Molecular Nanostructures : Proceedings of the International Winterschool on Electronic Properties of Novel Materials

by International Winter School on Electronic Properties of Novel material; Fink, Jorg; Mehring, Michael; Roth, Siegmar; Kuzmany, Hans; Kuzmany, Hans

• ISBN13: 9789810232610
• ISBN10: 9810232616
• Format: Hardcover
• Copyright: 1997-09-01
• Publisher: WORLD SCIENTIFIC PUB CO INC

Summary

This volume is the latest of the "Kirchberg-Proceedings". The previous 11 International Winterschools on Electronic Properties of Novel Materials, all held in Kirchberg, Austria, were devoted to conducting polymers, high temperature superconductors, fullerenes, and carbon nanotubes. Fullerenes and nanotubes are still in the center of interest, but the topic of the school and the proceedings is molecular nanostructures in general. The organizers have attempted to treat carbon nanostructures as a special case of molecular nanostructures, which also include silicon clusters, gold clusters, vanadium oxide tubes, and many others. The Winterschool provides a platform for reviewing and discussing new developments in the field of molecular nanostructures and their applications. Materials discussed include fullerenes, fullerene-derived structures, carbonaceous nanotubes, non-carbonaceous nanotubes, layer by layer systems, molecular clusters, new phases of carbon, endohedral compounds and related materials. The book aims to give an overview of the current status of fullerenes, carbon-nanotubes and related molecular nanostructures. The majority of the contributions present the latest results of experiments and calculations conducted in the field. However, about a dozen contain some degree of instructional material which even newcomers will benefit from.

Table of Contents

Preface	vii
MOLECULAR NANOSTRUCTURES	3	(52)
New Materials in the Nanoscale from Fullerenes, Silicon Clusters and Biomolecules	3	(11)
W. Andreoni
Nucleation and Growth of Diamond Crystals Inside Carbon Onions	14	(5)
F. Banhart
P.M. Ajayan
Ph. Redlich
Computations of Metal-Coated Fullerenes: C(60)Be(n)	19	(4)
Z. Slanina
F. Uhlik
L. Adamowicz
E. Osawa
Self-Organization of Fullerenes from Solution to Clathrate	23	(5)
D. Mihailovic
A. Mrzel
A. Hassanien
Fractal Fullerene Structures in Solutions	28	(5)
A. V. Eletskii
M. V. Okun
B.M. Smirnov
Metallic-Covalent Bonding Conversion in Boron-Based and Aluminum-Based Icosahedral Clusters and Cluster Solids	33	(6)
K. Kimura
Study of the Growth Mechanism of Carbon Clusters by Anion Photoelectron Spectroscopy	39	(4)
M. Kohno
T. Moriwaki
S. Suzuki
H. Shiromaru
Y. Achiba
Silicon Clusters in Solids and Novel Redox-Active Templated Materials	43	(4)
R. Nesper
NMR Studies of Si(46) Superconductors	47	(8)
Y. Maniwa
H. Sakamoto
H. Shimizu
H. Kawaji
S. Yamanaka
CHEMISTRY	55	(88)
Chemical Faraday Cages: The Inert Inner Surfaces of Strongly Bent sp^2-Carbon Networks and Fullerenes	55	(6)
