Catalyst Components for Coupling Reactions

by Molander, Gary A.

• ISBN13: 9780470518113
• ISBN10: 0470518111
• Edition: 1st
• Format: Hardcover
• Copyright: 2008-09-02
• Publisher: Wiley

Summary

While a number of books describe the importance and application of different aspects of coupling reactions, this Handbook compiles all major catalyst components in use in the area, and is intended to guide the experimentalist and facilitate choice among the numerous reagents available for any one purpose. The Handbook details pre-catalysts, catalysts, and ligands prominently employed in coupling reactions, broadly defined. Catalyst systems used in Heck, Kumada-Tamao-Corriu, Suzuki-Miyaura, Hiyama-Hatanaka, Negishi, Migita-Kosugi-Stille, Buchwald-Hartwig, and Tsuji-Trost coupling reactions are also included. The Handbook features artices taken from the EROS database, with the inclusion of about 20 newly commissioned catalysts/pre-catalysts/ligands that have made an impact in this area of synthetic organic chemistry.

Author Biography

Gary A. Molander is a Professor with the Department of Chemistry at the University of Pennsylvania in Philiadelphia, Pennsylvania.

Table of Contents

Preface

Introduction

Recent Review Articles and Monographs

1-Adamantyl-di-tert-butylphosphine

Benzylchlorobis(triphenylphosphine)palladium (II)

[1,1?-Biphenyl]-2-yldicyclohexylphosphine

Carbonyl(chloro)bis(triphenylphosphine)rhodium(I)

Diacetatobis(tri=o-tolylphophine)palladium(II)

Encapsulated Palladium Catalysts

Hydrotetrakis(triphenylphosphine)rhodium

Ido(phenyl)bis(triphenylphosphine)palladium(II)

Lithium Trichloropalladate

(Maleic anhydride)bis(triphenylphosphine)palladium,

Nickel

Palladium(II) Acetate

Silver(I) Oxide

Tetrakis(acetonitrille)copper(I) Perchlorate

Zinc/Nickel Couple

List of Contributors

Reagent Formula Index

Subject Index

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