Metal-Containing and Metallo-supramolecular Polymers and Materials

by Schubert, Ulrich S.; Newkome, George R.; Manners, Ian

• ISBN13: 9780841239296
• ISBN10: 0841239290
• Format: Hardcover
• Copyright: 2006-03-23
• Publisher: American Chemical Society

Summary

The last few years have brought a dramatic boom in the area of metal-containing systems and materials, both in supramolecular and polymer chemistry as well as nanoscience. Besides synthetic advances, a major increase in knowledge regarding metallopolymer characterization has been apparent. Moreover, recently a growing interest in the application of these materials can be seen. Potential applications are identified in the areas of smart or intelligent materials, systems with special photochemical and photophysical properties (such as LEDs or solar cells), nanoscience, sensory materials, as well as materials with very special thermal and mechanical properties. This symposium series book covers the complete range of metal-containing polymers and materials by first-hand articles from the world-leading groups. These include design, synthesis, characterization as well as selected applications.

Table of Contents

Preface	xiii
Metallosupramolecular Polymers
Dendronized Copper(I)-Metallopolymers	2	(15)
Julia Kubasch
Matthias Rehahn
A Comparative Study of Polymer Composition, Molecular Weight, and Counterion Effects on the Chelation of Bipyridine Macroligands to Iron(II)	17	(13)
Robert M. Johnson
Anne Pfister
Cassandra L. Fraser
Aqueous Metallosupramolecular Micelles with Spherical or Cylindrical Morphology	30	(13)
Jean-Francois Gohy
Bas G. G. Lohmeijer
Alexander Alexeev
Xiao-Song Wang
Ian Manners
Mitchell A. Winnik
Ulrich S. Schubert
Thermodynamics of 2,2':6',2''-Terpyridine--Metal Ion Complexation	43	(19)
Rainer Dobrawa
Pablo Ballester
Chantu R. Saha-Moller
Frank Wurthner
Grid Forming Metal Coordinating Macroligands: Synthesis and Complexation	62	(10)
Richard Hoogenboom
Jurriaan Huskens
Ulrich S. Schubert
Light-Active Metal-Based Molecular-Scale Wires	72	(14)
Anthony Harriman
Abderahim Khatyr
Sarah A. Rostron
Raymond Ziessel
Triads Containing Terpyridine--Ruthenium(II) Complexes and the Perylene Fluorescent Dye	86	(11)
Harald Hofmeier
Philip R. Andres
Ulrich S. Schubert
The Preparation of Metallosupramolecular Polymers and Gels by Utilizing 2,6-bis-(1'-Methyl-benzimidazolyl)Pyridine--Metal Ion Interactions	97	(16)
J. Benjamin Beck
Stuart J. Rowan
Thermal Stability, Rheology, and Morphology of Metallosupramolecular Polymers Based on bis-Terpyridine Ruthenium(II) Complexes	113	(13)
Harald Hofmeier
Marielle Wouters
Daan Wouters
Ulrich S. Schubert
Novel Block Copolymers with Terpyridine Pendant Groups	126	(15)
Gregory N. Tew
Khaled A. Aamer
Raja Shunmugam
Complexation Parameters of Terpyridine-Metal Complexes	141	(16)
Philip R. Andres
Harald Hofmeier
Ulrich S. Schubert
Poly[2-(Acetoacetoxy)Ethyl Methacrylate]-Based Hybrid Micelles	157	(11)
Theodora Krasia
Helmut Schlaad
Designing Supramolecular Porphyrin Arrays for Surface Assembly and Patterning of Optoelectronic Materials	168	(18)
Jayne C. Garno
Chang Xu
Griorgio Bazzan
James D. Batteas
Charles Michael Drain
Metallodendrimers
Metallodendrimers: Fractals and Photonics	186	(19)
Tae Joon Cho
Charles N. Moorefield
Pingshan Wang
George R. Newkome
Encapsulation Effects on Homogeneous Electron Self-Exchange Dynamics in Tris(Bipyridine) Iron-Core Dendrimers	205	(10)
Young-Rae Hong
Christopher B. Gorman
Extraction of Metal Nanoparticles from within Dendrimer Templates	215	(15)
Joaquin C. Garcia-Martinez
Orla M. Wilson