A. Hirsch
H. Mauser
T. Clark
A Systematic Entry to Regular Multifunctionalization of the [60]-Fullerene	61	(7)
B. Krautler
Organic Chemistry of C(60): Synthesis and Applications	68	(5)
T. da Ros
M. Prato
M. Maggini
G. Scorrano
On the Structures and Properties of Heterofullerene Salts	73	(8)
K. Kordatos
C.M. Brown
K. Prassides
C. Bellavia-Lund
P. de la Cruz
F. Wudl
J.D. Thompson
A.N. Fitch
Recent Progress in the Theoretical Approach to Azafullerenes	81	(5)
A. Curioni
W. Andreoni
The Electronic Structure of C(59)N and its A(x)C(59)N (A=K,Rb,Cs) Salts from High Energy Spectroscopy	86	(6)
M.S. Golden
T. Pichler
M. Knupfer
R. Friedlein
S. Haffner
J. Fink
W. Andreoni
A. Curioni
M. Keshavarz-K
C. Bellavia-Lund
A. Sastre
J.-C. Hummelen
F. Wudl
Pulse ESR of Triplet States of the Fullerene Dimers (C(60)-Morpholine)(2) and (C(59)N)(2)	92	(4)
S. Knorr
A. Grupp
M. Mehring
B. Nuber
G. Schick
A. Hirsch
The C(60)-C(60)O System: A Source of New Fullerene Derivatives	96	(5)
A. Gromov
S. Ballenweg
W. Kratschmer
S. Giesa
S. Lebedkin
Raman and Infrared Signatures of C(120)O: Experiments and Theoretical Predictions	101	(5)
M. Krause
L. Dunsch
G. Seifert
A. Ayuela
A. Gromov
W. Kratschmer
R. Gutierrez
D. Porezag
Th. Frauenheim
Characterization of the Fullerene Derivative C(119)	106	(4)
A. Gromov
S. Ballenweg
S. Giesa
W. Kratschmer
S. Lebedkin
W.E. Hull
C-F Bond Dissociation Enthalpy of Fluorofullerenes and Their Anions	110	(4)
O.V. Boltalina
D.B. Ponomarev
L.N. Sidorov
X-Ray Diffraction Study of Fluorofullerenes: Effect of Fluorine Content	114	(4)
O.V. Boltalina
I. Gol'dt
T. Zatsepin
F.M. Spiridonov
S.I. Troyanov
L.N. Sidorov
R. Taylor
Ruthenium(II)/C(60) Based Donor-Bridge-Acceptor Dyad: Photoinduced Electron and Energy Transfer	118	(6)
D.M. Guldi
M. Maggini
S. Mondini
G. Scorrano
M. Prato
F. Paolucci
P. Ceroni
S. Roffia
Langmuir Films of Mono-, Di-, and Tetra-n-Octyl Adduct of C(60) at the Water-Air Interface	124	(4)
K. Noworyta
P. Kuran
R. Bilewicz
L. Dunsch
W. Kutner
The Optoelectronic Porperties of Fullerene -- Conjugated Polymer -- Conventional Polymer Guest-Host Systems	128	(4)
C.J. Brabec
N.S. Sariciftci
W. Graupner
G. Leising
F. Wudl
A.J. Heeger
Fullerene Core Star Polymers	132	(4)
S. Delpeux
N. Manolova
I. Rashkov
F. Beguin
Is there a Fullerene Future?	136	(7)
R. Taylor
C(60), C(70), C(84), .... , ONIONS	143	(30)
Molecular Dynamics Simulation of Fullerene Formation	143	(4)
I. Laszlo
Reaction Coordinate Analysis on the Excited Potential Surfaces of Fullerenes	147	(4)
P.R. Surjan
M. Kallay
G. Domotor
L. Stacho
M.I. Ban
Orientational Flip of C(60) Molecules on Metals Determined by XPD	151	(4)
A. Santaniello
R.G. Agostino
P. Aebi
R. Fasel
Thermally Modulated Optical Response of C(60) Thin Films in the Region of Absorption Edge	155	(4)
B. Handlirova
J. Humlicek
L. Bocanek
T. Nguyen Manh
H. Sitter
Surface Effects on the Electronic Structure of Solid C(60)	159	(4)
