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9780471490715

Interfacial Supramolecular Assemblies

by ; ;
  • ISBN13:

    9780471490715

  • ISBN10:

    0471490717

  • Edition: 1st
  • Format: Hardcover
  • Copyright: 2003-03-14
  • Publisher: WILEY

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Summary

Describes the supramolecular properties of molecular assemblies that contain a solid phase, offering an integrated approach to measurement and addressibility. * Offers an integrated approach to measurement and addressibility. * Features case studies describing the major devices developed using this technology. * The prospects for the future of interfacial supramolecular assemblies are considered.

Author Biography

Robert J. Forster is the author of Interfacial Supramolecular Assemblies, published by Wiley.

Tia E. Keyes is the author of Interfacial Supramolecular Assemblies, published by Wiley.

Johannes G. Vos is the author of Interfacial Supramolecular Assemblies, published by Wiley.

Table of Contents

Introduction
1(8)
Introductory Remarks
1(1)
Interfacial Supramolecular Chemistry
2(2)
Objectives of this Book
4(1)
Testing Contemporary Theory Using ISAs
4(1)
Analysis of Structure and Properties
5(1)
Formation and Characterization of Interfacial Supramolecular Assemblies
5(1)
Electron and Energy Transfer Properties
6(1)
Interfacial Electron Transfer Processes at Modified Semiconductor Surfaces
6(3)
Further Reading
6(3)
Theoretical Framework for Electrochemical and Optical Processes
9(42)
Introduction
9(1)
Electron Transfer
9(19)
Homogenous Electron Transfer
10(11)
Heterogeneous Electron Transfer
21(7)
Photoinduced Processes
28(13)
Photochemistry and Photophysics of Supramolecular Materials
28(3)
Photoinduced Electron Transfer
31(2)
Photoinduced Energy Transfer
33(3)
Photoinduced Molecular Rearrangements
36(5)
Photoinduced Interfacial Electron Transfer
41(5)
Dye-Sensitized Photoinduced Electron Transfer at Metal Surfaces
43(1)
Dye-Sensitized Photoinduced Electron Transfer at Semiconductor Surfaces
44(1)
Photoinduced Interfacial Energy Transfer
45(1)
Elucidation of Excited-State Mechanisms
46(2)
Conclusions
48(3)
References and Notes
48(3)
Methods of Analysis
51(36)
Structural Characterization of Interfacial Supramolecular Assemblies
51(12)
Scanning Probe Microscopy
52(1)
Scanning Electrochemical Microscopy
53(2)
Contact Angle Measurements
55(1)
Mass-Sensitive Approaches
56(3)
Ellipsometry
59(1)
Surface Plasmon Resonance
60(2)
Neutron Reflectivity
62(1)
Voltammetric Properties of Interfacial Supramolecular Assemblies
63(7)
Electrochemical Properties of an Ideal Redox-Active Assembly
63(3)
The Formal Potential
66(1)
Effect of Lateral Interactions
66(1)
Diffusional Charge Transport through Thin Films
67(1)
Rotating Disk Voltammetry
68(2)
Interfacial Capacitance and Resistance
70(1)
Spectroscopic Properties of Interfacial Supramolecular Assemblies
70(11)
Luminescence Spectroscopy
71(1)
Fluorescence Depolarization
72(1)
Epifluorescent and Confocal Microscopy
73(1)
Near-Field Scanning Optical Microscopy
74(1)
Raman Spectroscopy
75(3)
Second Harmonic Generation
78(1)
Single-Molecule Spectroscopy
78(1)
Spectroelectrochemistry
79(1)
Intensity-Modulated Photocurrent Spectroscopy
80(1)
Time-Resolved Spectroscopy of Interfacial Supramolecular Assemblies
81(4)
Flash Photolysis
81(1)
Time-Resolved Luminescence Techniques
82(1)
Femtochemistry
83(2)
Conclusions
85(2)
References
85(2)
Formation and Characterization of Modified Surfaces
87(66)
Introduction
87(2)
Substrate Choice and Preparation
89(1)
Formation of Self-Assembled Monolayers
90(15)
Solution-Phase Deposition
91(2)
Electrochemical Stripping and Deposition
93(1)
Thermodynamics of Adsorption
94(5)
Double-Layer Structure
99(5)
Post-Deposition Modification
104(1)
Structural Characterization of Monolayers
105(4)
Packing and Adsorbate Orientation
105(3)
Surface Properties
108(1)
Electrochemical Characterization
109(3)
General Voltammetric Properties of Redox-Active Monolayers
109(1)
Measuring the Defect Density
110(2)
Multilayer Formation
112(5)
Electrostatically Driven Assemblies
112(3)
Ordered Protein Layers
115(1)
Surfactant-Based Multilayer Assemblies
115(2)
Polymer Films
