Catalytic Methods in Asymmetric Synthesis Advanced Materials, Techniques, and Applications

by Gruttadauria, Michelangelo; Giacalone, Francesco

• ISBN13: 9780470641361
• ISBN10: 0470641363
• Edition: 1st
• Format: Hardcover
• Copyright: 2011-09-27
• Publisher: Wiley

Summary

This book covers advances in the methods of catalytic asymmetric synthesis and their applications. Coverage moves from new materials such as chiral ionic liquids, supported catalysts and flow reactors; to homogeneous metal-free catalysts and homogeneous metal catalysts. The applications of several methodologies for the synthesis of biologically active molecules are discussed. Part I addresses recent advances in new technologies related to asymmetric catalysis. Part II covers advances and milestones with amino acids, both natural and unnatural, as powerful organocatalysts - including applications for the synthesis of biologically active molecules.

Author Biography

Francesco Giacalone, PhD, is a Researcher in the Organic Chemistry Department at the University of Palermo. He is author or coauthor of about forty scientific papers, including four reviews in peer-reviewed journals, as well as fifteen book Chapters and forty congress presentations. His current research interests focus on the preparation of recyclable materials in hetergeneous Catalysis for organic systhesis.

Table of Contents

Preface	p. xi
Foreword	p. xiii
Contributors	p. xv
New Materials And Technologies Supported Catalysts,Supports, Self Supported Catalysts ,Chirl Ionic Liquid, Supercritical Fluids,Flow Reactors, And Microwaves	p. 1
Recyclable Stereoselective Catalysts	p. 3
Recyclable Organocatalysts In Asymmetric Reactions	p. 83
Synthesis And Characterization Of Supported Chiral Catalysts	p. 177
Synthesis Of Chiral Catalysts Supported On Organic Polymers	p. 209
Sef-Supported Chiral Catalysts	p. 257
Catalysis With Chirally Modified Metal Surfaces: Scope And Mechanims	p. 291
Chiral ionic Liquids For Asymmetric Reactions	p. 323
Asymmetric Reactions In Flow Reactors	p. 345
Asymmetric Catalytic Synthesis In Supercritcal Fluids	p. 373
Microwaves-Assisted Transition Metal-Catalyzed Asymmetric Synthesis	p. 391
Recent Advances In Organovatalytic Enzymatic, And Metal-Based Mediated Asymmetric Synthesis	p. 413
Recent Advances On Stereoselective Orgnocatalytic Reactions. Organocatalytic Synthesis Of Natural Products And Drugs	p. 415
Recent Advances In Biocatalysis Applied To Organic Synthesis	p. 491
Peptides For Asymmetric Catalysis	p. 529
Silicate-Mediated Stereosseletive Reactions Catalyzed By Chiral Lewis Bases	p. 579
Recent Advances in the metal-Catalyzed Stereoselective Synthesis Of Biologically Active Molecules	p. 625
Stereoselective Nitrogen Heterocycle synthesis Mediataed By Chiral Metal Catalysts	p. 671
Index	p. 689
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