Part 1

by Claridge, R. F. C. (CON); Farley, Robert D. (CON); Marque, Sylvain (CON); Rowlands, Christopher Charles (CON); Tordo, Paul (CON)

• ISBN13: 9783540432746
• ISBN10: 3540432744
• Format: Hardcover
• Copyright: 2008-10-27
• Publisher: Springer Nature

Summary

Volume II/26 supplements the previous compilations II/l, II/9 and II/17 of the magnetic properties of free radicals. Due to the still rapid growth of the field and the necessary inclusion of new subjects the volume is divided into subvolumes which will appear in fast succession. Together with the earlier publications volume II/26 offers an up-to-date and comprehensive survey and collection of structures and data on the important chemical intermediates, namely radicals, polyradicals and related species such as carbenes. As before the species have been grouped according to chemical aspects. For each group of substances the literature has been compiled and extracted by experts in the fields. For the reader s convenience an index of substances follows in the last subvolume.

Table of Contents

Introduction
General introduction	p. 1
Definition and substances	p. 1
Magnetic properties	p. 1
Arrangements of the tables	p. 3
Monographs, reviews and important conference proceedings	p. 4
Data
Phosphorus-centered organic radicals and related radical ions	p. 7
Introduction	p. 7
General remarks	p. 7
Formulae and structure	p. 7
Reviews	p. 8
Remarks	p. 8
Phosphinyl radicals X2P• and related species	p. 9
Phosphonyl (X2P•=O) and thiophosphonyl (X2P•=S) radicals	p. 22
Phosphoranyl radicals X4P•, including related species	p. 29
Phosphoniumyl cation radicals X3P•+, phosphine dimer cation radicals X3P•P+X3, phosphate anion radicals, and related species	p. 52
Miscellaneous	p. 63
References for 13	p. 79
Review articles	p. 79
References for 13.2 to 13.6	p. 79
Radicals centered on other heteroatoms	p. 83
Introduction	p. 83
Sulfur-, selenium-, tellurium-centered radicals	p. 84
Thiyl radicals of the type RS• R-S•R, R-S•-R2	p. 84
Sulfinyl radicals of the type R-S•=O	p. 87
Sulfonyl radicals of the type RS•O2	p. 89
Sulfuranyl radicals of the type X-S•-R2, X2-S•-R, S•X3, S•X4	p. 92
Disulfide radicals of the type R-S-S•	p. 93
Cation radicals	p. 94
Cation radicals of the type R2S•+, RPS•+ (incl. Se, Te)	p. 94
Cation radicals of the type RS-SR•+	p. 96
Cation radicals of the type R2S-O•+, R2S-O2•+, and R-S•+-N-R	p. 98
Anion radicals	p. 100
Anion radicals of the type R=S•−, <$>{{\rm RSH}_2}^{\bullet -}<$>, R3S•− (incl. Se, Te)	p. 100
Anion radicals of the type RS-SR•−	p. 106
Anion radicals of the type RS-X•−, RS-O•−, <$>{\hbox{RS-O}_2}^{\bullet -}<$> (incl. Se, Te)	p. 109
Silicon-centered radicals and related radical ions	p. 111
Silyl radicals X3Si•	p. 111
Silyl radicals from polysilanes	p. 119
Silicon-centered anion radicals	p. 121
Silicon-centered anion radicals from polysilanes	p. 122
Silicon-centered cation radicals	p. 123
Germanium-centered radicals and related radical ions	p. 129
Germyl radicals X3Ge•	p. 129
Germanium-centered anion radicals	p. 130
Germanium-centered cation radicals	p. 131
Tin-centered radicals and related radical ions	p. 132
Stannyl radicals X3Sn•	p. 132
Tin-centered anion radicals	p. 133
Tin-centered cation radicals	p. 134
Boron-centered radicals and related radical ions	p. 135
