Physical Chemistry Student Solutions Manual

by Trapp, Charles; Cady, Marshall; Guinta, Carmen; Atkins, Peter

• ISBN13: 9780716762065
• ISBN10: 0716762064
• Edition: 8th
• Format: Paperback
• Copyright: 2006-08-11
• Publisher: W. H. Freeman

Summary

With its modern emphasis on the molecular view of physical chemistry, its wealth of contemporary applications (in the new " Impact on" features), vivid full-color presentation, and dynamic new media tools, the thoroughly revised new edition is again the most modern, most effective full-length textbook available for the physical chemistry classroom. NOW AVAILABLE IN SPLIT VOLUMESFor maximum flexibility in your physical chemistry course, this text isnow offered as a traditional or in two volumes. Volume 1: Thermodynamics and Kinetics (ISBN 0-7167-8567-6) Volume 2: Quantum Chemistry, Spectroscopy, and StatisticalThermodynamics (ISBN 0-7167-8569-2)See Table of Contents for the contents of each volume.

Table of Contents

PART 1 Equilibrium	1	(154)
1 The properties of gases	3	(19)
Answers to discussion questions	3	(1)
Solutions to exercises	4	(9)
Solutions to problems	13	(9)
Solutions to numerical problems	13	(5)
Solutions to theoretical problems	18	(2)
Solutions to applications	20	(2)
2 The First Law	22	(28)
Answers to discussions questions	22	(1)
Solutions to exercises	23	(10)
Solutions to problems	33	(17)
Solutions to numerical problems	33	(8)
Solutions to theoretical problems	41	(6)
Solutions to applications	47	(3)
3 The Second Law	50	(28)
Answers to discussions questions	50	(1)
Solutions to exercises	51	(7)
Solutions to problems	58	(20)
Solutions to numerical problems	58	(1)
Solutions to theoretical problems	58	(16)
Solutions to applications	74	(4)
4 Physical transformations of pure substances	78	(13)
Answers to discussions questions	78	(2)
Solutions to exercises	80	(3)
Solutions to problems	83	(8)
Solutions to numerical problems	83	(3)
Solutions to theoretical problems	86	(1)
Solutions to applications	87	(4)
5 Simple mixtures	91	(21)
Answers to discussions questions	91	(1)
Solutions to exercises	91	(7)
Solutions to problems	98	(14)
Solutions to numerical problems	98	(6)
Solutions to theoretical problems	104	(3)
Solutions to applications	107	(5)
6 Phase diagrams	112	(15)
Answers to discussions questions	112	(1)
Solutions to exercises	113	(6)
Solutions to problems	119	(8)
Solutions to numerical problems	119	(5)
Solutions to theoretical problems	124	(1)
Solutions to applications	124	(3)
7 Chemical equilibrium	127	(28)
Answers to discussions questions	127	(1)
Solutions to exercises	128	(9)
Solutions to problems	137	(20)
Solutions to numerical problems	137	(11)
Solutions to theoretical problems	148	(2)
Solutions to applications	150	(5)
PART 2 Structure	155	(256)
8 Quantum theory: introduction and principles	157	(19)
Answers to discussions questions	157	(1)
Solutions to exercises	158	(4)
Solutions to problems	162	(14)
Solutions to numerical problems	162	(3)
Solutions to theoretical problems	165	(7)
Solutions to applications	172	(4)
9 Quantum theory: techniques and applications	176	(23)
Answers to discussion questions	176	(1)
Solutions to exercises	176	(7)
Solutions to problems	183	(16)
Solutions to numerical problems	183	(3)
Solutions to theoretical problems	186	(9)
Solutions to applications	195	(4)
10 Atomic structure and atomic spectra	199	(22)
Answers to discussion questions	199	(1)
Solutions to exercises	200	(7)
Solutions to problems	207	(14)
Solutions to numerical problems	207	(4)
Solutions to theoretical problems	211	(7)
Solutions to applications	218	(3)
11 Molecular structure	221	(23)
Answers to discussion questions	221	(2)
Solutions to exercises	223	(3)
Solutions to problems	226	(18)
Solutions to numerical problems	226	(12)