L. Udvardi
C(60)/C(70) Alloys -- A Model System for the Orientational Glass?	163	(4)
D. Havlik
W. Schranz
M. Haluska
J. Winter
H. Kuzmany
Excitation of Plasmons of Carbon Onions by Penetrating High Energy Electrons	167	(6)
T. Stockli
Z.L. Wang
J.-M. Bonard
W.A. de Heer
J.-P. Salvetat
P. Stadelmann
A. Chatelain
ENDOHEDRALS	173	(56)
Production and Investigation of N@C(60)	173	(3)
A. Weidinger
B. Pietzak
M. Waiblinger
T. Almeida Murphy
Carbon Nitride Films from Nitrogen Bombardment of C(60)	176	(4)
B. Pietzak
M. Waiblinger
M. Gossla
A. Weidinger
H. Jantoljak
C. Thomsen
N@C(60) as a Probe for Chemical Reactions on C(60)	180	(4)
B. Pietzak
M. Waiblinger
T. Almeida Murphy
A. Weidinger
M. Hohne
E. Dietel
A. Hirsch
IR Spectroscopy and HPLC Separation of Endohedral Li@C(60)	184	(5)
N. Krawez
R. Tellgmann
A. Gromov
W. Kratschmer
E.E.B. Campbell
Electronic Structure of Sc@C(82)	189	(4)
J. Schulte
M.C. Bohm
K.-P. Dinse
(13)C-NMR Structural Studies of Endohedral Metallofullerenes	193	(5)
T. Nakane
Z. Xu
E. Yamamoto
T. Kai
T. Tomiyama
H. Shinohara
Y. Kobayashi
Preparation and Characterization of Endohedral Gadolinium Fullerene	198	(5)
P. Kuran
L. Dunsch
M. Krause
A. Bartl
The Vibrational Spectroscopy of M@C(82) (M=La, Y): Raman, Far-Infrared, and Neutron Inelastic Scattering Results	203	(4)
S. Lebedkin
B. Renker
R. Heid
H. Rietschel
H. Schober
Resonant Photoelectron Spectroscopy and XANES from Endohedral La@C(82)	207	(4)
B. Kessler
S. Cramm
C. Schlebusch
W. Eberhardt
S. Suzuki
Y. Achiba
F. Esch
M. Barnaba
D. Cocco
The Electronic Structure of Tm(@)C(82)	211	(5)
T. Pichler
M.S. Golden
M. Knupfer
J. Fink
U. Kirbach
P. Kuran
L. Dunsch
EPR Study of Topoisomers of La@C(82) and La@C(90)	216	(4)
P. Schweitzer
K.-P. Dinse
Pulse ESR Investigation of M@C(82) (M=Sc, Y, La)	220	(4)
S. Knorr
A. Grupp
M. Mehring
U. Kirbach
A. Bartl
L. Dunsch
Vibration of Atomic Nitrogen Inside C(60)	224	(5)
A. Grupp
B. Pietzak
M. Waiblinger
T. Almeida Murphy
A. Weidinger
E. Roduner
FULLERENE SALTS	229	(72)
Correlation Effects in Doped C(60) Compounds	229	(6)
O. Gunnarsson
E. Koch
R.M. Martin
F. Aryasetiawan
Quantum Monte-Carlo Calculations for Integer-Doped Fullerides	235	(4)
E. Koch
O. Gunnarsson
R. Martin
Synthesis of Multinary Fulleride Superconductors with Tunable Crystal Structure and Band Filling	239	(6)
Y. Iwasa
H. Shimoda
M. Kawaguchi
Y. Miyamoto
T. Mitani
Y. Maniwa
Electronic Transport in Single Crystal BaxC(60) Films Grown by Hot-Wall Epitaxy	245	(4)
T. Nguyen Manh
H. Sitter
D. Stifter
Kinetics of C(60) Intercalation by Potassium	249	(4)
W. Kempinski
L. Piekara-Sady
J. Stankowski
Distorted, Inequivalently-Charged C(60) Anions in Yb(2.75)C(60)	253	(5)
P.H. Citrin
E. Ozdas
S. Schuppler
A.R. Kortan
K.B. Lyons
Jahn-Teller Distortion of Fullerenes in A(4)C(60)	258	(4)
G.M. Bendele
C.A. Kuntscher
P.W. Stephens
ESR and NMR Studies on Li- and Na-Doped C(60) Compounds and Lithiated Carbon Nanotubes	262	(4)