Boryl radicals X3B•	p. 135
Boron-centered anion radicals	p. 138
Boron-centered cation radicals	p. 138
Aluminum-centered radicals and related radical ions	p. 139
Aluminum-centered neutral radicals	p. 139
Aluminum-centered anion radicals	p. 145
Gallium-centered radicals and related radical ions	p. 146
Gallium-centered neutral radicals	p. 146
Gallium-centered radical anions	p. 146
Mercury-centered radicals and related radical ions	p. 148
Cation radicals	p. 148
References for Chapter 14	p. 151
Organic anion radicals with the exception of semiquinones	p. 155
Introduction	p. 155
General remarks	p. 155
Coverage	p. 156
Ordering	p. 156
Reviews and books	p. 156
Hydrocarbon and substituted hydrocarbon anion radicals	p. 157
Hydrocarbon radical anions	p. 157
Substituted compounds	p. 194
Substituted radical anions	p. 194
Perfluoro and perchloro substituted radical anions	p. 207
Substituted fluorenones	p. 209
Anion radicals from heterocycles	p. 214
Oxygen containing heterocycles	p. 214
Furan based heterocycles	p. 214
Arylfurans	p. 214
Nitrofurans	p. 215
Arylbenzylfurans	p. 216
Bromonitrodioxanes	p. 217
Oxoporphycenes	p. 218
Nitrogen containing heterocycles	p. 219
Halegenoimidazoles	p. 219
Pyrazines and pyrazinophanes	p. 220
Phenanthroline and phenanthroline based platinum complexes	p. 221
Pyridine based heterocycles	p. 223
Bipyridyls	p. 223
Dipyridylacetylenes	p. 223
Porphycenes	p. 224
Pyrimidines	p. 227
Diphenyl quinoxaline	p. 227
Boron substituted nitrogen containing heterocycles	p. 227
Indolines	p. 231
Sulphur containing heterocycles	p. 233
Thiophenes and polythiophenes	p. 233
Dicyanomethylidenethiopyrans	p. 234
Weitz type S-donors	p. 235
Phosphorus containing heterocycles	p. 237
Selenium and tellurium containing heterocycles	p. 238
Heterocycles with two or more different heteroatoms	p. 239
Anion radicals from nitro compounds	p. 240
Anion radicals from carbonyl compounds	p. 254
Esters and thioesters	p. 254
Arylesters	p. 254
Thioesters	p. 263
Oxocarbothioate and dithioate esters	p. 264
Aldehydes, ketones and their thio analogs	p. 269
Aliphatic aldehydes and ketones	p. 269
Furyl and thienyl aldehydes and ketones	p. 271
Tropones	p. 279
Benzene dicarbaldehydes	p. 280
Thiopyrane-2-thiones	p. 281
Silanones	p. 282
Semidiones	p. 283
Ethanediones	p. 283
Cyclobutanediones	p. 284
But-2-ene-1,4-diones	p. 285
Thiadiazoloquinoxalinediones	p. 287
Hypericin	p. 288
Dithioledithione	p. 288
Diones derived from carbohydrates	p. 289
Acid anhydrides and derivatives	p. 290
Anion radicals from azo compounds	p. 291
Aliphatic azoalkenes	p. 291
Open chain azoalkenes	p. 291
Cyclic azoalkenes	p. 292
Azopolycycloalkenes	p. 299
Benzo[c]cinnolines and azobenzene derivatives	p. 300
Benzo[c]cinnolines	p. 300
Azobenzene derivatives	p. 302
Arylazophosphonates	p. 302
Bidiazines	p. 303
Tetrazines	p. 306
Other anion radicals	p. 309
Sulphides and sulphones	p. 309
Diphenylsulphides and sulphones	p. 309
Aliphatic disulphides	p. 310
Imines and imides	p. 311
Imines	p. 311
Imides	p. 316
Fullerenes	p. 316
Tetracyanoquinodimethanes	p. 318
Phenylcarbonitriles	p. 319
Phosphaalkenes	p. 320
Silanes	p. 323
References for 15	p. 324
General symbols and abbreviations
Symbols	p. 329
Abbreviations	p. 329
Substances or part of substances	p. 330
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