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9780444826091

Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis : Proceedings of the International Symposium, Antwerp, Belgium, September 15-17, 1997

by ;
  • ISBN13:

    9780444826091

  • ISBN10:

    0444826092

  • Format: Hardcover
  • Copyright: 1997-09-01
  • Publisher: Elsevier Science Serials
  • Purchase Benefits
List Price: $435.00
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    $495.00
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Summary

Many processes of the chemical industry are based upon heterogeneous catalysis. Two important items of these processes are the development of the catalyst itself and the design and optimization of the reactor. Both aspects would benefit from rigorous and accurate kinetic modeling, based upon information on the working catalyst gained from classical steady state experimentation, but also from studies using surface science techniques, from quantum chemical calculations providing more insight into possible reaction pathways and from transient experimentation dealing with reactions and reactors. This information is seldom combined into a kinetic model and into a quantitative description of the process. Generally the catalytic aspects are dealt with by chemists and by physicists, while the chemical engineers are called upon for mechanical aspects of the reactor design and its control. The symposium "Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis" aims at illustrating a more global and concerted approach through a number of prestigious keynote lectures and severely screened oral and poster presentations.

Table of Contents

Preface xi
KEYNOTE LECTURES 3(156)
Catalytic surface reaction pathways and energetics from first principles
3(32)
M. Neurock
Molecular studies of the mobility of surface metal atoms and adsorbates during catalytic reactions
35(26)
G. A. Somorjai
G. Rupprechter
Molecular kinetics of heterogeneous catalytic reactions
61(18)
R. A. van Santen
A. v. d. Runstraat
R. J. Gelten
From supersonic beams and single crystal microcalorimetry to the control of catalytic reactions
79(12)
D. A. King
Dynamic phenomena at the oxide/water interface: the interplay of surface charge formation, metal complex adsorption, and dissolution/reprecipitation
91(20)
J. -F. Lambert
M. Che
The influence of oxygen poisoning on a multiply promoted iron catalyst used for ammonia synthesis: a temperature-programmed desorption and reaction study
111(10)
F. Rosowski
M. Muhler
Importance of dynamics in real catalyst systems
121(20)
H. Topsoe
C. V. Ovesen
B. S. Clausen
N. -Y. Topsoe
P. E. Hojlund Nielsen
E. Tornqvist
J. K. Norskov
Reaction kinetics as a basis for optimal transient operation of catalytic reactors
141(18)
Y. Sh. Matros
G. A. Bunimovich
V. O. Strots
ORAL COMMUNICATIONS 159(332)
THEORETICAL AND EXPERIMENTAL STUDIES ON THE DYNAMICS OF SURFACES 159(104)
A probabilistic model for the deactivation of a dual function catalyst by coke formation accounting for reaction and surface migration
159(16)
S. Singh
G. F. Froment
Self-sustained isothermal oscillations in N(2)O decomposition on Cu overexchanged ZSM-5
175(10)
P. Ciambelli
A. Di Benedetto
E. Garufi
R. Pirone
G. Russo
Adsorption characteristics of pyridine bases on zeolite (010) examined by atomic force microscopy (AFM)
185(8)
M. Komiyama
Transient and steady-state studies of the effect of water on cobalt Fischer-Tropsch catalysts
193(10)
K. F. Hanssen
E. A. Blekkan
D. Schanke
A. Holmen
Modelling of the dynamics of complex catalytic phenomena based on surface mobility processes and the remote control mechanism
203(14)
P. Ruiz
Y. -W. Li
E. Gaigneaux
B. Delmon
Adsorption and reactions of methane on ferric molybdate using DRIFTS technique
217(10)
S. Fuangfoo
A. S. Chellappa
D. S. Viswanath
Dynamics of multi-component adsorption with interactions: a mean -- field approach
227(14)
M. Dubel
S. D. Prasad
Models of adsorption kinetics on rough surfaces
241(10)
M. Giona
A. Adrover
Investigation of the structure sensitivity of nitrogen adsorption on single crystal ruthenium clusters using density functional theory
251(12)
D. J. Dooling
L. J. Broadbelt
CATALYSIS AND KINETICS 263(156)
Oxydehydrogenation of propane on NiMoO(4) catalyst under transient and steady-state conditions
263(10)
S. Pietrzyk
M. L. Ould Mohamed Mahmoud
T. Rembeczky
R. Bechara
M. Czernicki
N. Fatah
Catalytic ignition during methane oxidation on platinum: experiments and modelling
273(12)
G. Veser
J. Frauhammer
L. D. Schmidt
G. Eigenberger
Modelling catalytic cracking kinetics using estimated adsorption equilibrium constants
285(10)
B. Sowerby
S. J. Becker