S. Menu
H. Gaucher
J. Conard
P. Lauginie
A. Nozhov
V.A. Nalimova
Metallic Behavior of ABa(2)C(60) (A=K, Rb, Cs) Compounds	266	(4)
C. Goze
K.-F. Thier
M. Mehring
F. Rachdi
T. Yildirim
J.E. Fischer
NMR Studies of Sodium Fullerides	270	(5)
F. Rachdi
L. Hajji
T. Yildirim
J.E. Fischer
C. Goze
M. Mehring
Nuclear Spin Dynamics in the Model System [P(C(6)H(5))(4)](2)C(60)I	275	(4)
W. Schutz
A. Schilder
W. Bietsch
B. Gotschy
M. Schwoerer
Mean-Field Treatment of a Microscopic Magnetic Model of TDAE-C(60): Influence of a Dzyaloshinski-Moriya Type Interaction	279	(4)
C. Schindelin
High Field ESR and (1)H NMR in Powdered TDAE-C(70)	283	(4)
D. Arcon
R. Blinc
P. Cevc
G. Chouteau
Antiferromagnetic Resonance in TDAE-C(60)	287	(4)
R. Blinc
D. Arcon
P. Cevc
A. Omerzu
G. Chouteau
DC and RF Superconductive Response in the Fullerene Based Magnet TDAE-C(60)	291	(4)
M. Ricco
R. de Renzi
M. Bisbiglia
F. Bolzoni
G. Ruani
Microwave Conductivity of [TDAE]C(60) Reveals no Superconductivity	295	(6)
A. Schilder
W. Schutz
W. Bietsch
B. Gotschy
M. Schwoerer
POLYMERS	301	(74)
Electronic Structure and Energetics of Polymerized Fullerenes and Fullerides	301	(5)
S. Saito
Total Energy Calculations of Polyfulleride Ions	306	(4)
S. Pekker
G. Oszlanyi
G. Faigel
Metal-Insulator Phase Transition in AC(60): A Question of Dimensionality?	310	(5)
M. Fally
H. Kuzmany
Stability of the Charged (C(60))(n)^n- Oligomers with Various Length	315	(4)
J. Kurti
P. Rajczy
Antiferromagnetic Resonance in Rb(1)C(60)	319	(4)
M. Bennati
R.G. Griffin
S. Knorr
A. Grupp
M. Mehring
Structure and Dynamics of the RbC(60) Metastable Phases -- A NMR Investigation	323	(5)
K.-F. Thier
M. Schwaderer
M. Mehring
F. Rachdi
Role of Relative Orientation of Neighboring C(60) Chains in the Electronic Properties of the A(1)C(60) Polymers	328	(5)
V. Brouet
H. Alloul
A. Janossy
L. Forro
Electrical Transport, Thermoelectric, and Structural Measurements of Polymerized AC(60) (A=K,Rb) Under Zero and Applied Pressure	333	(4)
J. Hone
K. Khazeni
M. Muno
V. Crespi
J. Nguyen
R. Jeanloz
M.L. Cohen
A. Zettl
Polymeric Ground State of Na(2)RbC(60): Effect of Charge State on Bonding Geometry	337	(6)
G.M. Bendele
P.W. Stephens
K. Prassides
K. Vavekis
K. Kordatos
K. Tanigaki
Two-Dimensional Polymer Structure of Na(4)C(60)	343	(5)
G. Oszlanyi
G. Faigel
G. Baumgartner
L. Forro
Pressure Polymerized C(60) Single Crystals: First X-Ray Diffraction Results	348	(5)
P. Launois
R. Moret
P.-A. Persson
B. Sundqvist
Pressure and Charge Induced Polymerization of C(60): A Comparative Study of Lattice Vibrations	353	(4)
B. Renker
R. Heid
H. Schober
Structural Analysis of Phototransformed C(60) by Vibrational Spectroscopy	357	(4)
B. Burger
H. Kuzmany
T.M. Nguyen
H. Sitter
M. Walter
K. Martin
K. Mullen
Optical Investigation of Pressure Modified C(60)	361	(4)
M.E. Kozlov
M. Tokumoto
K. Yakushi
