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9780195146288

The Mechanisms of Atmospheric Oxidation of the Aromatic Hydrocarbons

by ; ; ; ; ; ;
  • ISBN13:

    9780195146288

  • ISBN10:

    019514628X

  • Format: Hardcover
  • Copyright: 2002-02-14
  • Publisher: Oxford University Press
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Supplemental Materials

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Summary

This text reviews many of the aspects of the chemistry of the aromatic hydrocarbons and a consensus evaluation of the data by seven of the leading atmospheric scientists. The book covers topics ranging from the relative importance of the compounds in ozone and haze development to methods of estimating elemantary rate coefficients based on structural features of the compounds to mechanisms of aerosol generation and atmostpheric reaction of the polycyclic compounds to photochemical processes. It identifies features of the aromatic hydrocarbons requiring further study and appendicies give the structural formulas and nomenclature of the compounds reviewed in the book.

Table of Contents

Acknowledgments ix
Importance of Aromatic Hydrocarbons in the Chemistry of Ozone Generation in the Urban Atmosphere
3(33)
Typical Composition of the Hydrocarbons Present in Urban Air
5(16)
Relative Importance of OH, NO3, O3, and O(3P) as Reactants for Aromatic Hydrocarbons
21(4)
Importance of Aromatic Hydrocarbons Relative to Other Volatile Organic Compounds as Reactants for OH, NO3, and O3
25(2)
Relative Importance of Individual Aromatic Hydrocarbons
27(6)
Other Sources of Atmospheric NMHCs
33(3)
Reactions of Aromatic Compounds With OH Radicals
36(99)
Mechanisms of the OH-Aromatic Compound Reactions
36(4)
Rate Coefficients for Reactions of OH Radicals with Monocyclic Aromatic Compounds
40(38)
Estimation of Rate Coefficients for Reactions of OH Radicals with Monocyclic Aromatic Compounds
78(4)
Major Products of OH-Aromatic Hydrocarbon Reactions
82(13)
Mechanisms of the Reactions of the Transient First Radical Products of OH-Oxidation of Aromatic Hydrocarbons
95(13)
Rate Coefficients for Gas-Phase Reactions of Polycyclic Aromatic Hydrocarbons (PAHs) with OH Radicals
108(14)
Mechanisms and Products of OH-Radical Reactions with PAHs
122(6)
Estimation of Rate Coefficients for OH-Radical Reactions with PAHs
128(7)
Reactions of Monocyclic and Polycyclic Aromatic Compounds with NO3 Radicals
135(32)
Mechanisms of NO3-Radical Reactions with Aromatic Compounds
135(2)
Rate Coefficients for Reactions of NO3 Radicals with Aromatic Compounds
137(21)
Estimation of Rate Coefficients for Reactions of NO3 Radicals with Monocyclic Aromatic Compounds
158(1)
Products of Reactions of NO3 Radicals with Monocyclic Aromatic Hydrocarbons
159(4)
Mechanisms of Reactions of NO3 Radicals with Polycyclic Aromatic Compounds
163(4)
Reactions of Ozone with Aromatic Compounds
167(23)
Mechanisms of Ozone-Aromatic Compound Reactions
167(1)
Rate Coefficients for Reactions of Ozone with Aromatic Compounds
168(17)
Estimation of Rate Coefficients for Reactions of Aromatic Compounds with Ozone
185(2)
Products and Mechanisms of Reactions of Ozone with Aromatic Hydrocarbons
187(3)
Reactions of O(3p) Atoms with Aromatic Compounds
190(10)
Mechanisms of O(3P)-Aromatic Compound Reactions
190(1)
Rate Coefficients for Reactions of O(3P) Atoms with Aromatic Compounds
191(6)
Products and Mechanisms for Reactions of O(3P) Atoms with Aromatic Hydrocarbons
197(3)
Reactions of Non-Aromatic Products of Aromatic Compound Oxidation
200(30)
Kinetic Data for Reactions of OH Radicals, NO3 Radicals, and Ozone with Non-Aromatic Products of Aromatic Compound Oxidation
201(20)