Solutions to theoretical problems	238	(3)
Solutions to applications	241	(3)
12 Molecular symmetry	244	(15)
Answers to discussion questions	244	(1)
Solutions to exercises	245	(4)
Solutions to problems	249	(10)
Solutions to applications	255	(4)
13 Molecular spectroscopy 1: rotational and vibrational spectra	259	(21)
Answers to discussion questions	259	(1)
Solutions to exercises	260	(9)
Solutions to problems	269	(11)
Solutions to numerical problems	269	(6)
Solutions to theoretical problems	275	(1)
Solutions to applications	276	(4)
14 Molecular spectroscopy 2: electronic transitions	280	(17)
Answers to discussion questions	280	(1)
Solutions to exercises	281	(3)
Solutions to problems	284	(13)
Solutions to numerical problems	284	(5)
Solutions to theoretical problems	289	(3)
Solutions to applications	292	(5)
15 Molecular spectroscopy 3: magnetic resonance	297	(18)
Answers to discussion questions	297	(2)
Solutions to exercises	299	(6)
Solutions to problems	305	(10)
Solutions to numerical problems	305	(4)
Solutions to theoretical problems	309	(2)
Solutions to applications	311	(4)
16 Statistical thermodynamics 1: the concepts	315	(16)
Answers to discussion questions	315	(1)
Solutions to exercises	315	(7)
Solutions to problems	322	(9)
Solutions to numerical problems	322	(4)
Solutions to theoretical problems	326	(3)
Solutions to applications	329	(2)
17 Statistical thermodynamics 2: applications	331	(26)
Answers to discussion questions	331	(1)
Solutions to exercises	332	(6)
Solutions to problems	338	(19)
Solutions to numerical problems	338	(7)
Solutions to theoretical problems	345	(8)
Solutions to applications	353	(4)
18 Molecular interactions	357	(13)
Answers to discussion questions	357	(1)
Solutions to exercises	358	(3)
Solutions to problems	361	(9)
Solutions to numerical problems	361	(5)
Solutions to theoretical problems	366	(2)
Solutions to applications	368	(2)
19 Materials 1: macromolecules and aggregates	370	(19)
Answers to discussions questions	370	(2)
Solutions to exercises	372	(3)
Solutions to problems	375	(14)
Solutions to numerical problems	375	(4)
Solutions to theoretical problems	379	(4)
Solutions to applications	383	(6)
20 Materials 2: the solid state	389	(22)
Answers to discussions questions	389	(1)
Solutions to exercises	390	(8)
Solutions to problems	398	(15)
Solutions to numerical problems	398	(7)
Solutions to theoretical problems	405	(3)
Solutions to applications	408	(3)
PART 3 Change	411
21 Molecules in motion	413	(27)
Answers to discussions questions	413	(1)
Solutions to exercises	414	(10)
Solutions to problems	424	(16)
Solutions to numerical problems	424	(6)
Solutions to theoretical problems	430	(3)
Solutions to applications	433	(7)
22 The rates of chemical reactions	440	(24)
Answers to discussions questions	440	(3)
Solutions to exercises	443	(7)
Solutions to problems	450	(14)
Solutions to numerical problems	450	(5)
Solutions to theoretical problems	455	(3)
Solutions to applications	458	(6)
23 The kinetics of complex reactions	464	(25)
Answers to discussions questions	464	(1)
Solutions to exercises	465	(3)
Solutions to problems	468	(21)
Solutions to numerical problems	468	(3)
Solutions to theoretical problems	471	(7)
Solutions to applications	478	(11)
24 Molecular reaction dynamics	489	(20)
Answers to discussions questions	489	(1)
Solutions to exercises	490	(7)
Solutions to problems	497	(12)
Solutions to numerical problems	497	(5)
Solutions to theoretical problems	502	(4)
Solutions to applications	506	(3)
25 Processes at solid surfaces	509
Answers to discussions questions	509	(2)
Solutions to exercises	511	(10)
Solutions to problems	521
Solutions to numerical problems	521	(10)
Solutions to theoretical problems	531	(3)
Solutions to applications	534