Chemistry of Advanced Materials An Overview

by Interrante, Leonard V.; Hampden-Smith, Mark J.

• ISBN13: 9780471185901
• ISBN10: 0471185906
• Edition: 1st
• Format: Hardcover
• Copyright: 1997-06-30
• Publisher: Wiley-VCH

Summary

This is to be initial, 'overview' volume of a series on the "Chemistry of Advanced Materials". This series of volumes is intented to complement VCH's existing series on "Materials Science and Technology" and, in particular, to highlight the role of chemistry in the preparation and processing of advanced materials. The introductory volume in the series is intented to "set the stage" for the succeeding volumes and to introduce the subject of materials chemistry to a general audience of scientifically literate nonspecialists. Subjects covered in this intitial volume will eventually be the subject of one or more individual volumes in the series. This series is directed to a broad audience of chemists and materials scientists. This volume, in particular, should be appropriate for a general scientific audience and be of interest, as well as comprehensible, even to undergraduate students in chemistry and materials science.

Author Biography

LEONARD V. INTERRANTE, PhD, is Professor of Chemistry at Rensselaer Polytechnic Institute. He is Editor of the ACS journal, Chemistry of Materials. MARK J. HAMPDEN-SMITH, PhD, is Professor of Chemistry at the University of New Mexico in Albuquerque.

Table of Contents

Preface	xi
1. Introductory Terms and Concepts	1	(18)
Mark J. Hampden-Smith
Leonard V. Interrante
1.1 Materials Chemistry: Introduction	1	(1)
1.2 Materials Chemistry: Past	2	(3)
1.3 Materials Chemistry: Present	5	(9)
1.4 Materials Chemistry: Future	14	(3)
References	17	(1)
General Bibliography	18	(1)
2. Electron-Transfer Salt-Based Conductors, Superconductors, and Magnets	19	(54)
Patrick Cassoux
Joel S. Miller
2.1 Introduction	19	(2)
2.2 Definitions and Units	21	(4)
2.3 Historical Background	25	(2)
2.4 One-Dimensional Conductors	27	(4)
2.5 Quasi One- and Two-Dimensional Superconductors	31	(9)
2.6 Fullerides	40	(2)
2.7 Related Research Areas	42	(5)
2.8 Electron-Transfer Salt-Based Magnets	47	(10)
2.9 Conclusions	57	(2)
References	59	(14)
3. Advanced Polymeric Materials: Functional Electroactive Polymers	73	(26)
Bashir M. Sheikh-Ali
Gary E. Wnek
3.1 Introduction	73	(1)
3.2 Brief Structural Overview of Conjugated Polymers	73	(1)
3.3 Synthesis, Processing, and Doping of Conjugated Polymers	74	(6)
3.4 Ionically Conducting Polymers	80	(3)
3.5 Applications of Conjugated Polymers	83	(6)
3.6 Electronically and Ionically Conducting Polymers in Energy Storage Applications	89	(3)
3.7 Other Electroactive Polymer Systems	92	(1)
References	93	(6)
4. Polymers in Electronics	99	(44)
E. Reichmanis
T. X. Neenan
4.1 Introduction	99	(1)
4.2 Lithographic Materials	100	(2)
4.3 Resist Design Requirements	102	(1)
4.4 Solution-Developed Resist Chemistry	103	(14)
4.5 Dry-Developed Resist Chemistry	117	(4)
4.6 Polymers as Packaging Materials and Encapsulants	121	(10)
References	131	(12)
5. Chemical Vapor Deposition	143	(64)
Mark J. Hampden-Smith
Toivo T. Kodas
Audunn Ludviksson
5.1 Introduction	143	(7)
5.2 Fundamental Aspects of CVD Processes	150	(21)
5.3 Overview of Vapor-Phase Deposition Methods, Related and Unrelated to CVD	171	(9)
5.4 Case Studies	180	(17)
5.5 Summary, Conclusions, and Future Directions	197	(1)
References	198	(9)
6. Introduction to the Nonlinear Optical Properties of Organic Materials	207	(64)
Fabienne Meyers
Seth R. Marder
Joseph W. Perry
6.1 Introduction	207	(1)
6.2 Basic Concepts	208	(11)
6.3 Quantum-Chemical Description	219	(6)
6.4 Molecular Structure-NLO Properties Relationships	225	(18)
6.5 Materials Design	243	(18)
6.6 Conclusions	261	(1)
References	262	(9)
7. Nanoparticles and Nanostructural Materials	271	(58)
Kenneth J. Klabunde
Cathy Mohs
7.1 A World Bounded by Chemistry and Solid-State Physics	271	(7)
7.2 Methods of Preparation	278	(15)
7.3 Physical Properties	293	(11)
7.4 Chemical Properties of Surfaces	304	(12)
7.5 Possible Applications of Nanoparticles	316	(2)
References	318	(11)
8. Nanoporous Materials	329	(60)
Peter T. Tanev
Jean-Remi Butruille
Thomas J. Pinnavaia
8.1 Introduction	329	(1)
8.2 Zeolites and Molecular Sieves	330	(28)
8.3 Porous Lamellar Solids	358	(21)
8.4 Summary and Conclusions	379	(2)
References	381	(8)
9. Molecular Precursor Routes to Inorganic Solids	389	(60)
Jacques Livage
C. Sanchez
F. Babonneau
9.1 Introduction	389	(1)
9.2 Sol-Gel Chemistry of Metal Alkoxides	390	(19)
9.3 Hybrid Organic-Inorganic Compounds	409	(20)
9.4 Polymeric Routes to Nonoxide Ceramics	429	(12)
9.5 Conclusions	441	(1)
References	442	(3)
General Bibliography	445	(4)
10. Layered Transition-Metal Oxides and Chalcogenides	449	(50)
Paul A. Salvador
Thomas O. Mason
Michael E. Hagerman
Kenneth Poeppelmeier
10.1 Introduction	449	(6)
10.2 Materials Chemist's Approach	455	(14)
10.3 Layering in Advanced Materials	469	(17)
10.4 Summary and Future Prospects	486	(5)
References	491	(8)
11. Biomaterials	499	(64)
Carole C. Perry
11.1 Introduction	499	(5)
11.2 Key Tissues in the Human Body	504	(6)
11.3 Biomineralization: The Controlled Formation of Biological Composites	510	(9)
11.4 Bone and Other Mineralized Tissues	519	(8)
11.5 Materials of Construction	527	(26)
11.6 Other Applications	553	(2)
11.7 Biocompatibility Testing	555	(2)
11.8 Funding for Research: The Way Forward	557	(1)
References	558	(5)
Index	563