C-h Activation

by Yu, Jin-quan; Shi, Zhangjie; Ackermann, L. (CON); Beck, E. M. (CON); Bouffard, J. (CON)

• ISBN13: 9783642123559
• ISBN10: 3642123554
• Edition: 1st
• Format: Hardcover
• Copyright: 2010-06-30
• Publisher: Springer Verlag

Summary

Table of Contents- Synthesis in the Key of Catellani: Norbornene-Mediated ortho C–H Functionalization - Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation- Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C–H and C–Hal Bonds- Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus- Remote C–H Activation via Through-Space Palladium and Rhodium Migrations- Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation- Palladium-Catalyzed Allylic C–H Bond Functionalization of Olefins- Ruthenium-Catalyzed Direct Arylations Through C–H Bond Cleavages- Rhodium-Catalyzed C–H Bond Arylationof Arenes - Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C–H Bonds- Functionalization of Carbon–Hydrogen Bonds Through Transition Metal Carbenoid Insertion- Metal-Catalyzed Oxidations of C–H to C–N Bonds

Table of Contents

Synthesis in the Key of Catellani: Norbornene-Mediated ortho C-H Functionalization	p. 1
Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation	p. 35
Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C-H and C-Hal Bonds	p. 57
Pd-Catalyzed C-H Bond Functionalization on the Indole and Pyrrole Nucleus	p. 85
Remote C-H Activation via Through-Space Palladium and Rhodium Migrations	p. 123
Palladium-Catalyzed Aryl-Aryl Bond Formation Through Double C-H Activation	p. 165
Palladium-Catalyzed Allylic C-H Bond Functionalization of Olefins	p. 195
Ruthenium-Catalyzed Direct Arylations Through C-H Bond Cleavages	p. 211
Rhodium-Catalyzed C-H Bond Arylation of Arenes	p. 231
Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C-H Bonds	p. 281
Functionalization of Carbon-Hydrogen Bonds Through Transition Metal Carbenoid Insertion	p. 303
Metal-Catalyzed Oxidations of C-H to C-N Bonds	p. 347
Index	p. 379
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