High-Resolution Thermal Expansion of High-Pressure Polymerized and `Normal' C(60) from 10K to 500K: Kinetics of Depolymerization	365	(4)
P. Nagel
C. Meingast
P.-A. Persson
B. Sundqvist
Doping of Rhombohedral Pressure Polymerized C(60) with Alkali Metals	369	(6)
C. Kugler
J. Winter
H. Kuzmany
Y. Iwasa
NANOTUBES	375	(116)
Controlled Production of Nanotubes Via Pyrolytic Techniques	375	(6)
M. Terrones
N. Grobert
J. Olivares
K. Kordatos
W.K. Hsu
J.P. Hare
P.D. Townsena
K. Prassides
H.W. Kroto
D.R.M. Walton
H. Terrones
J.P. Zhang
A.K. Cheetham
The Electrochemical Formation of Nanowires	381	(5)
W.K. Hsu
M. Terrones
J.P. Hare
N. Grobert
H.W. Kroto
D.R.M. Walton
H. Terrones
A.I. Kirkland
Bundles of Carbon Single Wall Nanotubes: Production by the Arc Discharge Technique and Characterization	386	(5)
C. Journet
W.K. Maser
P. Bernier
A. Loiseau
M. Lamy de la Chapelle
P. Deniard
S. Lefrant
R. Lee
J.E. Fischer
Investigation of the Growth Mechanism of Carbon Nanotubes Produced by the Catalytic Method	391	(4)
P. Piedigrosso
A.G. Bosquillon
A. Fonseca
J. B. Nagy
Characteristics of Catalytic Carbon Nanotubes: Their Evolution After Thermal and Chemical Modifications	395	(4)
H. Gaucher
R. Pellenq
S. Bonnamy
F. Beguin
V. Nalimova
Y. Grillet
Boron Nitride Nanotubes: Synthesis and Tip Characterization	399	(6)
F. Willaime
A. Loiseau
X. Deschanels
N. Demoncy
G. Hug
C. Colliex
H. Pascard
They are Unique: The (10,10) Tube and Its Tip	405	(5)
A. Thess
R.E. Smalley
Purification of Carbon Nanotubes by Liquid-Phase Separation of a Kinetically Stable Colloidal Suspension	410	(4)
J.-M. Bonard
J.-P. Salvetat
T. Stora
F. Maier
T. Stockli
L. Forro
W.A. de Heer
A. Chatelain
Crystalline Ropes of Single Wall Carbon Nanotubes: Structure, Electronic Transport and Intercalation	414	(5)
J.E. Fischer
R.S. Lee
H.J. Kim
A. Thess
H. Dai
R.E. Smalley
Scanning Tunneling Microscopy of Carbon Nanotubes. Beyond the Image	419	(4)
L.P. Biro
J.B. Nagy
Ph. Lambin
S. Lazarescu
A. Fonseca
P.A. Thiry
A.A. Lucas
STM Manipulation of Individual Carbon Nanotubes	423	(4)
S. Curran
S. Roth
D. L. Carroll
Ph. Redlich
M. Ruthle
P.M. Ajayan
Topological Defects on Single-Walled Carbon Nanotubes: Dislocations, Burgers Vectors, Mobilities	427	(4)
P. Lauginie
J. Conard
Morphology and Electronic Structure of Doped Fullerene Nanostructures	431	(4)
P. Byszewski
J. Radomska
E. Mizera
H. Lange
A. Huczko
Electronic Properties of Single Wall Carbon Nanotubes	435	(4)
P. Petit
E. Jouguelet
N. Parizel
J.E. Fischer
A. Thess
R.E. Smalley
Electronic Transport and Magnetic Properties of Carbon Nanotubes	439	(4)
A. Fujiwara
F. Katayama
K. Tomiyama
H. Ootoshi
H. Suematsu
M. Yumura
K. Uchida
Magnetotransport in Bundles of K-Intercalated Helicoidal Carbon Nanotubes	443	(4)
M. Baxendale
V.Z. Mordkovich
S. Yoshimura
R.P.H. Chang
Vibrational Spectroscopy of Single Wall Carbon Nanotubes	447	(4)
B. Burger
H. Kuzmany
A. Thess
R.E. Smalley
