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Dr. Gilbert F. Froment is Professor Emeritus of Chemical Engineering at the University of Gent, Belgium, and Research Professor of Texas A&M University. Kenneth B. Bischoff is the author of Chemical Reactor Analysis and Design, 3rd Edition, published by Wiley.
Elements of Reaction Kinetics | |
Definitions of Chemical Rates | |
Rate Equations | |
Coupled Reactions | |
Reducing the Size of Kinetic Models | |
Bio-Kinetics | |
Complex Reactions | |
Modeling the Rate Coefficient | |
Kinetics of Heterogeneous Catalytic Reactions | |
Introduction | |
Adsorption on Solid Catalysts | |
Rate Equations | |
Complex Catalytic Reactions | |
Experimental Reactors | |
Model Discrimination and Parameter Estimation | |
Sequential Design of Experiments | |
Expert Systems in Kinetics Studies | |
Transport Processes with Reactions Catalyzed by Solids | |
Interfacial Gradient Effects | |
Reaction of a component of a fluid at the surface of a solid | |
Mass and heat transfer resistances | |
Concentration or partial pressure and temperature differences | |
Intraparticle Gradient Effects | |
Molecular-, Knudsen-, and surface diffusion in pores | |
Diffusion in a catalyst particle | |
Diffusion and reaction in a catalyst particle. A continuum model | |
Falsification of rate coefficient and activation energy by diffusion limitations | |
Influence of diffusion limitations on the selectivities of coupled reactions | |
Criteria for the importance of intraparticle diffusion limitations | |
Multiplicity of steady states in catalyst particles | |
Combination of external and internal diffusion limitations | |
Diagnostic experimental criteria for the absence of internal and external mass transfer limitations | |
Nonisothermal particles | |
Noncatalytic Gas-Solid Reactions | |
A Qualitative Discussion of Gas-Solid Reactions | |
General Model with Interfacial and Intraparticle Gradients | |
Heterogeneous Model with Shrinking Unreacted Core | |
Models Accounting Explicitly for the Structure of the Solid | |
On the Use of More Complex Kinetic Equations | |
Catalyst Deactivation | |
Types of Catalyst Deactivation | |
Kinetics of Catalyst Poisoning | |
Kinetics of Catalyst Deactivation by Coke Formation | |
Gas-Liquid Reactions | |
Introduction | |
Models for Transfer at a Gas-Liquid Interface | |
Two-Film Theory | |
Surface Renewal Theory | |
Experimental Determination of the Kinetics of Gas-Liquid Reactions | |
The Modeling of Chemical Reactors | |
Approach | |
Aspects of Mass-, Heat- and Momentum Balances | |
The Fundamental Model Equations | |
The Batch and Semibatch Reactors | |
Introduction | |
The Isothermal Batch Reactor | |
The Nonisothermal Batch Reactor | |
Semibatch Reactor Modeling | |
Optimal Operation Policies and Control Strategies | |
The Plug Flow Reactor | |
The Continuity, Energy, and Momentum Equations | |
Kinetic Studies Using a Tubular Reactor with Plug Flow | |
Design and Simulation of Tubular Reactors with Plug Flow | |
The Perfectly Mixed Flow Reactor | |
Introduction | |
Mass and Energy Balances | |
Design for Optimum Selectivity in Simultaneous Reactions | |
Stability of Operation and Transient Behavior | |
Fixed Bed Catalytic Reactors | |
Introduction | |
The Importance and Scale of Fixed Bed Catalytic Processes | |
Factors of Progress: Technological Innovations and Increased Fundamental Insight | |
Factors Involved in the Preliminary Design of Fixed Bed Reactors | |
Modeling of Fixed Bed Reactors | |
Pseudohomogeneous Models | |
The Basic One-Dimensional Model | |
One-Dimensional Model with Axial Mixing | |
Two-Dimensional Pseudohomogeneous Models | |
Heteorgeneous Models | |
One-Dimensional Model Accounting for Interfacial Gradients | |
One-Dimensional Model Accounting for Interfacial and Intraparticle Gradients | |
Two-Dimensional Heterogeneous Models | |
Complex Flow Patterns | |
Introduction | |
Macro- and Micro-Mixing in Reactors | |
Models Explicitly Accounting for Mixing | |
Micro- Probability Density Function Methods | |
Micro-PDF Moment Methods: Computational Fluid Dynamics | |
Macro-PDF / Residence Time Distribution Methods | |
Semi-Empirical Models for Reactors with Complex Flow Patterns | |
Fluidized Bed and Transport Reactors | |
Introduction | |
Technological Aspects of Fluidized Bed and Riser Reactors | |
Some Features of the Fluidization and Transport of Solids | |
Heat Transfert in Fluidized Beds | |
Modeling of Fluidized Bed Reactors | |
Modeling of a Transport of Riser Reactor | |
Fluidized Bed Reactor Models Considering Detailed Flow Patterns | |
Catalytic Cracking of Vacuum Gas Oil | |
Multiphase Flow Reactors | |
Types of Multiphase Flow Reactors | |
Design Models for Multiphase Flow Reactors | |
Specific Design Aspects | |
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