Model discrimination for reactions with stop-effect
295(10)
S. Golay
O. Wolfrath
R. Doepper
A. Renken
Methanol oxidation over supported vanadium oxide catalysts: new fundamental insights about oxidation reactions over metal oxide catalysts from transient and steady state kinetics
305(10)
I. E. Wachs
G. Deo
M. V. Juskelis
B. M. Weckhuysen
The effects of alkali promoters on the dynamics of hydrogen chemisorption and syngas reaction kinetics on Ru/SiO(2) surfaces
315(10)
D. O. Uner
N. Savargoankar
M. Pruski
T. S. King
Interparticle migration of hydrogen on zeolite and their participation in the hydrogenation of adsorbed species and catalytic reaction
325(8)
I. Nakamura
A. Zhang
Y. Fan
K. Fujimoto
"State-defining" TAP pulse response experiments
333(8)
J. T. Gleaves
G. S. Yablonskii
P. Phanawadee
Y. Schuurman
Transient and steady-state microkinetic models of catalytic reactions on nonuniform surfaces
341(10)
L. J. Broadbelt
J. E. Rekoske
Transient kinetics of methane dehydrogenation and aromatisation: experiments and modelling
351(10)
Y. Schuurman
T. Decamp
A. Pantazidis
Y. -D. Xu
C. Mirodatos
The desorption of CO(2) from the surface as a kinetically relevant step in the CO oxidation reaction over platinum
361(10)
T. A. Nijhuis
M. Makkee
A. D. van Langeveld
J. A. Moulijn
Non-linear steady-state kinetics of complex catalytic reactions: theory and applications
371(8)
G. S. Yablonskii
M. Z. Lazman
Neural network based model of the kinetics of catalytic hydrogenation reactions
379(10)
E. J. Molga
K. R. Westerterp
Microkinetic analysis of temperature-programmed experiments in a microreactor flow system
389(12)
O. Hinrichsen
F. Rosowski
M. Muhler
G. Ertl
A microkinetic analysis of the reverse water gas shift reaction
401(18)
E. Tserpe
K. C. Waugh
TRANSIENT OPERATION OF REACTIONS AND REACTORS 419(72)
Selectivity enhancement in consecutive reactions using the pressure swing reactor
419(10)
A. J. Kodde
A. Bliek
Experimental studies of transient thermal effects during catalytic oxidation in a packed-bed reactor
429(10)
S. Marengo
P. Comotti
S. Scappatura
M. Vasconi
Dynamic operation of trickle bed reactors
439(10)
H. W. Piepers
A. A. H. Drinkenburg
Simulation of a catalytic converter of automotive exhaust gas under dynamic conditions
449(10)
A. J. L. Nievergeld
E. R. v. Selow
J. H. B. J. Hoebink
G. B. Marin
Effect of variables on the periodic operation of a trickle bed reactor
459(10)
L. Gabarain
J. Cechini
P. Haure
Oxidative coupling of toluene under periodic conditions on Pb/Li/MgO: a selective pathway to 1, 2-diphenylethane
469(10)
S. Dubuis
M. Lorenzi
R. Doepper
A. Renken
Reduction-oxidation-cycling in a fixed bed reactor with periodic flow reversal
479(12)
H. Seiler
G. Emig
POSTERS 491(96)
Ether decomposition activity of CaNi(5) hydrogen storage alloy
491(4)
H. Imai
T. Hosoya
S. Futami
Chemical kinetics of a two component phase segregated system. A simple rate model
495(16)
A. A. Al-Haddad
J. Mathew
Influence of some phenomena occurring on the surface and in the active phase of the vanadium catalyst on the reactor dynamics
511(6)
K. Gosiewski
A detailed kinetic model for the hydrogenolysis, isomerization and dehydrogenation of n-butane
517(6)
I. Machin
T. Romero
M. M. Ramirez de Agudelo
Limitation of metal particle size to carbon chain growth in Fischer-Tropsch synthesis
523(6)
Y. Yang
K. Xie
X. Li
Network simulation of catalytic cracking reactions
529(6)
C. I. C. Pinheiro
F. Lemos
F. Ramoa Ribeiro
Non-catalytic carbon gasification modelling
535(6)
I. Santos Silva
C. Palma
F. Lemos
F. Ramoa Ribeiro
J. Sousa Lobo
Effect of solubility parameter on the MTBE synthesis kinetics
541(6)
C. Fite
J. Tejero
M. Iborra
F. Cunill
J. F. Izquierdo
Hydrogen spillover effect over the oxide surfaces in supported nickel catalysts
547(6)
V. Almasan
T. Gaeumann
M. Lazar
P. Marginean
N. Aldea
Transient investigation of the catalytic activity of copper in NO decomposition over Cu-ZSM5
553(6)
R. Pirone
P. Ciambelli
E. Garufi
G. Russo
Thermodynamic transition-state theory and extrathermodynamic correlations for the liquid-phase kinetics of ethanol derived ethers
559(6)
R. Datta
K. Jensen
P. Kitchaiya
T. Zhang
Hydrodemetallation kinetics of residual petroleum fractions
565(6)
M. T. Martinez
M. A. Callejas
E. Carbo
A. Hernandez
Development of a computational tool for the transient kinetics of complex chemical heterogeneous reaction systems
571(6)
G. A. Carrillo Le Roux
I. Bergault
H. Delmas
X. Joulia
Methods of elimination and the problem of nonuniqueness of inverse problem solutions in models of non-stationary chemical kinetics
577(10)
S. I. Spivak
R. M. Asadullin
Authors' index 587

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