Bulk Metallic Glasses

by Johnson, William L.; Inoue, Akihisa; Liu, C. T.

• ISBN13: 9781558994607
• ISBN10: 1558994602
• Format: Hardcover
• Copyright: 1999-03-01
• Publisher: Materials Research Society

Summary

Bulk metallic glasses (bulk amorphous alloys) constitute an exciting class of metallic materials for structural and functional use. These glass-forming metallic alloys vitrify at relatively low cooling rates (from the molten state), compared with conventional rapidly quenched metallic glasses. Owing to their exceptional resistance to crystallization, these 'easy' glass-forming alloys can be cast in bulk form with dimensions of millimeters or centimeters. The development of such alloys has opened the possibility for studies of the kinetic and thermodynamic properties of undercooled liquids. It also looks at applications for glassy metals based on the ability to fabricate three-dimensional shapes and components. It has become apparent that the development of bulk glass-forming alloys has ushered in a second generation of development in the field of amorphous metals. This book discusses the progress being made. Topics include: atomic and electronic structure; general topics in bulk metallic glasses; glass-forming ability and thermal stability; thermal stability, transport and magnetic properties and mechanical and other properties.

Table of Contents

Preface	xi
Acknowledgments	xiii
Materials Research Society Symposium Proceedings	xiv
PART I: ATOMIC AND ELECTRONIC STRUCTURE I
Oxygen Distribution in Zr-Based Metallic Glasses	3	(6)
D.H. Ping
K. Hono
A. Inoue
Decomposition in Pd40Ni40P20 Bulk Metallic Glass	9	(6)
M.K. Miller
R.B. Schwarz
Y. He
A Local Probe Into the Atomic Structure of Metallic Glasses Using EELS	15	(6)
F.M. Alamgir
Y. Ito
H. Jain
D.B. Williams
R.B. Schwarz
Volume Effects in Bulk Metallic Glass Formation	21	(10)
A.R. Yavari
A. Inoue
EXELFS of Metallic Glasses	31	(6)
Y. Ito
F.M. Alamgir
H. Jain
D.B. Williams
R.B. Schwarz
Simulation of Stress Distribution and Mechanical Response of Metallic Glasses	37	(6)
Y. Kogure
M. Doyama
Calculation of Mechanical, Thermodynamic and Transport Properties of Metallic Glass Formers	43	(8)
T. Cagin
Y. Kimura
Y. Qi
H. Li
H. Ikeda
W.L. Johnson
W.A. Goddard III
PART II: ATOMIC AND ELECTRONIC STRUCTURE II
*Thermodynamics and Glass Forming Ability From the Liquid State	51	(12)
P.J. Desre
Viscosity Measurements for La-Al-Ni Liquid Alloys by an Oscillating Crucible Method	63	(6)
T. Yamasaki
T. Tatibana
Y. Ogino
A. Inoue
In Situ Electron Diffraction Study of Structural Change in the Supercooled Liquid Region in Amorphous La-Al-Ni Alloy	69	(6)
T. Ohkubo
T. Hiroshima
Y. Hirotsu
S. Ochiai
A. Inoue
Free Volume Changes in Bulk Amorphous Alloys During Structural Relaxation and in the Supercooled Liquid State	75	(6)
C. Nagel
K. Ratzke
E. Schmidtke
F. Faupel
Heat Treatment of Molten Rapidly Quenched Precursor as a Method to Improve the Glass Forming Ability of Alloys	81	(6)
V. Manov
E. Brook-Levinson
V.V. Molokanov
M.I. Petrzhik
T.N. Mikhailova
Probing Slow Atomic Motions in Metallic Glasses Using NMR	87	(8)
