Annual Reports on Nmr Spectroscopy

by Webb, Graham A.

• ISBN13: 9780125053419
• ISBN10: 012505341X
• Format: Hardcover
• Copyright: 2000-03-01
• Publisher: Elsevier Science Serials

Summary

Over recent years, no other technique has grown to such importance as that of NMR spectroscopy. It is used in all branches of science where precise structural determination is required and where the nature of interactions and reactions in solution is being studied. Annual Reports on NMR Spectroscopy has established itself as a means for the specialist and non-specialist alike to become familiar with new applications of the technique in all branches of chemistry, including biochemistry, and pharmaceutics. This volume focuses on theoretical aspects of NMR nuclear shielding and on applications of NMR to polymer science.

Table of Contents

List of Contributors	v
Preface	vii
Cobalt-59 NMR Spectroscopy
Jerry C. C. Chan
Steve C. F. AU-Yeung
Introduction	1	(1)
Solid-state NMR	2	(32)
Solution-state NMR	34	(9)
Theoretical studies	43	(6)
Concluding remarks	49	(8)
References	49	(8)
Advances in Theoretical and Physical Aspects of Spin--Spin Coupling Constants
Ruben H. Contreras
Juan E. Peralta
Claudia G. Giribet
Martin C. Ruiz De Azua
Julio C. Facelli
Introduction	57	(3)
Calculation and analysis of spin--spin coupling constants	60	(40)
Intra- and intermolecular interaction effects on spin--spin coupling constants	100	(85)
References	166	(19)
Dipolar Recoupling under Magic-Angle Spinning Conditions
Stephan Dusold
Angelika Sebald
Introduction	185	(2)
Theory	187	(6)
The heteronuclear dipolar interaction	193	(19)
The homonuclear dipolar interaction	212	(42)
Hybrid experiments and other borderline crossings	254	(11)
References	259	(6)
Characterization of Porous Media Using NMR Methods
Patrick J. Barrie
Introduction	265	(3)
Spectroscopy of adsorbates within the pore space	268	(5)
NMR relaxation times of adsorbates within the pore space	273	(12)
Pulsed field gradient (PFG) NMR methods	285	(12)
Magnetic resonance imaging (MRI) methods	297	(9)
Characterizing the pore space of microporous materials	306	(2)
Conclusions	308	(9)
References	308	(9)
Index	317