium(0)-Catalyzed Reactions. | |
Palladium(II)-Catalyzed Reactions. | |
References. | |
Cross-Coupling Reactions via ¿-Allylmetal In | |
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