9780470467329

Summary

Design and Construction of Coordination Polymers Edited by Mao-Chun Hong Ling Chen A Unique Resource on coordination Polymers Coordination polymers are a growing, interdisciplinary field with numerous potential applications in chemistry and materials. Design and Construction of Coordination Polymers provides a comprehensive introduction to this field, focusing on synthetic strategies, structures, properties, and potential applications. Each chapter provides a unique perspective on coordination polymers, offering a dedicated approach as well as deeper insights on the most important facets of this interdisciplinary area. Combining the consistent editorial approach of a textbook with the up-to-date data and topics usually found in the latest monographs and handbooks, Design and Construction of Coordination Polymers offers an unparalleled reference to the state of the art. Among other topics, it covers: Coordination polymers with versatile structures Crystal engineering of coordination polymers Organic/inorganic hybrid complexes based on polyoxometalates Molecular-based magnetic and ferroelectric compounds Heavy main-group iodometalates Gas storage MOFs Bioinorganic coordination complexes Addressing a wide range of readers, Design and Construction of Coordination Polymers will prove an invaluable resource to everyone from senior-level undergraduate and graduate students to working scientists.

Contributors
Preface
Coordinative Flexibility of Monovalent Silver in [AgI!L1]L2 Complexes
Introduction
Ligands L1 with 1,2 N-Donor Functions
Ligands L1 with 1,3 N-Donor Functions
Ligands L1 with 1,4 N-Donor Functions
Conclusions
References
Indium(III)-Organic Coordination Polymers with Versatile Topological Structures Based on Multicarboxylate Ligands
Introduction
Architectures Constructed by In(III) and Benzenedicarboxylates
Architectures Constructed by In(III) and Benzenetricarboxylates
Architectures Constructed by In(III) and Other Benzenemulticarboxylates
Luminescence, Ion Exchange, and Hydrogen Storage
Conclusions
References
Crystal Engineering of Coordination Polymers via Solvothermal In Situ Metal-Ligand Reactions
Introduction
Metal-Redox Reaction
Conversion of Carboxylic Acid
Carbon-Carbon Bond Formation
Heterocycle Formation from Small Molecules
Transformation of Sulfur-Containing Ligands
Conclusions
References
Construction of Some Organic-Inorganic Hybrid Complexes Based on Polyoxometalates
Introduction
Complexes Built Up by POMs with 1,2,4-Triazolate and Its Derivatives
Complexes Built Up by Molybdenum Oxide Chains with Pyridine Derivatives
Conclusions
References
Silver(I) Coordination Polymers
Introduction
Coordination Geometries of Ag þ Ions
Ligands in Silver(I) Coordination Polymers
Supramolecular Interactions and Counter Anions in Silver(I) Coordination Polymers
One- to Three-Dimensional Coordination Polymers Based on Silver-Ligand Coordination Bonds
Intertwining or Interpenetrating of Silver(I) Coordination Polymers
Properties of Silver(I) Coordination Polymers
References
Tuning Structures and Properties of Coordination Polymers by the Noncoordinating Backbone of Bridging Ligands
Introduction
Ligand Design for Coordination Polymers
Role of Noncoordinating Backbones of Bridging Ligands
Conclusions
References
Ferroelectric Metal-Organic Coordination Compounds
Introduction
Homochiral Discrete or Zero-Dimensional MOCCs
Acentric MOCPs Produced by Supramolecular Crystal Engineering
Homochiral MOCPs Constructed with Optical Organic Ligands
Conclusions
References
Constructing Magnetic Molecular Solids by Employing Three-Atom Ligands as Bridges
Introduction
Coordination Characteristics of Three-Atom Bridges and Their Role in Mediating Magnetic Interaction
Co-Ligands, Templating Cations, and Other Short Bridges
Magnetic Molecular Solids Based on Three-Atom Bridges
Conclusions
References
Structures and Properties of Heavy Main-Group Iodometalates
Introduction
Structural Features of Iodobismuthates and Iodoplumbates
Structural Modification
Optical and Thermal Properties
Summary
References
Cluster-Based Supramolecular Compounds from Mo(W)/Cu/S Cluster Precursors
Introduction
Strategies for Design and Assembly
Structural Features
Luminescent and Third-Order Nonlinear Optical Properties
Conclusions
References
Microporous Metal-Organic Frameworks as Functional Materials for Gas Storage and Separation
Introduction
Design, Rational Synthesis, and Structure Description
Structure Stability, Permanent Microporosity, and Hydrogen Adsorption
Hydrocarbon Adsorption
Ship-in-Bottle Synthesis
Summary and Conclusions
References
Design and Construction of Metal-Organic Frameworks for Hydrogen Storage and Selective Gas Adsorption
Introduction
Hydrogen Storage in Porous Metal-Organic Frameworks
Porous Metal-Organic Frameworks for Selective Gas Adsorption
Outlook
References
Structure and Activity of Some Bioinorganic Coordination Complexes
Introduction
Biomimetic Modeling of a Metalloenzyme with a Cluster Structure
Bioinspired Complexes with a Recognition Domain
Functional Complexes as Therapeutic Agents
Conclusions
References
Index
Table of Contents provided by Publisher. All Rights Reserved.

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Design and Construction of Coordination Polymers

0470467320

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Table of Contents

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