Solid-Liquid Electrochemical Interfaces

by Jerkiewicz, Gregory; Soriaga, Manuel P.; Uosaka, Kohei; Wieckowski, Andrzej

• ISBN13: 9780841234802
• ISBN10: 0841234809
• Format: Hardcover
• Copyright: 1997-02-01
• Publisher: American Chemical Society

Summary

This book presents a range of applications for low-energy electron diffraction (LEED), Auger electron spectroscopy (AES), and X-ray photoelectron spectroscopy (XPS). It applies both scanning tunneling and atomic force microscopy to in situ studies of structures of substrates and adsorbatesduring electrochemical measurements. It then presents a theoretical approach to modeling the electrochemical interface.

Table of Contents

Preface	xi
1. From Electrochemistry to Molecular-Level Research on the Solid--Liquid Electrochemical Interface: An Overview	1	(12)
Gregory Jerkiewicz
2. Molecular Dynamics Simulation of Interfacial Electrochemical Processes: Electric Double Layer Screening	13	(18)
Michael R. Philpott
James N. Glosli
3. Computer Simulation of the Structure and Dynamics of Water Near Metal Surfaces	31	(14)
E. Spohr
4. Fundamental Thermodynamic Aspects of the Underpotential Deposition of Hydrogen, Semiconductors, and Metals	45	(16)
Alireza Zolfaghari
Gregory Jerkiewicz
5. Micrometer-Scale Imaging of Native Oxide on Silicon Wafers by Using Scanning Auger Electron Spectroscopy	61	(10)
Mikio Furuya
6. Growth Kinetics of Phosphate Films on Metal Oxide Surfaces	71	(16)
T. S. Murrell
M. G. Nooney
L. R. Hossner
D. W. Goodman
7. The Effects of Bromide Adsorption on the Underpotential Deposition of Copper at the Pt(111)--Solution Interface	87	(19)
Nenad M. Markovic
C. A. Lucas
Hubert A. Gasteiger
Philip N. Ross, Jr.
8. Electron Spectroscopy Studies of Acidified Water Surfaces	106	(9)
D. Howard Fairbrother
H. S. Johnston
G. A. Somorjai
9. Electrochemical Digital Etching: Atomic Level Studies of CdTe(100)	115	(11)
T. A. Sorenson
B. K. Wilmer
J. L. Stickney
10. Adsorption of Bisulfate Anion on the Au(111), Pt(111), and Rh(111) Surfaces: A Comparative Study	126	(16)
S. Thomas
Y. -E. Sung
Andrzej Wieckowski
11. Ex Situ Low-Energy Electron Diffraction and Auger Electron Spectroscopy and Electrochemical Studies of the Underpotential Deposition of Lead on Cu(100) and Cu(111)	142	(14)
Gessie M. Brisard
Entissar Zenati
Hubert A. Gasteiger
Nenad M. Markovic
Philip N. Ross, Jr.
12. Anion Adsorption and Charge Transfer on Single-Crystal Electrodes	156	(15)
Roberto Gomez
Jose M. Orts
Juan M. Feliu
13. In Situ Scanning Tunneling Microscopy of Organic Molecules Adsorbed on Iodine-Modified Au(111), Ag(111), and Pt(111) Electrodes	171	(18)
K. Itaya
N. Batina
M. Kunitake
K. Ogaki
Y.-G. Kim
L. -J. Wan
T. Yamada
14. Structure of the GaAs(100) Surface During Electrochemical Reactions Determined by Electrochemical Atomic Force Microscopy	189	(13)
Kohei Uosaki
Michio Koinuma
Namiki Sekine
Shen Ye
15. Microfabrication and Characterization of Solid Surfaces Patterned with Enzymes or Antigen-Antibodies by Scanning Electrochemical Microscopy	202	(8)
H. Shiku
Y. Hara
T. Takeda
T. Matsue
I. Uchida
16. Electroactive Polymers: An Electrochemical and In Situ Scanning Probe Microscopy Study	210	(26)
P. Forrer
G. Repphun
E. Schmidt
H. Siegenthaler
17. X-ray Photoelectron Spectroscopy and Scanning Tunneling Microscopy Studies of Thin Anodic Oxide Overlayers on Metal and Alloy Single-Crystal Surfaces	236	(9)
P. Marcus
V. Maurice
18. Structure and Catalysis of Rh--Pt(100), Pt--Rh(110), Pt--Rh(100), and Pt--Rh(110) Surfaces Prepared by Electrochemical Metal Deposition	245	(29)
K. Tanaka
Y. Okawa
A. Sasahara
Y. Matsumoto
19. Electron Spectroscopy and Electrochemical Scanning Tunneling Microscopy of the Solid--Liquid Interface: Iodine-Catalyzed Dissolution of Pd(110)	274	(9)
Manuel P. Soriaga
W. F. Temesghen
J. B. Abreu
K. Sashikata
K. Itaya
20. Electrocatalysis of Formic Acid and Carbon Monoxide with Probe Adlayers of Carbon and Ethylidyne on Pt(111)	283	(14)
D. E. Sauer
R. L. Borup
E. M. Stuve
21. Photooxidation Reaction of Water on an n-TiO(2) Electrode: Investigation of a Previously Proposed New Mechanism by Addition of Alcohols to the Electrolyte	297	(13)
Y. Magari
H. Ochi
S. Yae
Y. Nakato
22. The Behavior of Pyrazine and Monoprotonated Pyrazine Adsorbed on Silver Electrodes: A Surface-Enhanced Raman Scattering Study	310	(13)
A. G. Brolo
D. E. Irish
23. Temperature Dependence of Growth of Surface Oxide Films on Rhodium Electrodes	323	(22)
Francis Villiard
Gregory Jerkiewicz
INDEXES	345
Author Index	345	(1)
Affiliation Index	345	(1)
Subject Index	346