X-P. Tang
R. Busch
W.L. Johnson
Y. Wu
PART III: GENERAL TOPICS IN BULK METALLIC GLASSES (POSTER SESSION)
NMR Investigations of the Bulk Metallic Glass Zr55Cu30Al10Ni5	95	(6)
W. Hoffmann
M. Baenitz
K. Luders
A. Gebert
J. Eckert
L. Schultz
Fast X-ray Measurement System for Structural Study in Zr60Al15Ni25 Supercooled Liquid	101	(6)
S. Sato
E. Matsubara
Y. Waseda
T. Zhang
A. Inoue
Production of Zirconium-Based Glassy Alloy Wires by Melt Extraction Method and Their Mechanical Properties	107	(6)
A. Katsuya
A. Inoue
Bulk Metallic Glasses Produced by Detonation Gun Spraying	113	(6)
T.P. Shmyreva
On the Effect of Al on the Formation of Amorphous Mg-Al-Cu-Y Alloys	119	(6)
M. Ohnuma
S. Linderoth
N. Pryds
M. Eldrup
A.S. Pedersen
Experimental Measurements of Nucleation Frequency and Crystal Growth Rate in Pd-Cu-Ni-P Metallic Glass	125	(6)
N. Nishiyama
A. Inoue
Phase Equillibria in the Zr-Cu-Al System: Implications for Bulk Metallic Glass Formation	131	(6)
S.A. Syed
D. Swenson
Deformation Behavior of Bulk Amorphous Zr-Base Alloys	137	(6)
A. Leonhard
M. Heilmaier
J. Eckert
L. Schultz
High-Strength Bulk Nanostructure Alloys Consisting of Compound and Amorphous Phases	143	(6)
A. Inoue
C. Fan
Mechanical Properties of Zr-Al-Cu-Ni Alloy Glass at Different Quenching Condition	149	(6)
H. Yabe
R. Toyoshima
Y. Hiraiwa
K. Oguri
Y. Miyazawa
Y. Nishi
Compositional Dependence of Thermal Stability and Soft Magnetic Properties for Fe-Al-Ga-P-C-B Glassy Alloys	155	(6)
T. Mizushima
A. Makino
S. Yoshida
A. Inoue
Investigations on the Electrochemical Behavior of Zr-Al-Cu-Ni Bulk Metallic Glass	161	(6)
K. Buchholz
A. Gebert
K. Mummert
J. Eckert
L. Schultz
Oxide Formation on the Bulk Metallic Glass Zr46.75Ti8.25Cu7.5Ni10Be27.5	167	(6)
M. Kiene
T. Strunskus
G. Hasse
F. Faupel
Continuous Amorphization of Zr-Based Alloys by Controlled Mechanical Intermixing	173	(6)
G. Wilde
H. Sieber
J.H. Perepezko
The Shear Modulus of Glassy and Supercooled Liquid Pd40Ni40P20	179	(6)
A.S. Bains
C.A. Gordon
A.V. Granato
R.B. Schwarz
Fracture in Bulk Amorphous Alloys	185	(6)
J.A. Horton
J.L. Wright
J.H. Schneibel
Mechanism for Light Emission During Fracture of a Zr-Ti-Cu-Ni-Be Bulk Metallic Glass: Temperature Measurements in Air and Nitrogen	191	(8)
C.J. Gibert
J.W. Ager III
V. Schroeder
R.O. Ritchie
PART IV: GLASS FORMING ABILITY AND THERMAL STABILITY
Characterization of Gas Atomized Cu48Ti34Zr10Ni8 Amorphous Metal Powder	199	(6)
J.C. Foley
D.J. Sordelet
T.A. Lograsso
Significant Undercooled Liquid Region of Over 200K in Rare Earth Based Metallic Glasses	205	(6)
Z.P. Lu
Y. Li
S.C. Ng
Y.P. Feng
Formation of Glassy Spinodals in Bulk Metallic Glasses	211	(6)
W.H. Guo
C.C. Leung
H.W. Kui
Equilibrium Thermodynamics Near the Glass Transition---The Conceptual Application of the Limiting Fictive Temperature	217	(6)
G. Wilde
J.H. Perepezko
*Viscosity, Relaxation and Crystallization Kinetics in Zr-Ti-Cu-Ni-Be Strong Bulk Metallic Glass Forming Liquids	223	(14)
R. Busch
A. Masuhr
E. Bakke
T.A. Waniuk
W.L. Johnson
Critical Cooling Rate Versus Reduced Glass Transition: Scaling Factors and Master Curves	237	(6)
