Chirality in Transition Metal Chemistry : Molecules, Supramolecular Assemblies and Materials

by Hani Amouri (Laboratoire de Chimie Inorganique); Michel Gruselle (Laboratoire de Chimie Inorganique); Series Editor: Derek Woollins (University of St Andrews); Series Editor: David A. Atwood (University of Kentucky, USA); Series Editor: Robert

• ISBN13: 9780470721605
• ISBN10: 047072160X
• Format: eBook
• Copyright: 2008-11-01
• Publisher: Wiley

Summary

Chirality in Transition Metal Chemistry is an essential introduction to this increasingly important field for students and researchers in inorganic chemistry. Emphasising applications and real-world examples, the book begins with an overview of chirality, with a discussion of absolute configurations and system descriptors, physical properties of enantiomers, and principles of resolution and preparation of enantiomers. The subsequent chapters deal with the the specifics of chirality as it applies to transition metals.Some reviews of Chirality in Transition Metal Chemistry"...useful to students taking an advanced undergraduate course and particularly to postgraduates and academics undertaking research in the areas of chiral inorganic supramolecular complexes and materials." Chemistry World, August 2009"...the book offers an extremely exciting new addition to the study of inorganic chemistry, and should be compulsory reading for students entering their final year of undergraduate studies or starting a Ph.D. in structural inorganic chemistry." Applied Organometallic Chemistry Volume 23, Issue 5, May 2009"...In conclusion the book gives a wonderful overview of the topic. It is helpful for anyone entering the field through systematic and detailed introduction of basic information. It was time to publish a new and topical text book covering the important aspect of coordination chemistry. It builds bridges between Inorganic, organic and supramolecular chemistry. I can recommend the book to everybody who is interested in the chemistry of chiral coordination compounds ." Angew. chem. Volume 48, Issue 18, April 2009About the SeriesChirality in Transition Metal Chemistry is the latest addition to the Wiley Inorganic Chemistry Advanced Textbook series. This series reflects the pivotal role of modern inorganic and physical chemistry in a whole range of emerging areas such as materials chemistry, green chemistry and bioinorganic chemistry, as well as providing a solid grounding in established areas such as solid state chemistry, coordination chemistry, main group chemistry and physical inorganic chemistry.

Table of Contents

Foreword by Alex von Zelewsky1.Introduction2 Chirality and enantiomers2.1 Chirality2.2 Enantiomers and racemic compounds2.3 Absolute configurations and system descriptors2.4 Physical properties of enantiomers and racemics2.5 Principles of resolution and preparation of enantiomers2.6 Summary3 Some examples of chiral organometallic complexes and asymmetric catalysis3.1 Chirality at metal half-sandwich compounds3.2 Chiral-at-metal complexes in organic synthesis3.3 Asymmetric catalysis by chiral complexes4 Chiral recognition in organometallic and coordination compounds4.2 Chiral recognition using the chiral anion strategy:4.3 Brief introduction to DNA discrimination by octahedral polypyridyl metal complexes:5 Chirality in supramolecular coordination compounds5.1 Self-assembly of chiral polynuclear complexes from achiral building units.5.2 Chirality transfer in polynuclear complexes: Enantioselective Synthesis6 Chiral enantiopure molecular materials6.1 General considerations6.2 Conductors6.3 Metallomesogens6.4 Porous metal-organic coordination networks (MOCN)6.5 Molecular magnets6.6 Chiral surfaces6.7 Summary