Handbook of Bond Dissociation Energies in Organic Compounds

by Luo, Yu-Ran

• ISBN13: 9781420039863
• ISBN10: 1420039865
• Copyright: 2002-12-26
• Publisher: Taylor & Francis

Summary

So many compounds, so many experiments reported by so many researchers using so many methods…Finding reliable data on bond dissociation energies (BDEs) can be like looking for a needle in a haystack. But these data are crucial to work in chemical kinetics, free radical chemistry, organic thermochemistry, and physical organic chemistry-so where does one turn? With data on almost 2900 bonds in 2500 organic compounds, the Handbook of Bond Dissociation Energies in Organic Compounds is the first comprehensive collection of experimental BDE data. Author Dr. Yu-Ran Luo has spent more than 10 years collecting, assessing, and tabulating BDE experiment results and presents them here in a well-organized, easy-to-use series of tables. For each compound, the tables list up to five recent experimental values, indicate which is the recommended value, give the method used to determine each value, and provide references for each value. An outstanding format and complete indexing both by compound name and by compound class make searching for data quick and easy. While experimental BDE values carry inherent uncertainties, the value of this compilation does not. There is simply no other resource that provides as much data. With this book, when you need data on a particular bond dissociation energy, you'll find it within just a few minutes.

Table of Contents

Introduction

A Database of the BDEs

What is the BDE?

Why We Need Reliable BDEs

Scope of this Book

On Energy Units

How to Search for BDEs in this Book

How to Use the Tables of the BDE Data

Experimental Methods For Measuring Bdes

TABULATED Bdes Of C-H Bonds

Chain-Saturated Hydrocarbons

Chain-Unsaturated Hydrocarbons

Cyclic Hydrocarbons

Aromatic Hydrocarbons

Halogenated Hydrocarbons

Organic Compounds Containing Heteroatoms

TABULATED bdes of C-C Bonds

Saturated Hydrocarbons

Chain-Unsaturated Hydrocarbons

Aromatic Hydrocarbons

Halogenated Hydrocarbons

Organic Compounds Containing Heteroatoms

TABULATED Bdes Of C-Halogen Bonds

C-F Bonds

C-Cl Bonds

C-Br Bonds

C-I Bonds

TABULATED Bdes Of O-X Bonds

O-H Bonds

O-O Bonds

O-C Bonds

O-N Bonds

O-S, O-Halogen, and O-P Bonds

TABULATED Bdes Of N-X Bonds

N-H Bonds

N-N Bonds

N-C Bonds

N-S Bonds

N-Halogen Bonds

TABULATED Bdes Of S-X Bonds

S-H Bonds

S-S Bonds

S-C Bonds

S-Halogen and S-P Bonds

TABULATED Bdes of Si-, Ge-, Sn-, P-, And Se-X Bonds

Si-X Bonds

Ge-X Bonds

Sn-X Bonds

P-X Bonds

Se-X Bonds

TABULATED Bdes In Some Inorganic Compounds

Heats Of Formation Of Atoms, Inorganic And Organic Radicals

Gaseous Atoms

Small Inorganic Radicals in the Gas Phase

Organic Radicals in the Gas Phase

Group Additivity Values for Organic Radicals

References

Index Of Compound Classes

Index Of Compound Names

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