117(17)
Film Deposition Methods
118(3)
Synthetic Procedures for the Preparation of Redox-Active Polymers
121(5)
Synthetic Methods for the Preparation of Conducting Polymers
126(8)
Structural Features and Structure--Property Relationships of Thin Polymer Films
134(12)
Structural Assessment of Redox Polymers using Neutron Reflectivity
134(4)
Structural Features of Electrostatically Deposited Multilayer Assemblies
138(2)
Self-Assembled Monolayer Films of Thiol-Derivatized Polymers
140(1)
Structural Properties of Block Copolymers
141(2)
Domain Control with Styrene--Methyl Methacrylate Copolymers
143(1)
Structure--Conductivity Relationships for Alkylthiophenes
144(2)
Biomimetic Assemblies
146(4)
Protein Layers
147(1)
Biomolecule Binding to Self-Assembled Monolayers
148(1)
Redox Properties of Biomonolayers
149(1)
Conclusions
150(3)
References
151(2)
Electron and Energy Transfer Dynamics
153(100)
Introduction
153(1)
Electron and Energy Transfer Dynamics of Adsorbed Monolayers
154(31)
Distance Dependence of Electron Transfer
155(2)
Resonance Effects on Electron Transfer
157(5)
Electrode Material Effects on Electron Transfer
162(3)
Effect of Bridge Conjugation on Electron Transfer Dynamics
165(2)
Redox Properties of Dimeric Monolayers
167(2)
Coupled Proton and Electron Transfers in Monolayers
169(5)
Redox-Switchable Lateral Interactions
174(3)
Electron Transfer Dynamics of Electronically Excited States
177(3)
Conformational Gating in Monolayers
180(3)
Electron Transfer within Biosystems
183(1)
Protein-Mediated Electron Transfer
183(2)
Nanoparticles and Self-Assembled Monolayers
185(2)
Conductivities of Single Clusters -- Molecular Switching
186(1)
Electroanalytical Applications
187(5)
Microarray Electrodes
187(1)
Selective Permeation
188(1)
Preconcentration and Selective Binding
188(1)
SAM-Based Biosensors
189(1)
Kinetic Separation of Amperometric Sensor Responses
190(2)
Light-Addressable Assemblies
192(1)
Surface--Photoactive Substrate Interactions
193(1)
Photoactive Self-Assembled Monolayers
194(1)
Photocurrent Generation at Modified Metal Electrodes
194(5)
Photoinduced Molecular Switching
199(7)
Luminescent Films
206(5)
Photoinduced Processes in Bio-SAMs
211(4)
Photoinduced Electron and Energy Transfer in SAMs
215(8)
Distance Dependence of Photoinduced Electron and Energy Transfer
216(3)
Photoinduced Energy Transfer
219(1)
Monolayer Mobility and Substrate Roughness
220(3)
Multilayer Assemblies
223(12)
Photoinduced Charge Separation in Multilayers
229(6)
Electrochemistry of Thin Redox--Active Polymer films
235(12)
Homogeneous Charge Transport
236(3)
Electrochemical Quartz Crystal Microbalance Studies
239(1)
Interfacial Electrocatalysis
240(7)
Conclusions and Future Directions
247(6)
Challenges for the Next Decade
248(1)
References
249(4)
Interfacial Electron Transfer Processes at Modified Semiconductor Surfaces
253(48)
Introduction
253(1)
Structural and Electronic Features of Nanocrystalline TiO2 Surfaces
254(8)
Electronic Properties of Bulk TiO2
254(2)
Electronic Properties of Nanoparticles
256(3)
Preparation and Structural Features of Nanocrystalline TiO2 Surfaces
259(3)
Physical and Chemical Properties of Molecular Components
262(7)
Charge Separation at Nanocrystalline TiO2 Surfaces
267(2)
Photovoltaic Cells Based on Dye-Sensitized TiO2
269(4)
Photoinduced Charge Injection
273(7)
External Factors which Affect Photoinduced Charge Injection
275(1)
Composition of Electrolyte
275(4)
The Effect of Redox Potential
279(1)
Interfacial Supramolecular Assemblies
280(11)
Ruthenium Phenothiazine Assembly
280(2)
Rhodium--Ruthenium Assembly
282(4)
Ruthenium Osmium Assembly
286(5)
Electrochemical Behavior of Nanocrystalline TiO2 Surfaces
291(6)
Electrochromic Devices
294(3)
Alternative Semiconductor Substrates
297(2)
Concluding Remarks
299(2)
References
300(1)
Conclusions and Future Directions
301(8)
Conclusions -- Where to from Here. . . . . .?
301(1)
Molecular Self-Assembly
301(1)
Molecular Components and Nanotechnology
302(1)
Biosystems
303(1)
`Smart Plastics'
304(1)
Interfacial Photochemistry at Conducting Surfaces
305(1)
Modified Semiconductor Surfaces
306(1)
Concluding Remarks
306(3)
Index 309

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