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9780873395410

The Production and Processing of Inorganic Materials

by ;
  • ISBN13:

    9780873395410

  • ISBN10:

    0873395417

  • Format: Paperback
  • Copyright: 2002-10-01
  • Publisher: Wiley
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Supplemental Materials

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Summary

Guiding readers from the significance, history, and sources of materials to advanced materials and processes, this second edition textbook looks at the production and primary processing of inorganic materials, such as ceramics, metals, silicon, and some composite materials. The text encourages instructors to teach the production of all types of inorganic materials as one. While recognizing the differences between producing various types of materials, the authors focus on the commonality of thermodynamics, kinetics, transport phenomena, phase equilibria and transformation, process engineering, and surface chemistry to all inorganic materials.The text focuses on fundamentals and how fundamentals can be applied to understand how the major inorganic materials are produced and the initial stages of their processing. Understanding of these fundamentals will equip students for engineering future processes for producing materials or for studying the processing of the many less common materials not examined in this text.The text is intended for use in an undergraduate course at the junior or senior level, but will also serve as a useful introductory and reference work for graduate students and practicing scientists and engineers.

Table of Contents

Preface vii
Significance, History, and Sources of Materials
1(28)
What materials are and their importance
1(3)
Historical summary
4(5)
Materials at present
9(3)
The earth as the source of materials
12(5)
Mining
17(2)
Mineral processing
19(8)
Concluding remarks
27(2)
Chemical Thermodynamics
29(45)
Introduction
29(1)
Reversibility (or otherwise) of changes
29(2)
Entropy
31(3)
Free energy
34(3)
Equilibrium
37(21)
Significance of Ellingham diagrams
58(3)
Predominance (Pourbaix) diagrams
61(5)
Physical equilibria
66(1)
Concluding remarks
67(7)
Reaction Kinetics
74(36)
Introduction and some definitions
74(3)
Rate equations
77(9)
Temperature effects
86(3)
Mass transport and heterogeneous reactions
89(10)
The case of the disappearing solid
99(1)
The case of the shrinking core
100(4)
Concluding remarks
104(6)
Powders and Particles
110(24)
Introduction
110(8)
Characterization of particles
118(6)
Characterization of agglomerates and compacts
124(5)
Concluding remarks
129(5)
Surfaces and Colloids
134(36)
Significance of colloids in materials processing
134(1)
Surface structure
135(11)
Colloid interactions
146(21)
Concluding remarks
167(3)
Fundamentals of Heat Treatment and Sintering
170(41)
Introduction
170(1)
Transport of matter
170(21)
Phase equilibria
191(10)
Kinetics of phase changes
201(4)
Sintering: an introduction
205(2)
Concluding remarks
207(4)
Process Engineering
211(30)
Introduction
211(6)
Material and enthalpy balances
217(2)
Recycles
219(2)
Staged operations
221(5)
Heat balances
226(1)
Supply of heat to unit operations
226(4)
Process control
230(5)
Concluding remarks
235(6)
High-Temperature Processing for the Production of Metals and Glass
241(40)
Introduction
241(1)
Thermodynamic considerations
241(2)
Kinetic considerations and selectivity
243(2)
Roasting
245(7)
Reduction of oxides
252(12)
Smelting and converting of sulfides
264(5)
Steelmaking: preliminary refining technologies
269(5)
Glassmaking
274(3)
Concluding remarks
277(4)
Hydrometallurgy and Electrometallurgy
281(40)
Introduction
281(1)
Leaching
282(7)
Solution purification
289(2)
Electrometallurgy
291(25)
Concluding remarks
316(5)
Refining, Solidification, and Finishing of Metals
321(34)
Refining and alloying of metals
321(8)
Solidification of metals
329(13)
Finishing operations
342(9)
Concluding remarks
351(4)
Production of Powders
355(28)
Introduction
355(1)
Mechanical methods for powder production
355(5)
Production of powders from solutions
360(14)
Production of powders by solid-solid and gas-solid reactions
374(2)
Production of metal powder
376(3)
Production of other important ceramic powders
379(1)
Concluding remarks
379(4)
Powder Compaction
383(19)
Introduction
383(1)
Packing of particles
383(5)
Powder compaction
388(2)
Die compaction
390(4)
Isostatic compaction
394(1)
Casting methods
395(3)
Extrusion methods
398(4)
Sintering of Powder Compacts
402(38)
Introduction
402(1)
The sintering process
403(3)
Sintering mechanisms
406(1)
Driving forces for sintering
406(12)
Densification by grain boundary diffusion
418(3)
Densification by volume diffusion
421(1)
Creep of porous solids and the shape factor Φ
422(3)
Interrelation of various transport mechanisms: sintering maps
425(4)
Densification of heterogeneous powder compacts: differential densification
429(4)
Liquid-phase sintering
433(3)
Concluding remarks
436(4)
Microstructure Development During Sintering
440(21)
Introduction
440(1)
Grain growth
441(7)
Pore evaluation during densification
448(5)
Pore movement and pore breakaway
453(5)
Concluding remarks
458(3)
Densification Technology
461(16)
Introduction
461(2)
Free sintering or pressureless sintering
463(3)
Pressure assisted sintering
466(7)
Concluding remarks
473(4)
Advanced Materials and Processes
477(35)
Introduction
477(1)
Rapid solidification
477(3)
Production of silicon
480(6)
Zone refining
486(1)
Chemical vapor deposition
487(7)
Preparation of composite materials from liquid metals
494(3)
Surface modification processes
497(15)
Appendix 512(9)
Index 521

Supplemental Materials

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