Products and Mechanisms of Reactions of OH Radical with Some Major Oxidation Products of Aromatic Hydrocarbons
221(9)
Primary Photochemical Processes of the Aromatic Hydrocarbons and Some of Their Common Oxidation Products
230(81)
Tropospheric Photochemistry of the Aromatic Hydrocarbons
230(3)
Photochemistry of Polycyclic Aromatic Hydrocarbons in the Troposphere
233(4)
Photochemistry of Some Common Ring-Fragmentation Products of Atmospheric Oxidation of Aromatic Hydrocarbons
237(53)
Photochemistry of Some Common Aromatic Ring-Retaining Products of Atmospheric Oxidation of Aromatic Hydrocarbons
290(21)
Aerosol Generation in Atmospheric Oxidation of Aromatic Hydrocarbons
311(35)
Organic Composition of Atmospheric Aerosols
311(2)
Mechanisms of Aerosol Generation from Aromatic Hydrocarbons
313(9)
Observed Molecular Composition of Aromatic Secondary Organic Aerosols
322(7)
Atmospheric Oxidation Mechanisms Inferred from Aromatic Aerosol Molecular Composition
329(9)
Possible Influence of Aromatic Aerosols on the Chemistry of Urban Ozone Formation
338(4)
Fate and Lifetime of Atmospheric Organic Aerosols
342(4)
Atmospheric Chemistry of Polycyclic Aromatic Hydrocarbons Sorbed on Particles
346(52)
The Polycyclic Aromatic Hydrocarbons
346(5)
Sources of PAH Emissions to the Atmosphere
351(3)
PAHs in the Atmosphere
354(15)
Reactions, Mechanisms, Products, and Reaction Rates of PAHs Sorbed on Particles
369(29)
Application of Findings to Modeling the Atmospheric Chemistry of Aromatic Hydrocarbons
398(9)
Modeling Urban Air Chemistry
399(3)
Modeling the Atmospheric Chemistry of the Aromatic Hydrocarbons
402(2)
Improvements in Tests of Aromatic Hydrocarbon Atmospheric Oxidation Mechanisms and Experimental Product Data
404(2)
Modeling of Aerosol-Phase Atmospheric Chemistry of Aromatic Hydrocarbons
406(1)
Important Areas for Further Laboratory Studies
407(13)
Kinetic Studies of Gas-Phase Atmospheric Oxidation of Aromatic Hydrocarbons
408(3)
Product and Mechanism Studies of Gas-Phase Atmospheric Oxidation of Aromatic Compounds
411(2)
Gas-Phase Photochemistry of Aromatic Hydrocarbons and Their Oxidation Products
413(3)
Aerosol Generation in Oxidation of Aromatic Hydrocarbons
416(1)
Atmospheric Chemistry of Polycyclic Aromatic Hydrocarbons Sorbed on Particles
417(1)
Qualitative Prioritization of Research Efforts in Areas Suggested for Further Studies
418(2)
Summary
420(10)
Importance of Aromatic Hydrocarbons in the Chemistry of Ozone Generation in the Urban Atmosphere
420(2)
Reactions of Aromatic Compounds with OH Radicals
422(1)
Reactions of Monocyclic and Polycyclic Aromatic Compounds with NO3 Radicals
423(1)
Reactions of Ozone with Aromatic Compounds
424(1)
Reactions of O(3P) Atoms with Aromatic Compounds
424(1)
Reactions of Non-Aromatic Products of Aromatic Compound Oxidation
425(1)
Primary Photochemical Processes of the Aromatic Hydrocarbons and Some of Their Common Oxidation Products
425(1)
Aerosol Generation in Atmospheric Oxidation of Aromatic Hydrocarbons
426(1)
Atmospheric Chemistry of Polycyclic Aromatic Hydrocarbons Sorbed on Particles
427(2)
Application of Findings to Modeling the Atmospheric Chemistry of Aromatic Hydrocarbons
429(1)
Important Areas for Further Laboratory Studies
429(1)
References 430(34)
APPENDIX I: NOMENCLATURE AND MOLECULAR STRUCTURE OF AROMATIC HYDROCARBONS 464(24)
A Substituted Benzenes
465(9)
B Polycyclic Aromatic Hydrocarbons
474(14)
APPENDIX II: NOMENCLATURE AND MOLECULAR STRUCTURE OF SOME COMMON PRODUCTS OF THE ATMOSPHERIC OXIDATION OF THE AROMATIC HYDROCARBONS 488(35)
A Aromatic Ring-Retaining Products
489(22)
B Aromatic Ring-Opening Products
511(12)
Author Index 523(17)
Subject Index 540

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