Bio-inorganic Hybrid Nanomaterials Strategies, Synthesis, Characterization and Applications

by Ruiz-Hitzky, Eduardo; Ariga, Katsuhiko; Lvov, Yuri M.

• ISBN13: 9783527317189
• ISBN10: 352731718X
• Edition: 1st
• Format: Hardcover
• Copyright: 2008-02-04
• Publisher: Wiley-VCH

Summary

This ready reference is the first to collate the interdisciplinary knowledge from materials science, bioengineering and nanotechnology to give an in-depth overview of the topic. As such, it provides broad coverage of combinations between inorganic materials and such key biological structures as proteins, enzymes, DNA, or biopolymers. With its treatment of various application directions, including bioelectronic interfacing, tissue repair, porous membranes, sensors, nanocontainers, and DNA engineering, this is essential reading for materials engineers, medical researchers, catalytic chemists, biologists, and those working in the biotechnological and semiconductor industries.

Author Biography

Eduardo Ruiz-Hitzky is the director of the Department of Porous Materials and Intercalation Compounds at the Materials Science Institute of Madrid (CSIC), Spain. His research work during the last 30 years has focused on organic-inorganic hybrids and bio-nanocomposite materials. Professor Ruiz-Hitzky has authored over 150 scientific publications and edited two journal special issues, one of them (now in preparation) on bio-nanohybrid materials. He has received several scientific awards from different countries, including the AIPEA Medal from the International Association for the Study of Clays (Tokyo, 2005).

Katsuhiko Ariga is the director of the Supermolecules Group at the National Institute for Materials Science (NIMS), Japan. His research work during the last 20 years has focused on fabrication of nanostructured materials through specific interaction at interfaces, creating novel hybrids of inorganic, organic and biological materials. Dr. Katsuhiko Ariga has authored over 230 scientific publications and received more than 3600 citations. He has published three text books on supramolecular chemistry and served as an editor of one book and one journal special issue on nanomaterials.

Yuri M. Lvov is Chemistry Professor and Pipes Endowed Chair on Micro and Nanosystems at Louisiana Tech University, USA. Earlier, he worked in the Center for Biomolecular Science and Engineering at the Naval Research Laboratory. He is author of more than 150 scientific publications on ultrathin films, biomaterials, clay nanocomposites, and nanocapsules for sustained drug release. Professor Yuri Lvov was among the pioneers of the layer-by-layer nanoassembly technique based on alternate adsorption of oppositely charged components with more than 4000 citations of these works.

Table of Contents

Preface

Contributors

An Introduction to Bio-nanohybrid Materials

Introduction: The Assembly of Biological Species to Inorganic Solids

Bio-nanohybrids Based on Silica Particles and Siloxane Networks

Calcium Phosphates and Carbonates in Bioinspired and Biomimetic Materials

Clay Minerals and Organoclay Bio-nanocomposites

Bio-Nanohybrids Based on Metal and Metal Oxide Nanoparticles

Carbon-based Bio-nanohybrids

Bio-nanohybrids Based on Layered Transition Metal Solids

Trends and Perspectives

References

Biomimetic Nanohybrids Based on Organosiloxane Units

Introduction

Monolayer on Solid Support

Layered Alkylsiloxane

Organic–Inorganic Hybrid Vesicle Cerasome

Mesoporous Silica Prepared by the Lizard Template Method

Future Perspectives

References

Entrapment of Biopolymers into Sol–Gel-derived Silica Nanonocomposites

Introduction

Sol–Gel Processes

Biocompatible Approaches

One-Stage Approach Based on a Silica Precursor with Ethylene Glycol Residues

Perspectives

References

Immobilization of Biomolecules on Mesoporous Structured Materials

Introduction

Immobilization of Protein on Mesoporous Silica

Immobilization of Protein on Mesoporous Carbon and Related Materials

Immobilization of Other Biopolymers on Mesoporous Materials

Immobilization of Small Biomolecules on Mesoporous Materials

Advanced Functions of Nanohybrids of Biomolecules and Mesoporous Materials

Future Perspectives

References

Bio-controlled Growth of Oxides and Metallic Nanoparticles

Introduction

Biomimetic Approaches

In vitro Synthesis of Hybrid Nanomaterials

Perspectives: Towards a Green Nanochemistry

References

Biomineralization of Hydrogels Based on Bioinspired Assemblies for Injectable Biomaterials

Introduction

Fundamental Concept of Bioinspired Approach

Alternate Soaking Process for Biomineralization and their Bio-functions

Electrophoresis Process for Biomineralization

Conclusions

References

Bioinspired Porous Hybrid Materials via Layer-by-Layer Assembly

Introduction

Porous Materials

LbL Assembly

LbL Assembly on MS Substrates

LbL Assembly on Macroporous Substrates

Summary and Outlook

References

Bio-inorganic Nanohybrids Based on Organoclay Self-assembly

Introduction

Synthesis and Characterization of Organically Functionalized 2:1 Magnesium Phyllosilicates

MagnesiumOrganophyllosilicates withHigher-order Organization

Intercalation of Biomolecules within Organically Modified Magnesium Phyllosilicates

Hybrid Nanostructures Based on Organoclay Wrapping of Single Biomolecules

Functional Mesolamellar Bio-inorganic Nanocomposite Films

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