Controlled/Living Radical Polymerization Progress in ATRP, NMP and RAFT

by Matyjaszewski, Krzysztof

• ISBN13: 9780841237070
• ISBN10: 0841237077
• Format: Hardcover
• Copyright: 2000-07-20
• Publisher: American Chemical Society

Summary

This book examines recent progress in controlled/living radical polymerization. The volume focuses on three synthetic methods: atom transfer radical polymerization, nitroxide mediated polymerization and degenerative transfer via addition fragmentation. In addition, the volume covers the preparation and characterization of many never before seen materials using ATRP, NMP and RAFT.

Table of Contents

Preface	xi
Advances in Conventional and Controlled Radical Polymerization
Comparison and Classification of Controlled/Living Radical Polymerizations	2	(25)
Krzysztof Matyjaszewski
Kinetics of Living Radical Polymerization	27	(12)
Takeshi Fukuda
Atsushi Goto
Initiation and Termination Rates Associated with Free-Radical Polymerization in Extended Ranges of Temperature and Pressure	39	(18)
Michael Buback
Stereochemistry in Radical Polymerization of Vinyl Esters	57	(11)
Yoshio Okamoto
Kazunobu Yamada
Tamaki Nakano
Electron Paramagnetic Resonance Study of Conventional and Controlled Radical Polymerizations	68	(14)
Atsushi Kajiwara
Krzysztof Matyjaszewski
Mikiharu Kamachi
Models for Free-Radical Copolymerization Propagation Kinetics	82	(11)
Michelle L. Coote
Thomas P. Davis
Leo Radom
Topochemical Polymerization of Diene Monomers in the Crystalline State to Control the Stereochemistry of the Polymers	93	(15)
Akikazu Matsumoto
Toru Odani
Nitroxide-Mediated Polymerization
Use of Phosphonylated Nitroxides and Alkoxyamines in Controlled/``Living'' Radical Polymerization	108	(15)
C. Le Mercier
J.-F. Lutz
S. Marque
F. Le Moigne
P. Tordo
P. Lacroix-Desmazes
B. Boutevin
J.-L. Couturier
O. Guerret
R. Martschke
J. Sobek
H. Fischer
Progress Toward a Universal Initiator for Nitroxide Mediated `Living' Free Radical Procedures	123	(15)
Didier Benoit
Eva Harth
Brett Helms
Ian Rees
Robert Vestberg
Marlene Rodlert
Craig J. Hawker
Nitroxide-Mediated Controlled Free-Radical Emulsion and Miniemulsion Polymerizations of Styrene	138	(14)
M. Lansalot
C. Farcet
B. Charleux
J.-P. Vairon
R. Pirri
P. Tordo
Triazolinyl Radicals: Toward a New Mechanism in Controlled Radical Polymerization	152	(16)
Markus Klapper
Thorsten Brand
Marco Steenbock
Klaus Mullen
Atom Transfer Radical Polymerization
Living Radical Polymerization of Styrene: RuCl2(PPh3)3 and Alkyl Iodide-Based Initiating Systems	168	(14)
Yuzo Kotani
Masami Kamigaito
Mitsuo Sawamoto
Copper-Mediated Living Radical Polymerization Utilizing Biological and End Group Modified Poly(ethylene-co-butylene) Macroinitiators	182	(15)
David M. Haddleton
Adam P. Jarvis
Carl Waterson
Stefan A. F. Bon
Alex M. Heming
Atom Transfer Radical Copolymerization of Styrene and Butyl Acrylate	197	(14)
Gregory Chambard
Bert Klumperman
The Copper Catalyst in Atom Transfer Radical Polymerizations: Structural Observations	211	(12)
Guido Kickelbick
Ulrich Reinohl
Teja S. Ertel
Helmut Bertagnolli
Krzysztof Matyjaszewski
Atom Transfer Radical Polymerization Mediated by Ruthenium(II)-Arene Complexes	223	(11)
Francois Simal
Dominique Jan
Albert Demonceau
Alfred F. Noels
Polychloroalkanes as ATRP Initiators: Fundamentals and Application to the Synthesis of Block Copolymers from the Combination of Conventional Radical Polymerization and ATRP	234	(14)
M. Destarac
B. Boutevin
Krzysztof Matyjaszewski
Controlled Radical Polymerization Utilizing Preformed Metal Complexes Based on Substituted Bipyridines and Terpyridines	248	(15)
U. S. Schubert
G. Hochwimmer
C. E. Spindler
O. Nuyken
Reverse Atom Transfer Radical Polymerization Using AIBN or BPO as Initiator	263	(15)
Wenxin Wang
Deyue Yan
Other Methods for Controlled Radical Polymerization
Synthesis of Defined Polymers by Reversible Addition-Fragmentation Chain Transfer: The RAFT Process	278	(19)
Ezio Rizzardo
John Chiefari
Roshan T. A. Mayadunne
Graeme Moad
San H. Thang
Preparation of Macromonomers via Chain Transfer with and without Added Chain Transfer Agent	297	(16)
John Chiefari
Justine Jeffery
Roshan T. A. Mayadunne
Graeme Moad
Ezio Rizzardo
San H. Thang
End-Group Control in Catalytic Chain Transfer Polymerization	313	(21)
Johan P. A. Heuts
David A. Morrison
Thomas P. Davis
New Materials by Controlled Radical Polymerization
Synthesis of Polystyrene-Polyacrylate Block Copolymers by Nitroxide-Mediated Radical Polymerization	334	(13)
Sophie Robin
Yves Gnanou
Functionalized Polymers by Atom Transfer Radical Polymerization	347	(14)
Scott G. Gaynor
Krzysztof Matyjaszewski
Copolymerization of n-Butyl Acrylate with Methyl Methacrylate and PMMA Macromonomers by Conventional and Atom Transfer Radical Copolymerization	361	(11)
Sebastian G. Roos
Axel H. E. Muller
Krzysztof Matyjaszewski
Quantitative Derivatizations of 1-Chloro-1-phenylethyl Chain End of Polystyrene Obtained by Quasiliving Atom Transfer Radical Polymerization	372	(12)
Bela Ivan
Tamas Fonagy
Synthesis of Alternating Copolymers of N-Substituted Maleimides with Styrene via Atom Transfer Radical Polymerization	384	(10)
Fu-Mian Li
Guang-Qiang Chen
Ming-Qiang Zhu
Peng Zhou
Fu-Sheng Du
Zi-Chen Li
Controlled Radical Copolymerization of Styrene and Acrylonitrile	394	(14)
S. Brinkmann-Rengel
N. Niessner
Synthesis of Oligomers by Stable Free Radical Polymerization of Acrylates, Methacrylates, and Styrene with Alkoxyamine Initiators	408	(19)
Helmut Keul
Dirk Achten
Birte Reining
Hartwig Hocker
Potential Impact of Controlled Radical Polymerization on Markets for Polymeric Materials	427	(18)
James Spanswick
Elizabeth A. Branstetter
William F. Huber, Jr.
Indexes
Author Index	443	(2)
Subject Index	445