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This book focuses on the new microspheres and new microcapsules especially designed and prepared for the applications in biotechnology and biopharmaceuticals, including bio-reaction, bio-separation, bio-formulation, bio-detection, and other new bio-applications. The book provides deep knowledge about the principle of design, preparation methods, and application results of new microsphere and microcapsules for each bio-application area; identifies problems that need to be studied further; and discusses future prospects.