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9780470822333

Chemistry of Zeolites and Related Porous Materials Synthesis and Structure

by ; ; ; ;
  • ISBN13:

    9780470822333

  • ISBN10:

    0470822333

  • Edition: 1st
  • Format: Hardcover
  • Copyright: 2007-09-17
  • Publisher: Wiley-Interscience
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Summary

Widely used in adsorption, catalysis and ion exchange, the family of molecular sieves such as zeolites has been greatly extended and many advances have recently been achieved in the field of molecular sieves synthesis and related porous materials. Chemistry of Zeolites and Related Porous Materials focuses on the synthetic and structural chemistry of the major types of molecular sieves. It offers a systematic introduction to and an in-depth discussion of microporous, mesoporous, and macroporous materials and also includes metal-organic frameworks. Provides focused coverage of the key aspects of molecular sieves Features two frontier subjects: molecular engineering and host-guest advanced materials Comprehensively covers both theory and application with particular emphasis on industrial usesThis book is essential reading for researches in the chemical and materials industries and research institutions. The book is also indispensable for researches and engineers in R&D (for catalysis) divisions of companies in petroleum refining and the petrochemical and fine chemical industries.

Author Biography

Professor Ruren Xu is Professor of Chemistry at Jilin University, P. R. China and an elected member of the Chinese Academy of Sciences. With over 400 papers in international journals and 6 research monographs, he is known worldwide for contributions in the synthesis of new families of microporous materials, establishment of solvothermal synthetic route, and pioneering work in the rational micropore-synthesis. Prof. Xu has served as a main editor or on the editorial board for 12 journals in the field. He was a councilor of International Zeolite Association from1998 to 2004 and is the current President of Chinese Zeolite Association. Between 2005 and 2007, he is also the Chairman for the 15th International Zeolite Conference.

Prof. Wenqin Pang is Professor of Chemistry at Jilin University, with research interest on synthetic chemistry of micro- and mesoporous compounds, especially on hetro-atom containing porous materials.  She has published over 300 papers and 5 books. 

Prof. Jihong Yu is Professor of Chemistry at Jilin University. Her research interest is design and synthesis of inorganic open-framework materials, with over 100 papers. She is a member of editorial boards of Microporous and Mesoporous Materials and Current Chemical Biology.

Dr. Qisheng Huo is a Staff Member, Fundamental Science Directorate, Pacific Northwest National Laboratory, USA. His current research interests include the design and synthesis of multi-functional nano-structured catalyst.

Prof. Jiesheng Chen is Professor of Chemistry, Jilin University. His research interests are host-guest chemistry and physics, and synthesis of solid compounds with new structures and functions. He has published over 120 papers.

Table of Contents

Preface
Introduction
The Evolution and Development of Porous Materials
From Natural Zeolites to Synthesized Zeolites
From Low-silica to High-silica Zeolites
From Zeolites to Aluminophosphate Molecular Sieves and Other Microporous Phosphates
From 12-Membered-ring Micropores to Extra-large Micropores
From Extra-large Micropores to Mesopores
Emergence of Macroporous Materials
From Inorganic Porous Frameworks to Porous Metal-organic Frameworks (MOFs)
Main Applications and Prospects
The Traditional Fields of Application and Prospects of Microporous Molecular Sieves
Prospects in the Application Fields of Novel, High-tech, and Advanced Materials
The Main Application Fields and Prospects for Mesoporous Materials
The Development of Chemistry for Molecular Sieves and Porous Materials
The Development from Synthesis Chemistry to Molecular Engineering of Porous Materials
Developments in the Catalysis Study of Porous Materials
Structural Chemistry of Microporous Materials
Introduction
Structural Building Units of Zeolites
Primary Building Units
Secondary Building Units (SBUs)
Characteristic Cage-building Units
Characteristic Chain- and Layer-building Units
Periodic Building Units (PBUs)
Composition of Zeolites
Framework Composition
Distribution and Position of Cations in the Structure
Organic Templates
Framework Structures of Zeolites
Loop Configuration and Coordination Sequences
Ring Number of Pore Opening and Channel Dimension in Zeolites
Framework Densities (FDs)
Selected Zeolite Framework Structures
Zeolitic Open-framework Structures
Anionic Framework Aluminophosphates with Al/P (less than or equal to) 1
Open-framework Gallophosphates with Extra-large Pores
Indium Phosphates with Extra-large Pores and Chiral Open Frameworks
Zinc Phosphates with Extra-large Pores and Chiral Open Frameworks
Iron and Nickel Phosphates with Extra-large Pores
Vanadium Phosphates with Extra-large Pores and Chiral Open Frameworks
Germanates with Extra-large Pores
Indium Sulfides with Extra-large-pore Open Frameworks
Summary
Synthetic Chemistry of Microporous Compounds (I) - Fundamentals and Synthetic Routes
Introduction to Hydro(solvo)thermal Synthesis
Features of Hydro(solvo)thermal Synthetic Reactions
Basic Types of Hydro(solvo)thermal Reactions
Properties of Reaction Media
Hydro(solvo)thermal Synthesis Techniques
Survey of the Applications of Hydro(solvo)thermal Synthetic Routes in the Synthesis of Microporous Crystals and the Preparation of Porous Materials
Synthetic Approaches and Basic Synthetic Laws for Microporous Compounds
Hydrothermal Synthesis Approach to Zeolites
Solvothermal Synthesis Approach to Aluminophosphates
Crystallization of Zeolites under Microwave Irradiation
Hydrothermal Synthesis Approach in the Presence of Fluoride Source
Special Synthesis Approaches and Recent Progresses
Application of Combinatorial Synthesis Approach and Technology in the Preparation of Microporous Compounds
Typical Synthetic Procedures for some Important Molecular Sieves
Linde Type A (LTA)
Faujasite (FAU)
Mordenite (MOR)
ZSM-5 (MFI)
Zeolite Beta (BEA)
Linde Type L (LTL)
AlPO 4 -5 (AFI)
AlPO 4 -11 (AEL). 3
Table of Contents provided by Publisher. All Rights Reserved.

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