Robert W. J. Scott
Richard M. Crooks
Metallo Groups Linked to the Surface of Phosphorus-Containing Dendrimers	230	(14)
Jean-Pierre Majoral
Anne-Marie Caminade
Regis Laurent
Hyperbranched Polyynes-Containing Cobaltcarbonyls as Precursors to Nanostructured Magnetoceramics	244	(14)
Matthias Haußler
Jacky W. Y. Lam
Hongchen Dong
Hui Tong
Ben Zhong Tang
Syntheses and Nonlinear Optical Properties of Alkynylruthenium Dendrimers	258	(16)
Mark G. Humphrey
Clem E. Powell
Marie P. Cifuentes
Joseph P. Morrall
Marek Samoc
Organometallic Polymers, Materials, and Nanoparticles: Ferrocene-Containing Systems
Synthesis, Self-Assembly, and Applications of Polyferrocenylsilane Block Copolymers	274	(18)
Xiaosong Wang
Mitchell A. Winnik
Ian Manners
Carbanion-Pump Mediated Synthesis and Bulk Morphologies of Ferrocenyldimethylsilane--Methyl Methacrylate Diblock Copolymers	292	(14)
Christian Kloninger
Matthias Rehahn
Lithographic Patterning and Reactive Ion Etching of a Highly Metallized Polyferrocenylsilane	306	(14)
Scott B. Clendenning
Alison Y. Cheng
Ian Manners
Poly(ferrocenylsilane-block-methacrylate)s via Sequential Anionic and Atom Transfer Radical Polymerization	320	(14)
Mark A. Hempenius
Igor Korczagin
G. Julius Vancso
Synthesis and Layer-by-Layer Assembly of Water-Soluble Polyferrocenylsilane Polyelectrolytes	334	(22)
Zhuo Wang
Geoffrey A. Ozin
Ian Manners
Synthesis and an Bulk Morphology of Styrene-Ferrocenylsilane-Methyl Methacrylate Tri- and Pentablock Copolymers	356	(18)
Christian Kloninger
Uttam Datta
Matthias Rehahn
Organometallic Polymers, Materials, and Nanoparticles: Non-Ferrocene-Containing Systems
Evolution of Lowest Singlet and Triplet Excited States with Electronic Structure of Fluorene Group in Metal Polyyne Polymers	374	(18)
Wai-Yeung Wong
Ka-Ho Choi
Guo-Liang Lu
Li Liu
Jian-Xin Shi
Kok-Wai Cheah
Peptide Films on Surfaces: Preparation and Electron Transfer	392	(9)
G. A. Orlowski
H. B. Kraatz
Neutral and Cationic Cyclopentadienyliron Macromolecules Containing Azo Dyes	401	(15)
Alaa S. Abd-El-Aziz
Patrick O. Shipman
Ring-Collapsed Alternating Copolymerization of Organoarsenic Homocycles and Acetylenic Compounds	416	(13)
Kensuke Naka
Tomokazu Umeyama
Akiko Nakahashi
Yoshiki Chujo
Photodegradable Polymers Containing Metal-Metal Bonds Along Their Backbones: Mechanistic Study of Stress-Induced Rate Accelerations in the Photochemical Degradation of Polymers	429	(14)
Rui Chen
David R. Tyler
Spectroscopic and Liquid Crystal Properties of Phthalocyanine Macromolecules with Biomedical Applications	443	(14)
Ernie H. G. Langner
Wade L. Davis
Rebotsamang F. Shago
Jannie C. Swarts
Synthesis, Reactivity and Ring-Opening Polymerization of Sila-Metallacyclobutanes	457	(15)
Hemant K. Sharma
Keith H. Pannell
Luminescence Properties of Phosphine-Isocyanide Cu(I)- and Ag(I)-Containing Oligomers in the Solid State	472	(14)
Pierre D. Harvey
Eric Fournier
Facile Synthesis of High-Quality Large-Pore Periodic Mesoporous Organosilicas Templated by Triblock Copolymers	486	(14)
Wanping Guo
Jin-Woo Park
Chang-Sik Ha
Assembling Prussian Blue Nanoclusters along Single Polyelectrolyte Molecules	500	(14)
Anton Kiriy
Vera Bocharova
Ganna Gorodyska
Paul Simon
Ingolf Monch
Dieter Elefant
Manfred Stamm
Reactive Polymers Possessing Metallacycles in the Main Chain	514	(13)
Ikuyoshi Tomita
Coordination Compounds for Functional Nonlinear Optics: Enhancing and Switching the Second-Order Nonlinear Optical Responses	527	(14)
Inge Asselberghs
Michael J. Therien
Benjamin J. Coe
Jon A. McCleverty
Koen Clays
Author Index	541	(2)
Subject Index	543