Raman-Active Vibrational Modes in Pristine and Doped Carbon Nanotube Bundles	451	(8)
P.C. Eklund
A.M. Rao
Raman Spectroscopy on Carbon Nanotubes	459	(4)
H. Jantoljak
C. Thomsen
S. Curran
S. Roth
W. Maser
C. Journet
P. Bernier
Raman Studies of Singlewalled Carbon Nanotubes Elaborated by the Electric Arc Discharge Technique	463	(4)
M. Lamy de la Chapelle
S. Lefrant
C. Journet
W. Maser
P. Bernier
A. Loiseau
Electronic Properties of Individual Single-Wall Carbon Nanotubes: Transport and STM Results	467	(5)
C. Dekker
S.J. Tans
M.H. Devoret
L.J. Geerligs
R.J.A. Groeneveld
L.C. Venema
J.W.G. Wildoer
A.R.M. Verschueren
A. Bezryadin
A. Thess
H. Dai
R.A. Smalley
Quantum Transport in a Multiwalled Carbon Nanotube	472	(5)
L. Langer
V. Bayot
E. Grivei
J.-P. Issi
L. Stockman
C. van Haesendonck
Y. Bruynsereade
J.P. Heremans
C.H. Olk
Boron-doped Nanotubes: Density of States from Tunneling Spectroscopy	477	(5)
D.L. Carroll
P. Kinlen
S. Raman
Ph. Redlich
M. Ruhle
X. Blase
J.-C. Charlier
S. Curran
S. Roth
P.M. Ajayan
Exceptionally High Young's Modulus for Individual Carbon Nanotubes: Comparing Theory to Observations	482	(9)
E.G. Gamaly
APPLICATIONS	491	(50)
Field Emission Stability of Single Carbon Nanotubes Tips and Carbon Nanotube Films	491	(4)
J.-M. Bonard
F. Maier
T. Stockli
J.-P. Salvetat
L. Forro
W.A. de Heer
A. Chatelain
Synthesis, Characterization and Properties of Catalytically Grown Graphite Nanostructures	495	(5)
N.M. Rodriguez
Synthesis of Amorphous Carbon and Nanocrystalline Diamond by Fullerene Plasma Deposition	500	(6)
H.-G. Busmann
U. Brauneck
H.-W. David
S. Dieckhoff
S. Boseck
Structure and Properties of 3D-Polymerized C(60): Comparison with Diamond and C(70)	506	(5)
V.D. Blank
S.G. Buga
G.A. Dubitsky
N.R. Serebryanaya
S.N. Sulyanov
M.Yu. Popov
Unoccupied Density of States of Commercially Used Organic Photoreceptors Doped with C(60)	511	(4)
C. Schlebusch
J. Morenzin
B. Kessler
S. Cramm
W. Eberhardt
M. Biermann
M. Lutz
Self-Assembly of Fullerene Monolayers for Optoelectronic Applications	515	(4)
C. Kallinger
A. Haugeneder
U. Lemmer
J. Feldmann
H. Hong
M. Tarabia
D. Davidov
E. Harth
M. Walter
U. Scherf
A. Gugel
K. Mullen
Molecular Engineering of Sol-Gel Materials Containing Fullerence for Optical Limiting	519	(5)
S. Signorini
M. Meneghetti
R. Bozio
M. Maggini
G. Scorrano
M. Prato
G. Brusatin
M. Guglielmi
C(60) Aggregates and Nanoscale Carbon Particles	524	(4)
K. Suzuki
J.S. Ahn
Y. Iwasa
A.Q. He
N. Ootuka
T. Mitani
Fullerenes in Membranes -- Structural and Dynamical Effects of Lipophilic C(60) Derivatives in Phospholipid Bilayers	528	(5)
M. Hetzer
S. Bayerl
T.M. Bayerl
X. Camps
O. Vostrovsky
A. Hirsch
Magnetic Resonance of Amorphous Carbon Thin Films	533	(4)
D. Arcon
P. Cevc
R. Blinc
I. Pocsik
M. Koos
Z. Trontelj
Z. Jaglicic
Synchrotron Irradiation of Fullerenes Used for a Pure-Carbon Lithography	537	(4)
H. Kramer
R. Baumann
J. Bargon
J. Hormes
H. Zumaque-Diaz
G.A. Kohring
Author Index	541