N. Clavaguera
M.T. Clavaguera-Mora
Glass Formation and Phase Separation in The Vitreloy Type Bulk Metallic Glasses	243	(8)
C.C. Hays
P. Kim
W.L. Johnson
PART V: THERMAL STABILITY, TRANSPORT, AND MAGNETIC PROPERTIES
*Synthesis and Properties of Ferromagnetic Bulk Amorphous Alloys	251	(12)
A. Inoue
T. Zhang
H. Koshiba
T. Itoi
Crystallization of Supercooled Zr41Ti14Cu12Ni10Be23 Melts During continuous Heating and Cooling	263	(6)
J. Schroers
A. Masuhr
R. Busch
W.L. Johnson
Self-Diffusion in Bulk Metallic Glasses	269	(6)
K. Knorr
M-P. Macht
H. Mehrer
*Atomic Diffusion in Bulk Metallic Glasses	275	(12)
U. Geyer
A. Rehmet
S. Schneider
Hydrogenation and Crystallization of Zr-Cu-Ni-Al Glasses	287	(6)
U. Koster
D. Zander
H. Leptien
N. Eliaz
D. Eliezer
Elastic and Dissipative Properties of Amorphous and Nanocrystalline Mg-Ni-Y Alloy	293	(6)
Y.M. Soifer
N.P. Kobelev
I.G. Brodova
A.N. Manukhin
E. Korin
L. Soifer
A Relation Between Fragility, Specific Heat, and Shear Modulus Temperature Dependence for Simple Supercooled Liquids	299	(6)
A.V. Granato
Effect of Small Amounts of B and C Additions on Glass Formation and Mechanical Properties of a Zr-Base Alloy	305	(6)
C.T. Liu
L.M. Pike
N.G. Chen
*Bulk Glass-Forming Metallic Alloys: Science and Technology (1998 MRS Medal Award Lecture Presented at Symposium MM)	311	(32)
W.L. Johnson
PART VI: MECHANICAL AND OTHER PROPERTIES I
*Fracture and Fatigue in a Zr-Based Bulk Metallic Glass	343	(12)
C.J. Gilbert
V. Schroeder
R.O. Ritchie
Environmental and Stress State Effects on Fracture and Fatigue Crack-Growth in Zr-Ti-Ni-Cu-Be Bulk Amorphous Metals	355	(6)
K.M. Flores
D. Suh
R.H. Dauskardt
High Dynamic Mechanical Strength of Zirconium-Based Bulk Amorphous Alloys	361	(6)
T. Zhang
A. Inoue
Deformation Behavior of FCC Crystalline Metallic Nanowires Under High Strain Rates	367	(6)
Y. Qi
H. Ikeda
T. Cagin
K. Samwer
W.L. Johnson
W.A. Goddard III
Deformation Behavior in La55Al25Ni20 Metallic Glass	373	(6)
Y. Kawamura
T. Nakamura
A. Inoue
Superplastic Deformation and Viscous Flow in a Zr-Based Metallic Glass at 410°C	379	(6)
T.G. Nieh
J.G. Wang
J. Wadsworth
T. Mukai
C.T. Liu
Microforming of MEMS Parts With Amorphous Alloys	385	(8)
Y. Saotome
T. Zhang
A. Inoue
PART VII: MECHANICAL AND OTHER PROPERTIES II
Synthesis and Properties of Bulk Metallic Glass Matrix Composites	393	(6)
H. Choi-Yim
R. Busch
W.L. Johnson
*Amorphous and Disordered Materials---The Basis of New Industries	399	(14)
S.R. Ovshinsky
Thermal Stability of Bulk Metallic Glasses: Influence on Mechanical Properties	413	(6)
J.M. Pelletier
Y. Jacquemard
J. Perez
R. Perrier De la Bathie
*Dynamic Failure Mechanisms in Beryllium-Bearing Bulk Metallic Glasses	419	(12)
D.M. Owen
A.J. Rosakis
W.L. Johnson
Residual Stresses in Bulk Metallic Glasses Due to Differential Cooling or Thermal Tempering	431	(6)
E. Ustundag
B. Clausen
J.C. Hanan
M.A.M. Bourke
A. Winholtz
A. Peker
Tribological Characteristics of Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 Bulk Metallic Glass	437	(6)
X-Y. Fu
D.A. Rigney
Author Index	443	(2)
Subject Index	445